Transmission Mechanism and Logical Operation of Graphene-Doped Poly(vinyl alcohol) Composite-Based Memristor.

Memristors are considered the best candidates for nonvolatile memory and advanced computing technologies, and polymer and two-dimensional (2D) materials have been developed as functional layer materials in memristors with high-performance resistive switching characteristics. In this work, a polymer memristor with a graphene (Gr)-doped poly(vinyl alcohol) (PVA) composite acting as the functional layer was prepared. The memristor device exhibited superior performance with good retention and a comparatively large ON/OFF ratio at room temperature.

Fluorinated Graphene Thermally Conductive Hydrogel with a Solid-Liquid Interpenetrating Heat Conduction Network.

Hydrogels with excellent mechanical flexibility are widely used in flexible electronic devices. However, it is difficult to meet further applications of high-power integrated flexible electronics as a result of their low thermal conductivity. Herein, highly thermally conductive composite hydrogels with a solid-liquid interpenetrating thermal conductivity network are constructed by aromatic polyamide nanofibers (ANF) and fluorinated graphene (FG) reinforced poly(vinyl alcohol) (PVA) and cross-linked by tannic acid (TA) solution immersion to obtain a hydrogel with a double cross-linked network.

Structure, Properties, Preparation, and Application of Layered Titanates.

As a typical cation-exchangeable layered compound, layered titanate has a unique open layered structure. Its excellent physical and chemical properties allow its wide use in the energy, environmental protection, electronics, biology, and other fields. This paper reviews the recent progress in the research on the structure, synthesis, properties, and application of layered titanates.

Ultra-Sleek High Entropy Alloy Tights: Realizing Superior Cyclability for Anode-Free Battery.

The development of Li-free anodes to inhibit Li dendrite formation and provide high energy density Li batteries is highly applauded. However, the lithiophobic interphase and heterogeneous Li deposition hindered the practical application. In this work, a 20 nm ultra-sleek high entropy alloy (HEA, NiCdCuInZn) tights loaded with HEA nanoparticles are developed by a thermodynamically driven phase transition method on the carbon fiber (HEA/C).

Molybdenum/selenium based heterostructure catalyst for efficient hydrogen evolution: Effects of ionic dissolution and repolymerization on catalytic performance.

Transition metal chalcogenides (TMCs) are recognized as highly efficient electrocatalysts and have wide applications in the field of hydrogen production by electrolysis of water, but the real catalytic substances and catalytic processes of these catalysts are not clear. The species evolution of Mo and Se during alkaline hydrogen evolution was investigated by constructing MoSe@CoSe heterostructure. The real-time evolution of Mo and Se in MoSe@CoSe was monitored using in situ Raman spectroscopy to determine the origin of the activity.

Towards sustainable electrochemistry: green synthesis and sintering aid modulations in the development of BaZrYMO (M = Mn, Co, and Fe) IT-SOFC electrolytes.

In this study, BaZrYMO perovskite electrolytes with sintering aids (M = Mn, Co, and Fe) were synthesized by a sustainable approach using spinach powder as a chelating agent and then compared with chemically synthesized BaZrYMO (M = Mn, Co, and Fe) electrolytes for intermediate temperature SOFCs. This is the first example of such a sustainable synthesis of perovskite materials with sintering aids. Structural analysis revealed the presence of a cubic perovskite structure in BaZrYMO (M = Mn, Co, and Fe) samples synthesized by both green and conventional chemical methods.

Unveiling the antibacterial strategies and mechanisms of MoS: a comprehensive analysis and future directions.

Antibiotic resistance is a growing problem that requires alternative antibacterial agents. MoS, a two-dimensional transition metal sulfide, has gained significant attention in recent years due to its exceptional photocatalytic performance, excellent infrared photothermal effect, and impressive antibacterial properties. This review presents a detailed analysis of the antibacterial strategies and mechanism of MoS, starting with its morphology and synthesis methods and focusing on the different interaction stages between MoS and bacteria.

Zn-Shik-PEG nanoparticles alleviate inflammation and multi-organ damage in sepsis.

Sepsis is defined as a life-threatening organ dysfunction caused by excessive formation of reactive oxygen species (ROS) and dysregulated inflammatory response. Previous studies have reported that shikonin (Shik) possess prominent anti-inflammatory and antioxidant effects and holds promise as a potential therapeutic drug for sepsis. However, the poor water solubility and the relatively high toxicity of shikonin hamper its clinical application.

Reshaping carbon-coated MnMoO nanotubes and enhanced sodium storage performance.

MnMoO/C nanotubes are successfully reshaped from micron-sized MnMoO blocks using a simple microwave-combined calcination method with dopamine as both scissors and carbon source. The synthesized MnMoO/C nanotube (MMOC-2) exhibits enhanced sodium storage performance as anodes for half-cell (217 mA h g with 99% coulombic efficiency after 500 cycles) and full-cell (capacity retention of 75% after 100 cycles), which is attributed to the uniquely reshaped nanostructures with abundant active sites, short ion diffusion path and fast charge transfer.

Nonadiabatic molecular dynamics simulations for ultrafast photo-induced ring-opening and isomerization reactions of 2,2-diphenyl-2-chromene.

Nonadiabatic molecular dynamics simulations with a global switching algorithm have been performed at the TD-CAM-B3LYP-D3/def2-SVP level of theory for ultrafast photo-induced ring-opening and isomerization reactions upon S excitation for 2,2-diphenyl-2-chromene (DPC). Both DPC-T and DPC-C conformers undergo ring-opening relaxation and isomerization pathways accompanied with pyran conformation conserved and converted on the S or S states competition and cooperation between C-O bond dissociation and pyran inversion motions. Upon S excitation, the DPC-T mainly relaxes to the T-type conical intersection region and thus yields a higher ring-opening efficiency with a faster S decay and intermediate formation than those of the DPC-C mainly relaxing to C-type conical intersection.

Interface-mediated protein aggregation.

The aggregation of proteins at interfaces has significant roles and can also lead to dysfunction of different physiological processes. The interfacial effects on the assembly and aggregation of biopolymers are not only crucial for a comprehensive understanding of protein biological functions, but also hold great potential for advancing the state-of-the-art applications of biopolymer materials. Recently, there has been remarkable progress in a collaborative context, as we strive to gain control over complex interfacial assembly structures of biopolymers.

A facile and large-scale route to prepare nitrogen/oxygen (N/O) co-doped two-dimensional carbon nanomesh with excellent microwave absorption properties.

Two-dimensional porous carbon materials have been considered good candidates for developing lightweight microwave absorbers because of their low density and tunable dielectric constant. However, large-scale synthesis, with precise control of the microstructure, by a simple method, remains is still a great challenging. Herein, a two-dimensional N/O co-doped carbon nanomesh (NOCN) was prepared via large-scale route by simple carbonization of analogue polyurea (PU) nanosheet consisted of p-phenyldiisocyanate and urea, and the graphitization degree, porous structure, sheet size and the heteroatom doping content could be easily adjusted by controlling carbonization temperature.

Improved Breakdown Strength and Restrained Leakage Current of Sandwich Structure Ferroelectric Polymers Utilizing Ultra-Thin AlO Nanosheets.

Flexible capacity applications demand a large energy storage density and high breakdown electric field strength of flexible films. Here, P(VDF-HFP) with ultra-thin AlO nanosheet composite films were designed and fabricated through an electrospinning process followed by hot-pressing into a sandwich structure. The results show that the insulating ultra-thin AlO nanosheets and the sandwich structure can enhance the composites' breakdown strength (by 24.

Flexible Fluorinated Graphene/Poly(vinyl Alcohol) Films toward High Thermal Management Capability.

Graphene is widely used in heat dissipation, owing to its inherently high in-plane thermal conductivity and excellent mechanical properties. However, its poor cross-plane thermal conductivity limits its use in some electronic applications. The electron distribution of graphene and the interaction with the base material can be greatly altered by introducing F, the most electronegative element, giving fluorinated graphene oxide (FG) with a high thermal conductivity.

Organic Excitonic State Management by Surface Metallic Coupling of Inorganic Lanthanide Nanocrystals.

The ability to harness charges and spins for control of organic excitonic states is critical in developing high-performance organic luminophores and optoelectronic devices. Here we report a facile strategy to efficiently manipulate the electronic energy states of various organic phosphors by coupling them with inorganic lanthanide nanocrystals. We show that the metallic atoms exposed on the nanocrystal surface can introduce strong coupling effects to 9-(4-ethoxy-6-phenyl-1,3,5-triazin-2-yl)-9H-carbazole (OCzT) and some organic chromophores with carbazole functional groups when the organics are approaching the nanocrystals.

Antiferroelectric AgNbO @KH550 Doped PVDF/PMMA Composites with High Energy Storage Performance.

The residual polarization of antiferroelectric ceramics is very small, yet they possess high energy storage density and efficiency. Incorporating antiferroelectric ceramic particles into a polymer matrix is beneficial for improving the energy storage performance of composites. However, excessive amounts of ceramic particles can lead to aggregation within the polymer, resulting in defects and a significant reduction in composite film performance.

Recent Advances in Room-Temperature Phosphorescence Metal-Organic Hybrids: Structures, Properties, and Applications.

Metal-organic hybrid (MOH) materials with room-temperature phosphorescence (RTP) have drawn attention in recent years due to their superior RTP properties of high phosphorescence efficiency and ultralong emission lifetime. Great achievement has been realized in developing MOH materials with high-performance RTP, but a systematic study on MOH materials with RTP feature is lacking. This review highlights recent advances in metal-organic hybrid RTP materials.

Electron density effect of aromatic carboxylic acids in naphthalenediimide-based coordination polymers: from thermal electron transfer and charge transfer to photoinduced electron transfer.

Various naphthalenediimide (NDI) based electron donor-acceptor coordination polymers (D-A CPs) have been constructed and used to explore charge transfer (CT) and electron transfer (ET) behaviors. Up to now, significant progress has been made in the interface contact and electron donor-acceptor ability matching mechanism, while the electronic density effect of the electron donors on the CT and ET behaviors is still not known. Herein, two NDI-based D-A CPs, [Cd(HNDI)(IPA)(HO)] (1) and [Cd(HNDI)(IPA-OH)(HO)] (2), are constructed using an NDI-based ligand and two aromatic carboxylic acid ligands (HNDI = 2,7-bis(3,5-dimethyl) dipyrazol-1,4,5,8-naphthalene tetracarboxydiimide, HIPA = isophthalic acid; and HIPA-OH = 5-hydroxyisophthalic acid).

Advancements in Microwave Absorption Motivated by Interdisciplinary Research.

Microwave absorption materials (MAMs) are originally developed for military purposes, but have since evolved into versatile materials with promising applications in modern technologies, including household use. Despite significant progress in bench-side research over the past decade, MAMs remain limited in their scope and have yet to be widely adopted. This review explores the history of MAMs from first-generation coatings to second-generation functional absorbers, identifies bottlenecks hindering their maturation.

Intrinsic Polarized Electric Field Induces a Storing Mechanism to Achieve Energy Storing Catalysis in V C MXene.

Efficient storage and separation of holes and electrons pose significant challenges for catalytic reactions, particularly in the context of single-phase catalysis. Herein, V C MXene, with its intrinsic polarized electric field, successfully overcomes this obstacle. To enhance hole storage, a multistep etching process is employed under reducing conditions to control the content of surface termination groups, thus exposing more defective active sites.

Superhydrophilic Interconnected Biomass-Based Absorbers Toward High-Speed Evaporation for Solar Steam Generation.

Taking abundant and sustainable solar energy as the only energy source, solar-powered interface evaporation has been regarded as a promising method to alleviate the pressure of freshwater shortage. However, the uptake of clean water from brine is constantly accompanied by evaporation of water and condensation of vapor, which inevitably generates salt solid, preventing further continuous and stable evaporation. The most direct method is to fabricate a photothermal material with salt self-resistance by using the reflux of salt ions.

Bioactivity and antibacterial properties of zinc-doped TaOnanorods on porous tantalum surface.

This paper focuses on the preparation of Zn-doped TaOnanorods on porous tantalum using the hydrothermal method. Porous tantalum is widely used in biomedical materials due to its excellent elastic modulus and biological activity. Porous tantalum has an elastic modulus close to that of human bone, and its large specific surface area is conducive to promoting cell adhesion.

Quenching modification of NiFe layered double hydroxides as efficient and highly stable electrocatalysts for the oxygen evolution reaction.

Nickel- and iron-containing layered double hydroxides (NiFe-LDHs) are prospective electrocatalysts for the oxygen evolution reaction (OER), but they suffer from poor electrical conductivity and inaccessible active sites. Herein, we employ a facile and efficient quenching strategy to modify the morphology and surface characteristics of NiFe-LDHs by rapid cooling in a series of salt solutions. After quenching in a SnCl solution, the modified NiFe-LDHs exhibit a low overpotential of 204 mV at a current density of 10 mA·cm and Tafel slope of 58.