Cross-Linked Polyamide-Integrated Argyrodite LiPSCl for All-Solid-State Lithium Metal Batterie.

Lithium dendrite growth has become a significant barrier to realizing high-performance all-solid-state lithium metal batteries. Herein, an effective approach is presented to address this challenge through interphase engineering by using a cross-linked polyamide (negative electrostatic potential) that is chemically anchored to the surface of LiPSCl (positive electrostatic potential). This method improves contact between electrolyte particles and strategically modifies the local electronic structure at the grain boundary.

Oxychloride Polyanion Clustered Solid-State Electrolytes via Hydrate-Assisted Synthesis for All-Solid-State Batteries.

Solid-state electrolytes (SSEs) play a vital role in the development of high-energy all-solid-state batteries. However, most adopted mechanical ball milling and/or high-temperature annealing are ineffective approaches for large-scale synthesis. Herein, a universal and scalable hydrate-assisted strategy for the synthesis of oxychloride SSEs is developed based on the chemical reaction among alkali chlorides, AlCl, and AlCl·6HO.

Preparation of Thin-Layered Hexagonal Boron Nitride Nanosheet with Oxygen Doping.

Hexagonal boron nitride nanosheet (h-BNNS), a structural analogue of graphene, possesses remarkable properties such as exceptional electrical insulation, great resistance to corrosion, excellent mechanical strength, and thermal conductivity. Nonetheless, its continued development is still hampered by the lack of a preparation technique with an easy-to-follow procedure and reliable composition and structure control. In this study, we investigated a two-step protocol for uniform size production of thin-layered h-BNNS.

Development of High-Precision NO Gas Sensor Based on Non-Dispersive Infrared Technology.

Increasing concerns about air quality due to fossil fuel combustion, especially nitrogen oxides (NO) from marine and diesel engines, necessitate advanced monitoring systems due to the significant health and environmental impacts of nitrogen dioxide (NO). In this study, a gas detection system based on the principle of the non-dispersive infrared (NDIR) technique is proposed. Firstly, the pyroelectric detector was developed by employing an ultra-thin LiTaO (LT) layer as the sensitive element, integrated with nanoscale carbon material prepared by wafer-level graphics technology as the infrared absorption layer.

A Bulk Oxygen Vacancy Dominating WO Photocatalyst for Carbamazepine Degradation.

Creating oxygen vacancy in tungsten trioxide (WO) has been considered as an effective strategy to improve the photocatalytic performance for degrading organic pollutants. In this study, oxygen vacancies were introduced into WO by thermal treatment under Ar atmosphere and their proportion was changed by setting different treatment times. WO samples show better photoelectric properties and photocatalytic degradation performance for carbamazepine (CBZ) than an oxygen-vacancy-free sample, and WO with the optimal proportion of oxygen vacancies is obtained by thermal treatment for 3 h in 550 °C.

Data-Driven Design of Nickel-Free Superelastic Titanium Alloys.

In this paper, a CatBoost model for predicting superelastic strains of alloys was established by utilizing features construction and selection as well as model filtering and evaluation based on 125 existing data points of superelastic titanium alloys. The alloy compositions of a TiNbMoZrSnTa system were optimized and three nickel-free titanium alloys with potentially excellent superelastic properties were designed using the Bayesian optimization algorithm using a superelastic strain as the optimization target. The experimental results indicated that only Ti-12Nb-18Zr-2Sn and Ti-12Nb-16Zr-3Sn exhibited clear superelasticity due to the absence of relevant information about the alloys' β stability in the machine learning model.

Gold-Catalyzed Oxidation Reactions of Thioalkynes with Quinoline N-Oxides: A DFT Study.

Mechanistic investigation of the gold-catalyzed oxidative reactions of thioalkynes with quinoline N-oxides was performed using density functional theory (DFT) calculations. For the oxidative rearrangement of thioalkynes with quinoline N-oxide to yield the same products, the C-oxidation of thioalkynes was predicted to be competitive with C-oxidation, with the C-oxidative process slightly more favorable. However, for the oxidative alkenylation of propargyl aryl thioethers with quinoline N-oxides, the C-oxidation of thioether by quinoline N-oxide generated the product 3-hydroxy-1-alkylidene phenylthiopropan-2-one.

Ultra-thin and Mechanically Stable LiCoO-Electrolyte Interphase Enabled by Mg Involved Electrolyte.

LiCoO (LCO) cathode materials have attracted significant attention for its potential to provide higher energy density in current Lithium-ion batteries (LIBs). However, the structure and performance degradation are exacerbated by increasing voltage due to the catastrophic reaction between the applied electrolyte and delithiated LCO. The present study focuses on the construction of physically and chemically robust Mg-integrated cathode-electrolyte interface (MCEI) to address this issue, by incorporating Magnesium bis(trifluoromethanesulfonyl)imide (Mg[TFSI]) as an electrolyte additive.

An All-Dielectric Metamaterial Terahertz Biosensor for Cytokine Detection.

In this paper, we report an all-dielectric metamaterial terahertz biosensor, which exhibits a high Q factor of 35 at an 0.82 resonance peak. A structure with an electromagnetically induced transparency effect was designed and fabricated to perform a Mie resonance for the terahertz response.

Effect of Cold Deformation and Heat Treatment on the Microstructures and Mechanical Properties of Au-15Ag-12Cu-6Ni Alloy Sheets.

The evolution of the microstructure and hardness changes in the Au-15Ag-12Cu-6Ni alloy during the processes of cold rolling and annealing were investigated and the heat treatment regimen for the alloy was optimized in this article. The hardness of the alloy continuously increases with the cold rolling reductions, leading to continuous deformation of the grains during the cold rolling process, ultimately resulting in smaller grain sizes. Subsequent annealing induces recovery and recrystallization, achieving complete recrystallization at 700 °C.

Structural regulation of halide superionic conductors for all-solid-state lithium batteries.

Metal halide solid-state electrolytes have gained widespread attention due to their high ionic conductivities, wide electrochemical stability windows, and good compatibility with oxide cathode materials. The exploration of highly ionic conductive halide electrolytes is actively ongoing. Thus, understanding the relationship between composition and crystal structure can be a critical guide for designing better halide electrolytes, which still remains obscure for reliable prediction.

Rapid discrimination of quality grade of black tea based on near-infrared spectroscopy (NIRS), electronic nose (E-nose) and data fusion.

For the manufacturing and sale of tea, rapid discrimination of overall quality grade is of great importance. However, present evaluation methods are time-consuming and labor-intensive. This study investigated the feasibility of combining advantages of near-infrared spectroscopy (NIRS) and electronic nose (E-nose) to assess the tea quality.

Equivalent Heat Treatments and Mechanical Properties in Cold-Rolled TiNiFe Shape-Memory Alloys.

Heat treatments after cold rolling for TiNiFe shape-memory alloys have been compared. After EBSD analysis and as calculated by the Avrami model and Arrhenius equation, the relationship between the heat-treatment temperature and manufacturing time of TiNiFe alloys is established. Through calculation, it can be found that TiNiFe alloys can obtain similar microstructures under the annealing processes of 823 K for 776 min, 827 K for 37 min, and 923 K for 12.

Inorganic Polysulfide Chemistries for Better Energy Storage Systems.

ConspectusSulfur-based cathode materials have become a research hot spot as one of the most promising candidates for next-generation, high-energy lithium batteries. However, the insulating nature of elemental sulfur or organosulfides has become the biggest challenge that leads to dramatic degradation and hinders their practical application. The disadvantage is more obvious for all-solid-state battery systems, which require both high electronic and ionic migration at the same sites to realize a complete electrochemical reaction.

Challenges and approaches of single-crystal Ni-rich layered cathodes in lithium batteries.

High energy density and high safety are incompatible with each other in a lithium battery, which challenges today's energy storage and power applications. Ni-rich layered transition metal oxides (NMCs) have been identified as the primary cathode candidate for powering next-generation electric vehicles and have been extensively studied in the last two decades, leading to the fast growth of their market share, including both polycrystalline and single-crystal NMC cathodes. Single-crystal NMCs appear to be superior to polycrystalline NMCs, especially at low Ni content (≤60%).

The Universal Super Cation-Conductivity in Multiple-cation Mixed Chloride Solid-State Electrolytes.

As exciting candidates for next-generation energy storage, all-solid-state lithium batteries (ASSLBs) are highly dependent on advanced solid-state electrolytes (SSEs). Here, using cost-effective LaCl and CeCl lattice (UCl -type structure) as the host and further combined with a multiple-cation mixed strategy, we report a series of UCl -type SSEs with high room-temperature ionic conductivities over 10  S cm and good compatibility with high-voltage oxide cathodes. The intrinsic large-size hexagonal one-dimensional channels and highly disordered amorphous phase induced by multi-metal cation species are believed to trigger fast multiple ionic conductions of Li , Na , K , Cu , and Ag .

Hopping Rate and Migration Entropy as the Origin of Superionic Conduction within Solid-State Electrolytes.

Inorganic solid-state electrolytes (SSEs) have gained significant attention for their potential use in high-energy solid-state batteries. However, there is a lack of understanding of the underlying mechanisms of fast ion conduction in SSEs. Here, we clarify the critical parameters that influence ion conductivity in SSEs through a combined analysis approach that examines several representative SSEs (LiYCl, LiHoCl, and LiPSCl), which are further verified in the LiCl-InCl system.

Polyethylene Glycol Functionalized Silicon Nanowire Field-Effect Transistor Biosensor for Glucose Detection.

Accurate monitoring of blood glucose levels is crucial for the diagnosis of diabetes patients. In this paper, we proposed a simple "mixed-catalyzer layer" modified silicon nanowire field-effect transistor biosensor that enabled direct detection of glucose with low-charge in high ionic strength solutions. A stable screening system was established to overcome Debye screening effect by forming a porous biopolymer layer with polyethylene glycol (PEG) modified on the surface of SiNW.

Measurement and the improvement of effective thermal conductivity for a metal hydride bed - a review.

Solid-state hydrogen storage based on metal hydrides is considered a promising method for hydrogen storage. However, the low inherent thermal conductivity of metal hydride powder significantly limits the hydrogenation/dehydrogenation process in the metal hydride bed. Accurate measurement and improvement of the effective thermal conductivity of a hydride bed is of great significance for design of solid-state hydrogen storage devices.