Exhalation metabolomics: A new force in revealing the impact of ozone pollution on respiratory health.

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Dual-Ligand-Driven Dark Reactive Oxygen Species Generation on Iron Oxyhydroxides: Implications for Environmental Remediation.

The dark generation of reactive oxygen species (ROS), particularly hydroxyl radicals (·OH), is crucial in the oxidative transformation of various pollutants. However, the mechanisms behind this process are predominantly linked to direct O activation by reduced substances such as Fe(II) and natural organic matter. In this study, we introduce a previously overlooked dual-ligand mechanism that significantly amplifies ·OH generation on iron oxyhydroxides, facilitated by cysteine and pyrophosphate.

Cadmium-Assisted Photochemical Vapor Generation of Arsenic from Low Concentration of Formic Acid Media.

A highly sensitive method for the determination of total arsenic (As) has been developed using photochemical vapor generation (PVG) coupled with inductively coupled plasma mass spectrometry (ICP MS). The efficient PVG of As is reported for the first time in the presence of Cd(II) in diluted formic acid (FA) medium. The PVG efficiency of 93 ± 1% can be achieved in the system with 0.

Environmental fate and transformation mechanisms of chlorinated organic pollutants from the petrochemical industry: Insights for pollution control and remediation.

Chlorinated organic pollutants (Cl-OPs), highly toxic and environmentally persistent, have become the spotlight, particularly from petrochemical industry. This study focuses on environmental fate of Cl-OPs from petrochemical industry, and transformation mechanisms in multi-media, aiming to enhance pollution control and remediation strategies. Emitted from leakage and waste discharge, Cl-OPs, encompassing chlorinated volatile organic compounds (Cl-VOCs), traditional and emerging persistent organic pollutants (POPs), were prevalent with average concentrations of 10-10 μg/m in the atmosphere, 10-10 μg/kg in soil and 10-10 μg/L in groundwater.

Biotransformation of chloramphenicol by enriched bacterial consortia and the newly isolated bacterial strain Bordetella sp. C3: Detoxifying biotransformation pathway and its potential application in agriculture.

Limited sources of consortia/pure cultures that degrade chloramphenicol (CAP) and the incomplete biodegradation profiles of CAP hinder the remediation of CAP pollution. In this study, two CAP-degrading consortia (designated as CM and PM) were obtained after long-term acclimation, and Alcaligenaceae and Enterobacteriaceae enriched in CM and PM, respectively. Notably, Bordetella sp.

Increased microbial complexity and stability in rhizosphere soil: A key factor for plant resilience during mining disturbance.

The network-based complexity and stability of the microbial community are critical for host fitness under disturbance, but there are still gaps in our understanding of whether there are general rules governing this relationship. Despite evidence that the rhizosphere microbiome plays an important role in host fitness, it is unclear whether rhizosphere microbial complexity and stability influence host plant fitness under scenarios of environmental disturbance. Here, we investigated the effects of mining disturbance on the complexity and stability of the rhizosphere microbiome and its potential role in plant fitness.

Effect of Elevated Temperatures on Inflammatory Cytokine Release: An and Population-Based Study.

Extreme high temperatures in the summer have become a global concern, and their risks to the inflammatory system have been largely unknown. Here we appraised the exposure risks of summer heatwaves by comparing the sera cytokine levels in healthy individuals under high and normal temperatures. In addition, we established a cell model with a 1.

[Analysis of Ozone Pollution and Precursor Control Strategies in the Pearl River Delta During Summer and Autumn Transition Season].

To analyze the causes of ozone pollution in the Pearl River Delta （PRD） Region during the summer and autumn transition seasons, a case study was carried out in Guangzhou, which is located in the center of the PRD Region, to analyze the ozone photochemical production and destruction pathways as well as emission reduction scenarios using a box model based on comprehensive observation. The results showed that the stagnant meteorological conditions and high temperature during the observation period were suitable for the photochemical production of ozone, which led to widespread and prolonged ozone pollution. Aromatic hydrocarbons （AHs） contributed the most to the ozone formation potential （OFP）, and /-xylene, toluene, and -xylene were the major three VOC species contributing to the OFP.

LC-MS guided discovery of a new type of abyssomicin, glycoabyssomicin A, from a deep-sea derived .

Glycoabyssomicin A (), a new type of abyssomicin containing a sugar unit, was isolated from the deep-sea derived SCSIO 5802 guided by LC-MS. The structure of was elucidated by HR-ESI-MS, 1D-NMR (H,C NMR), 2D-NMR (HSQC, COSY, HMBC, NOESY), and TFA hydrolysis and acetylation reactions. In the antibacterial activities evaluation against a series of gram-positive and gram-negative bacteria, it showed inactive at the concentration of 10 μg per filter paper disc.

Electrochemical oxidation of a membrane-distillation concentrate for the treatment of real pharmaceutical wastewater.

This study presents the first investigation of the electrochemical oxidation of a real membrane-distillation (MD) concentrate for the integrated treatment of highly concentrated pharmaceutical wastewater (PWW). The coupling of electro-Fenton and anodic oxidation applied to a real MD retentate, concentrated by a factor of 1.6 compared to the original PWW, reduced the total organic carbon (TOC) concentration from 23,460 to 12,199 mg/L in 24 h (mineralization efficiency of 48%).

Arsenic-contaminated soil remediation with hyperthermophilic compost: Effects on arsenic bioavailability, soil fertility and bacterial community.

Soil arsenic (As) contamination has posed a significant global environmental challenge seriously threatening human health. Compost has attracted broad interests as a kind of eco-friendly and versatile amendment. However, hyperthermophilic compost (HTC), which is newly-developed and more advantageous to environment, has not yet been widely utilized to remediate As-contaminated soil, and its effectiveness remains unclear.

Hydroxamate Siderophores Intensify the Co-Deposition of Cadmium and Silicon as Phytolith-Like Particulates in Rice Stem Nodes: A Natural Strategy to Mitigate Grain Cadmium Accumulation.

Sequestration of cadmium (Cd) in rice phytolith can effectively restrict its migration to the grains, but how hydroxamate siderophore (HDS) affects phytolith formation within rice plants especially the fate of Cd and silicon (Si) remains poorly understood. Here, we found that the addition of HDS increased the content of dissolved Si and Cd in soil pore water as well as its absorption by the rice roots during the reproductive growth stage. HDS effectively trapped orthosilicic acid and Cd ions at the third stem nodes of rice plants via hydrogen bonds and chelation interactions, which then rapidly deposited on the xylem cell wall through hydrophobic interactions.

Quantitatively Tracking the Speciation and Dynamics of Selenium Nanoparticles in Rice Plants.

The uptake, translocation, and transformation of engineered nanoparticles (ENPs) in plants present significant challenges due to the lack of effective determination methods. This is especially true for selenium nanoparticles (SeNPs), which hold promise for Se-biofortified agriculture and exhibit dynamic behaviors within plant system. Herein, we proposed a novel approach that incorporates enzymic digestion and membrane filtration to selectively extract SeNPs and dissolved Se from plant tissues, employing rice () plant as a model.

Synergistically enhanced heterogeneous activation of dissolved oxygen for aqueous carbamazepine degradation over S(III) coupled with siderite.

The wide occurrence of emerging contaminants (ECs) was drawing more attention due to the potential hazard and threat on human and environment. Carbamazepine (CBZ) is a widely prescribed medication that has garnered considerable research interest with the exposures exceeding the environmental carrying capacity. We have established the innovative heterogeneous advanced oxidation process (AOPs) based on the activated dissolved oxygen (DO) coupled with S(III) and natural iron ore (siderite).

Aquatic macrophytes mitigate the conflict between nitrogen removal and nitrous oxide emissions during tailwater treatments.

Tailwater from wastewater treatment plants (WWTP) usually reduces the nitrogen (N) removal efficiency while simultaneously elevates nitrous oxide (NO) emissions due to the low carbon-nitrogen (C/N) ratio. Conflicts between N removal and NO emissions require mitigation by selecting appropriate aquatic plants for tailwater treatment. In this study, a simulated tailwater mesocosm was established using three aquatic plants including Eichhornia crassipes, Myriophyllum aquaticum and Pistia stratiotes.