19 results match your criteria: "Huaibei Coal Normal College[Affiliation]"
Chem Pharm Bull (Tokyo)
April 2010
Department of Chemistry, Huaibei Coal Normal College, Huaibei Occupational Disease Prevention and Cure Hospital, Huaibei, Anhui Province, P R China
The interaction between prulifloxacin (PUFX) and human serum albumin (HSA) was investigated under simulated physiologic conditions with fluorescence spectra. The fluorescence quenching process of HSA may be mainly governed by a static quenching mechanism. The apparent binding constant K(b) between PUFX and HSA at different temperatures were 2.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
March 2010
Department of Chemistry, Huaibei Coal Normal College, Huaibei, Anhui Province, China.
The interaction between prulifloxacin, a kind of new oral taking antibiotic and pepsin, a kind of enzyme in the stomach has been investigated in vitro under a simulated physiological condition by different spectroscopic methods. The intrinsic fluorescence of pepsin was strongly quenched by prulifloxacin. This effect was rationalized in terms of a static quenching procedure.
View Article and Find Full Text PDFJ Nanosci Nanotechnol
July 2009
Department of Chemistry, Huaibei Coal Normal College, Anhui, Huaibei 235000, PR China.
p-n junction photocatalyst Cu2O/TiO2 was prepared by ball milling through doping Cu2O into TiO2 and using H2O solution as disperser. The p-n junction photocatalyst Cu2O/TiO2 was characterized by UV-Vis diffuse reflection spectrum, Scanning electron microscopy (SEM), X-ray powder diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The photocatalytic activity of the photocatalyst was evaluated by photocatalytic reduction of Cr2O7(2-) and photocatalytic oxidation of methyl orange (MO), respectively.
View Article and Find Full Text PDFJ Hazard Mater
December 2009
Department of Chemistry, Huaibei Coal Normal College, Anhui, Huaibei 235000, People's Republic of China.
p-n junction photocatalyst p-CaFe(2)O(4)/n-Ag(3)VO(4) was prepared by ball milling Ag(3)VO(4) in H(2)O doped with p-type CaFe(2)O(4). The structural and optical properties of the photocatalyst were characterized by X-ray powder diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and UV-vis diffuse reflection spectrum (DRS). The photocatalytic activity was evaluated by photocatalytic degradation of methylene blue (MB) under visible light irradiation.
View Article and Find Full Text PDFJ Hazard Mater
May 2009
Department of Chemistry, Huaibei Coal Normal College, Anhui, Huaibei 235000, People's Republic of China.
In this paper, the photocatalytic degradation of methamidophos, an organophosphorous pesticide, was investigated in aqueous solution by using TiO(2) as a photocatalyst. The degradation was studied under different conditions such as the amount of the photocatalyst, illumination time, pH of the system, reaction temperature, initial concentration, electron acceptors, metal ions and presence of anions. The results showed that the photocatalytic degradation of methamidophos was strongly influenced by these parameters.
View Article and Find Full Text PDFJ Hazard Mater
June 2008
Department of Chemistry, Huaibei Coal Normal College, Anhui, Huaibei 235000, People's Republic of China.
p-n Junction photocatalyst NiO/TiO2 was prepared by sol-gel method using Ni(NO3)2.6H2O and tetrabutyl titanate [Ti(OC4H9)4] as the raw materials. The p-n junction photocatalyst NiO/TiO2 was characterized by UV-vis diffuse reflection spectrum, X-ray powder diffraction (XRD) and X-ray photoelectron spectroscopy (XPS).
View Article and Find Full Text PDFYing Yong Sheng Tai Xue Bao
March 2007
Department of Biology, Huaibei Coal Normal College, Huaibei 235000, Anhui, China.
With pot experiment, this paper studied the effects of silicon supply on drought-resistance capability of maize plant. The results showed that under mild and severe drought stress, supplying silicon could increase the plant biomass by 31.1%-33.
View Article and Find Full Text PDFChemosphere
March 2007
Department of Chemistry, Huaibei Coal Normal College, Anhui, Huaibei 235000, People's Republic of China.
In this paper, the photocatalytic degradation of glyphosate selected as the deputy of organic pollutant in aqueous solution with TiO(2) powder as a photocatalyst has been studied. The effects of various parameters, such as the amount of the photocatalyst, illumination time, initial pH value, electron acceptors, metal ions, and anions on the photocatalytic degradation of glyphosate were investigated. From the studies, the best condition for the effect of the parameters on the photocatalytic degradation of glyphosate was obtained.
View Article and Find Full Text PDFGuang Pu Xue Yu Guang Pu Fen Xi
July 2006
Chemistry Department, Huaibei Coal Normal College, Huaibei 235000, China.
Nanometer-sized L-cysteine-capped ZnS particles as a fluorescence probe were synthesized, and the effect of proteins on the fluorescence intensity has been investigated. With deltalambda = 190 nm, the maximum and constant synchronous fluorescence enhancement was produced at 268.0 nm and pH 5.
View Article and Find Full Text PDFYing Yong Sheng Tai Xue Bao
February 2006
Department of Biology, Huaibei Coal Normal College, Huaibei 235000, China.
This paper studied the water regulation characteristics and stress resistance of Caragana opulens population in Helinger (semi-arid area) and Alashan (intensively arid area), aimed to understand the adaptation mechanisms of this population to arid environment. The results showed that compared with Helinger population, Alashan population had a higher content of osmotic adjustment substances in leaf cells, which resulted in a lower osmotic potential, and thus, stronger osmotic adjustment ability. The leaf water and free water contents of Alashan population were lower than those of Helinger population, while the bound water content and the ratio of bound water to free water of the former were higher than those of the latter.
View Article and Find Full Text PDFChemosphere
September 2005
Department of Chemistry, Huaibei Coal Normal College, Anhui, Huaibei 235000, People's Republic of China.
In this paper, dichromate and dichlorvos are selected as the deputies of inorganic and organic pollutants, respectively, and TiO2/beads is used as a photocatalyst. The effects of various parameters, such as the amount of the photocatalyst, H2O2 concentration, metal ions, anions, pH value, and organic compounds on the photocatalytic reduction of dichromate and photocatalytic oxidation of dichlorvos are studied. From the studies, the differences of the parameters effect on the photocatalytic degradation of organic and inorganic pollutants are obtained.
View Article and Find Full Text PDFGuang Pu Xue Yu Guang Pu Fen Xi
December 2004
Department of Chemistry, Huaibei Coal Normal College, Huaibei 235000, China.
In this paper, a new synergetic extraction catalytic spectrophotometric method for the determination of trace chromium was studied. The method is based on the iron(III) and chromium(VI) synergetic catalyzed oxidation of o-aminophenol by hydrogen peroxide in weak acidic medium at pH 5.5.
View Article and Find Full Text PDFGuang Pu Xue Yu Guang Pu Fen Xi
July 2004
Department of Chemistry, Huaibei Coal Normal College, Huaibei 235000, China.
In this paper, a new catalytic kinetic spectrophotometric method for the determination of trace amounts of ascorbic acid has been studied. The method is based on the activation effect of ascorbic acid on vanadium (V) catalyzed oxidation of deoxidized rhodamine B by potassium bromate in weak acidic medium at pH 4.5.
View Article and Find Full Text PDFYing Yong Sheng Tai Xue Bao
January 2004
Department of Biology, Huaibei Coal Normal College, Huaibei 235000, China.
Soybean plants were planted in pots to investigate the effects of soil available silicon on their growth, development and physiological functions. When the content of soil available silicon was 55.1-202.
View Article and Find Full Text PDFGuang Pu Xue Yu Guang Pu Fen Xi
April 2003
Department of Chemistry, Huaibei Coal Normal College, Huaibei 235000, China.
In this paper, a new catalytic kinetic spectrophotometric method for the determination of activator aluminum was studied. The method was based on the activation effect of aluminum (III) on the copper (II) which catalyzes the oxidation of pyrocatechol by hydrogen peroxide in acetic acid-sodium acetate buffer solution at pH 5.0.
View Article and Find Full Text PDFGuang Pu Xue Yu Guang Pu Fen Xi
February 2002
Department of Chemistry, Huaibei Coal Normal College, Huaibei 235000, China.
A new extraction catalytic kinetic spectrophotometric method for the determination of trace molybdenum is studied. The method is based on the molybdenum (VI) catalytic oxidation of o-aminophenol by hydrogen peroxide in week acidic medium at pH 5.5.
View Article and Find Full Text PDFGuang Pu Xue Yu Guang Pu Fen Xi
February 2003
Department of Chemistry, Huaibei Coal Normal College, Huaibei 235000, China.
A new catalytic fluorimetric method for the determination of trace oxalate has been developed. The method is based on the catalytic effect of oxalate on the oxidation of potassium dichromate with rhodamine B in sulfuric acid medium. The catalytic reaction takes place at 50 degrees C for 10 min in a water bath and is a pseudo-zero-order reaction.
View Article and Find Full Text PDFGuang Pu Xue Yu Guang Pu Fen Xi
February 2003
Department of Chemistry, Huaibei Coal Normal College, Huaibei 235000, China.
In this paper, the reaction mechanism of the system of thallium (III)-copper(II)-ethylenediaminete-traacetate-hydrogen peroxide-diphenylcarbazide has been studied by spectrophotometric method. The experimental results show that the reaction mechanism of the system is based on the replacement of copper(II) by thallium (III) in copper-ethylenediamine-tetraacetate complex and the copper(II) catalyzed oxidation of diphenylcarbazide by hydrogen peroxide to form diphenylcarbazone and the color reaction of copper(II) with diphenylcarbazone in weak acidic medium at pH 5.5.
View Article and Find Full Text PDFGuang Pu Xue Yu Guang Pu Fen Xi
December 2002
Department of Chemistry, Huaibei Coal Normal College, Huaibei 235000, China.
In this paper, a new extraction catalytic spectrophotometric method for the simultaneous determination of iron and molybdenum has been studied. The method is based on the difference of the reaction rate of iron(III) and molybdenum(VI) catalyzed oxidation of o-aminophenol by hydrogen peroxide in weak acidic medium at pH 5.5.
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