1 results match your criteria: "Freiburg Materials Research Center FMF Albertstraße 21 79104 Freiburg i. Br. Germany krossing@uni-freiburg.de.[Affiliation]"
From mixed group 13 cations [M(AlCp*)] (M = Ga/In/Tl) to an Al cluster.
Chem Sci
October 2022
Albert-Ludwigs-Universität Freiburg, Institute for Inorganic and Analytical Chemistry, Freiburg Materials Research Center FMF Albertstraße 21 79104 Freiburg i. Br. Germany
AlCp*-complexes with transition metals have shown to be highly reactive and enable C-H or Si-H bond activation. Yet, complexes of AlCp* with low-valent main-group metals are scarce. Here, we report the syntheses of [M(AlCp*)][Al(OR)] (R = C(CF)) with M = Ga, In, Tl, which include the first covalent Al-In and Al-Tl bonds.
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