A multidentate copper complex on magnetic biochar nanoparticles as a practical and recoverable nanocatalyst for the selective synthesis of tetrazole derivatives.

Waste recycling, novel and easy methods of recycling catalysts, use of green solvents, use of selective catalysts and preventing the production of by-products are the most important principles of green chemistry and modern technology. Therefore, in this work, biochar nanoparticles (B-NPs) were synthesized by the pyrolysis of chicken manure as a novel method for waste recycling. Subsequently, the B-NPs were magnetized by Fe(0) nanoparticles to improve the easy recovery of biochar.

A new Schiff base 2-benzoylpyridine-based copper complex on boehmite nanoparticles as a recoverable nanocatalyst for the homoselective synthesis of 5-substituted tetrazoles.

In this study, boehmite nanoparticles (B-NPs) were prepared by a simple process and then their surface was modified by (3-aminopropyl)triethoxysilane (3-APTES). The modified B-NPs (3-APTES@B-NPs) were functionalized by 2-benzoylpyridine Schiff-base ligand toward the immobilization of the Schiff-base 2-benzoylpyridine ligand on the 3-APTES@B-NPs's surface (2BP-Schiff-base@B-NPs). Finally, copper ions were coordinated with the supported Schiff-base ligand on B-NPs toward the formation of the final catalyst (Cu-2BP-Schiff-base@B-NPs).

A Schiff base complex of lanthanum on modified MCM-41 as a reusable nanocatalyst in the homoselective synthesis of 5-substituted 1-tetrazoles.

In this work, mesoporous MCM-41 was modified by a new Schiff-base formed from the condensation of triethylenetatramine and 5-bromosalicylaldehyde. Then, it was used for the stabilization of lanthanum metal (La-Schiff base@MCM-41) as a homoselective, reusable, efficient and biocompatible catalyst in the synthesis of 5-substituted 1-tetrazole derivatives. The synthesized tetrazoles were characterized using H NMR and FT-IR spectroscopy and methods to measure their physical properties.