Ru(ii)-catalyzed regioselective oxidative Heck reaction with internal olefins that tolerated strongly coordinating heterocycles.

The oxidative Heck reaction of strongly coordinating heterocycles with internal olefins often led to elusive reactivity and regioselectivity. Herein, by judicious choice of X-type directing groups under Ru(ii) catalysis, we achieved the regioselective oxidative Heck reaction of strongly coordinating heterocycles with sterically demanding internal olefins. It was postulated that the "match/mismatch effect" of sterically demanding internal olefins as coupling partners and subsequent kinetically favoured Michael addition or oxidative aromatization act as driving forces to facilitate the desired reactivity and site-selectivity.

-SR removal or -R removal? A mechanistic revisit on the puzzle of ligand etching of Au(SR) nanoclusters during electrocatalysis.

Accurate identification of active sites is highly desirable for elucidation of the reaction mechanism and development of efficient catalysts. Despite the promising catalytic performance of thiolated metal nanoclusters (NCs), their actual catalytic sites remain elusive. Traditional first-principles calculations and experimental observations suggested dealkylated S and dethiolated metal, respectively, to be the active centers.

Translating 2D Director Profile to 3D Topography in a Liquid Crystal Polymer.

Morphological properties of surfaces play a key role in natural and man-made objects. The development of robust methods to fabricate micro/nano surface structures has been a long pursuit. Herein, an approach based on molecular self-assembling of liquid crystal polymers (LCPs) is presented to directly translate 2D molecular director profiles obtained by a photoalignment procedure into 3D topographies, without involving further multi-step lithographic processes.

Dissolving organic matter from low-organic sewage sludge for shortening the anaerobic digestion time.

Pretreatments have been successfully used to shorten the HRT of anaerobic digestion (AD) of sewage sludge, but they become ineffective for low-organic sewage sludge, with HRT > 10 days. Herein, a new process using alkaline hydrolysis-anaerobic digestion has been developed to solve this problem. Firstly, maximum organic matter in the sludge was dissolved by strong alkaline hydrolysis (pH > 11) in a two-stage alkaline hydrolysis system (TSAHS).

Structure-Activity Relationship and Prediction of the Electron-Transfer Potential of the Xanthones Series.

The structure-activity relationships of 31 xanthones were analyzed by using the ferric reducing antioxidant power (FRAP) assay to determine their electron-transfer (ET) potential. It was proven that the ET potential of xanthones was dominated by four moieties (i.e.