Severity: Warning
Message: fopen(/var/lib/php/sessions/ci_sessionsmao5d77ia3idfgjpibeohek0eldgela): Failed to open stream: No space left on device
Filename: drivers/Session_files_driver.php
Line Number: 177
Backtrace:
File: /var/www/html/index.php
Line: 316
Function: require_once
Severity: Warning
Message: session_start(): Failed to read session data: user (path: /var/lib/php/sessions)
Filename: Session/Session.php
Line Number: 137
Backtrace:
File: /var/www/html/index.php
Line: 316
Function: require_once
15,703 results match your criteria: "Henan Normal University; wq11ab@163.com.[Affiliation]"
J Am Chem Soc
March 2025
State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China.
Understanding the participation of f-orbitals of actinide elements in covalent bond formations is less explored, compared to the well-studied d-orbitals of transition metals, leading to the significant interest in actinide-carbon multiple bonds. Uranium alkylidene complex, containing an alkylidene linkage of the form U═CR (R = H, alkyl, silyl), represents a key milestone in actinide-ligand multiple bonding, but their isolation and characterization have remained elusive. Herein, we present the synthesis of an unprecedented uranium disilyl-substituted alkylidene complex, achieved through sequential dehydrogenation reactions of a methyl group under mild conditions.
View Article and Find Full Text PDFBMC Psychol
March 2025
College of Culture and Arts, Sangmyung University, Seoul, 03016, Republic of Korea.
Objective: This Research explores the intermediary function of academic stress and sleep quality in the connection between physical exercise and subjective well-being among high school students.
Methods: This Research conducted an online survey through random sampling with a sample of 540 (males = 310, females = 217; grade 10 = 159, grade 11 = 190, grade 12 = 178) high school students to explore the intermediary function of academic stress and sleep quality between physical exercise and subjective well-being. The participants were surveyed using PSQI, the Subjective Well-Being Scale, the ESSA, and PSQI.
Oncogene
March 2025
Henan Key Laboratory for Helicobacter pylori & Microbiota and GI cancer, Marshall Medical Research Center, The Fifth Affiliated Hospital of Zhengzhou University, Zhengzhou, 450052, Henan, China.
Despite intensive multimodal therapy, the prognosis for patients with digestive system cancers remains poor. Cancer cell heterogeneity and immunosuppressive microenvironments are the main barriers to the effective CAR-T cell therapy with solid malignancies. In parallel, tumor-associated macrophages (TAMs) are essential for tumor immunosuppressive microenvironment formation.
View Article and Find Full Text PDFSci Rep
March 2025
School of Computer and Artificial Intelligence, Zhengzhou University, Zhengzhou, 450001, China.
With the rapid growth of e-commerce and ongoing innovations in the logistics industry, intelligent unmanned logistics warehousing systems have emerged to significantly enhance operational efficiency and reduce costs. In these systems, the two critical stages of order assignment and path planning are interconnected through racks in the order picking process. However, prior research has largely overlooked their joint optimization.
View Article and Find Full Text PDFNat Commun
March 2025
Department of Materials Science and Engineering, City University of Hong Kong, Hong Kong SAR, PR China.
Strain engineering offers an attractive strategy for improving intrinsic catalytic performance of a heterogeneous catalyst. Herein, we successfully create strain into layered indium sulfide (InS) at atomic scale via introducing oxygen coordination and sulfur vacancy using a wet-chemistry method. The atomically strained InS exhibits greatly enhanced CO photoreduction performance, achieving a CO to CO conversion rate of 5.
View Article and Find Full Text PDFMikrochim Acta
March 2025
Henan Key Laboratory of Biomolecular Recognition and Sensing, Henan Joint International Research Laboratory of Chemo/Biosensing and Early Diagnosis of Major Diseases, College of Chemistry and Chemical Engineering, Shangqiu Normal University, Shangqiu, 476000, China.
CuNi/Fe LDHs with HRP-like activity (nanozyme) have been prepared. Contrary to the expected design, free dopamine (DA) was found to greatly enhance the catalytic performances of CuNi/Fe LDHs nanozyme. As far as we know, this is the first report that free DA boosts the catalytic performances of LDHs.
View Article and Find Full Text PDFBioorg Med Chem
April 2025
Centre for Artificial Intelligence Driven Drug Discovery, Faculty of Applied Sciences, Macao Polytechnic University, Macao 999078, China. Electronic address:
Since 2020, numerous compounds have been investigated for their potential use in treating SARS-CoV-2 infections. By identifying the molecular targets during the virus replication process, rationally designed anti-SARS-CoV-2 agents are developed. Among these targets, the main protease (M) is a crucial enzyme required for virus replication, and its highly conserved characteristic make it an important drug target for the development of anti-SARS-CoV-2 drugs.
View Article and Find Full Text PDFActa Psychol (Amst)
April 2025
School of music and dance, Zhengzhou Normal University, Zhengzhou, Henan 450044, China. Electronic address:
Background: Academic burnout is a common mental health issue among college students, particularly pronounced among students majoring in music education. Despite evidence that professional identity influences academic burnout, the mechanism of action remains unclear, particularly the relationship between academic self-efficacy and academic burnout. Furthermore, research specifically addressing the connection between professional identity and academic burnout among music majors is relatively limited.
View Article and Find Full Text PDFConscious Cogn
March 2025
Department of Psychology, Xinxiang Medical University, Xinxiang 453003 Henan Province, China; Mental Illness and Cognitive Neuroscience Key Laboratory of Xinxiang (Xinxiang Medical University), Xinxiang 453003 Henan Province, China. Electronic address:
The Trait Anxiety Attention Control Theory suggests an imbalance in high trait anxiety individuals between bottom-up and top-down processing. To investigate this theory, we designed an experimental paradigm combining task-switching and Stroop tasks to investigate behavioral and neuroelectrophysiological features in trait anxiety. The results revealed a significant negative correlation between trait anxiety levels and switch costs, indicating a preference for automatic processing among those with high trait anxiety.
View Article and Find Full Text PDFJ Pediatr Surg
February 2025
Department of Pediatric Surgery, The First Affiliated Hospital of Zhengzhou University, Zhengzhou, Henan, 450000, China. Electronic address:
Introduction: We reviewed a 7-year experience (Jan 2016 to Oct 2023) in diagnosing and surgically treating Acquired Rectovestibular Fistula (ARVF). Our study describes the medical history, introduces new classifications based on fistula features, and outlines the application of diverse surgical techniques in treating these patients.
Methods: A total of 78 girls with ARVF appeared asymptomatic at birth.
Talanta
August 2025
School of Chemistry and Chemical Engineering/State Key Laboratory Incubation Base for Green Processing of Chemical Engineering, Shihezi University, Shihezi, 832003, PR China. Electronic address:
Hydrogen sulfide (HS) is a pivotal signaling molecule in plants and appropriate levels are essential for normal growth. As such the real-time detection of HS in plants is required since it enables timely targeted interventions. However, most fluorescent probes for detecting HS reported to date exhibit fluorescence quenching in aqueous solution thereby significantly constraining their potential for in vivo applications.
View Article and Find Full Text PDFJ Hazard Mater
February 2025
International Joint Research Center for Persistent Toxic Substances (IJRC-PTS), State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, Harbin 150090, China.
While traditional organochlorine pesticides (OCPs) have been phased out under international regulations, novel OCPs are increasingly used as substitutes, however, their environmental behavior was not well clarified. Here, the first comprehensive study on the occurrence, seasonal-spatial variation, and air-soil exchange of both traditional and novel OCPs across a 30° latitudinal gradient (22°N to 52°N) in Eastern China were conducted. Air concentrations of ΣOCPs peaked during summer months, whereas soil concentrations were elevated in winter.
View Article and Find Full Text PDFAnal Chem
March 2025
State Key Laboratory of Environmental Chemistry and Eco-Toxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, 18 Shuangqing Road, P.O. Box 2871, Beijing 100085, China.
Luminol-based chemiluminescence (CL) systems, as a powerful tool for bioanalysis, are limited owing to their weak CL intensity and self-decomposition of the classic oxidant HO. Herein, we introduced a new luminol CL enhancer, the natural light-driven photocatalyst MIL-100(Fe)/TiO, for the selective determination of dopamine (DA). By employing MIL-100(Fe)/TiO for the first time as an efficient enhancer, the MIL-100(Fe)/TiO-luminol CL intensity was 100 times higher than that of the classical HO-luminol system.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
February 2025
State Key Laboratory of Structural Chemistry and Fujian Provincial Key Laboratory of Materials and Techniques toward Hydrogen Energy, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China.
High-entropy materials are poised to revolutionize materials science and industrial applications due to their design flexibility, peculiar performance, and broad applicability. In this study, we present a proof-of-concept high-entropy engineered nanocarbon (HENC) co-doped with five nonmetal elements (B, F, P, S, and N), synthesized via in situ polymerization modification of ZIF-8 followed by pyrolysis. The HENC exhibits outstanding performance as a nonmetal electrocatalyst for the oxygen reduction reaction (ORR), with activity on par with benchmark Pt/C electrocatalysts and superior cyclic stability.
View Article and Find Full Text PDFBMC Biol
February 2025
State Key Laboratory of Biocontrol, School of Ecology, Sun Yat-sen University, Shenzhen, 518107, China.
Background: Dietary shifts are major evolutionary steps that shape ecological niches and biodiversity. The beetle family Coccinellidae, commonly known as ladybirds, first transitioned from a fungivorous to an insectivorous and subsequently a plant diet. However, the molecular basis of this dietary diversification remained unexplored.
View Article and Find Full Text PDFBMC Genomics
February 2025
The Shennong Laboratory, Henan Agricultural University, Zhengzhou, 450002, China.
Background: The fertility of roosters significantly impacts the economic outcome of the poultry industry. However, it is common for some roosters to fail to produce semen during production, and the underlying reasons remain largely unclear.
Results: To investigate a solution to this problem, induced molting (IM) was performed on no-semen (NS) roosters.
BMC Pediatr
February 2025
Department of Electrical Biology, Henan Children's Hospital, Children's Hospital Affiliated to Zhengzhou University, Henan Children's Hospital Zhengzhou Children's Hospital, Zhengzhou, 450018, China.
Background: Cardiac tumors in children are rare and usually have no obvious clinical symptoms. However, a small number of children may experience serious conditions such as arrhythmia, heart obstruction, and even death. When severe arrhythmia cannot be controlled by conservative treatment, surgical intervention is needed.
View Article and Find Full Text PDFSci Rep
February 2025
China Coal Technology and Engineering Group Chongqing Research Institute, Chongqing, 400037, China.
As an important geological environment medium for engineering construction in southwest China, basalt generally contains hidden microcracks at a micro-scale, which leads to significant size effect on its mechanical properties, and relevant research is lacking and unsystematic. A synthetic rock mass model based on the combination of a micro-discrete fracture network method and a finite-discrete element method is used to systematically explore the size effect of the mechanical properties of basalt rock blocks with hidden microcracks. The results showed that: (1) the fracture angle is uniformly distributed, and the fracture length conforms to the logarithmic normal distribution, with an areal fracture intensity P20 of 0.
View Article and Find Full Text PDFPathol Res Pract
April 2025
School of Basic Medical College, Beihua University, Jilin 132013, China. Electronic address:
Background: The aim of the research is to investigate correlation of immune infiltration between IL-17B and IL-17RB in colorectal cancer (CRC), then provide an experimental basis for clinical diagnostic marker screening of CRC.
Methods: Gene expression levels were assessed via TIMER and GEPIA databases, protein expression through the Human Protein Atlas (HPA), clinicopathological correlations and prognosis via UALCAN and KM-Plotter, respectively. Mutation analysis was conducted using cBioPortal, immune cell infiltration via TIMER, and hub genes were identified through protein-protein interaction (PPI) networks.
J Plant Physiol
February 2025
College of Agronomy, Henan Agricultural University, Zhengzhou, 450046, China. Electronic address:
Potassium (K), an indispensable nutrient for plant growth and development, plays a crucial role in plant stress resistance. Within the K regulatory network in plants, the HAK/KUP/KT gene family comprises a dominant group of K transport proteins responsible for K uptake and transport. This study functionally characterized the wheat gene TaHAK18, which encodes a putative K transporter.
View Article and Find Full Text PDFSci Adv
February 2025
State Key Laboratory of Vegetable Biobreeding, Department of Plant Protection, Institute of Vegetables and Flowers, Chinese Academy of Agricultural Sciences, Beijing 100081, China.
Tomato yellow leaf curl virus (TYLCV), a devastating pathogen of tomato crops, is vectored by the whitefly , yet the mechanisms underlying TYLVC epidemics are poorly understood. We found that TYLCV triggers the up-regulation of two β-myrcene biosynthesis genes in tomato, leading to the attraction of nonviruliferous . We also identified BtMEDOR6 as a key whitefly olfactory receptor of β-myrcene involved in the distinct preference of MED for TYLCV-infected plants.
View Article and Find Full Text PDFPLoS One
February 2025
College of Information, Mechanical and Electrical Engineering, Shanghai Normal University, Shanghai, China.
Ternary Optical Computer (TOC) is unique in the development of optical computers, in terms of principle, experiment, algorithm and application. After 20 years of development, six generations of prototypes have been developed. At present, tri-state optical signal storage is the main problem faced by TOC.
View Article and Find Full Text PDFJACS Au
February 2025
School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang 453007, Henan China.
A general method for the catalytic asymmetric α-selenenylation of simple carbonyl compounds is lacking. Herein, a copper(I)-catalyzed enantioselective α-selenenylation of 2-acylimidazoles with electrophilic selenosulfonates is uncovered. The reaction enjoys the advantages of mild conditions, easy reaction protocol, and broad substrate scopes on both 2-acylimidazoles and selenosulfonates.
View Article and Find Full Text PDFJ Am Chem Soc
March 2025
Catalonia Institute for Energy Research-IREC, Sant Adrià de Besòs, Barcelona 08930, Spain.
Room-temperature sodium-sulfur (Na-S) batteries are emerging as a promising next-generation energy storage technology, offering high energy densities at low cost and utilizing abundant elements. However, their practical application is hindered by the shuttle effect of sodium-polysulfides and the sluggish kinetics of sulfur redox reactions. In this study, we demonstrate a heteronuclear diatomic catalyst featuring Fe and Co bimetallic sites embedded in nitrogen-doped hollow carbon nanospheres (Fe-Co/NC) as an effective sulfur host at the cathode of Na-S batteries.
View Article and Find Full Text PDFBMC Psychol
February 2025
College of Education Science, Henan Institute of Science and Technology, Xinxiang, China.
Background: The mental health of first-generation college students has received much attention from researchers. The dual-factor model of mental health emphasizes the integration of psychopathology and well-being to achieve a comprehensive assessment of mental health. Previous research has focused on the psychopathology and well-being of first-generation college students in isolation while ignoring the overall mental health development.
View Article and Find Full Text PDF