Realization of Tunable Ferroelectricity in Perovskite Crystals for Multidirectional Self-Driven Photodetection.

Halide perovskite ferroelectrics endowed with a distinctive spontaneous polarization effect have been regarded as prospective electroactive materials and are prevalently utilized in solar cells, photoelectric detection, and other domains. Among them, multipolar-axis ferroelectrics featuring multiple equivalent polarization directions are particularly desirable for diverse areas of applications. Nevertheless, the design and regulation of multipolar axis perovskite ferroelectrics remains a significant challenge.