Highly selective CO photoreduction to CO on MOF-derived TiO.

Metal-Organic Framework (MOF)-derived TiO, synthesised through the calcination of MIL-125-NH, is investigated for its potential as a CO photoreduction catalyst. The effect of the reaction parameters: irradiance, temperature and partial pressure of water was investigated. Using a two-level design of experiments, we were able to evaluate the influence of each parameter and their potential interactions on the reaction products, specifically the production of CO and CH.