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Metal-free oxidative isocyanides insertion with aromatic aldehydes to aroylated N-heterocycles.
RSC Adv
January 2018
College of Chemistry and Materials Science, Guangxi Teachers Education University Nanning 530001 P. R. China
A metal-free, mild and efficient protocol for the construction of aroylated N-heterocycles radical cascade aroylation of phenyl or vinyl isocyanides with aromatic aldehydes has been developed. Both phenanthridine and isoquinoline derivatives are delivered quickly in moderate to good yields with high regioselectivity.
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