CoZr nanocomposites in a ceramic-metal AlO(OH)/Al matrix with a different Co/Zr ratio and its potential for syngas processing.

We investigated the possibility of synthesizing Co nanoparticles in CoZrH/AlO(OH)/Al ceramic-metal catalysts and controlling the catalytic properties of these nanoparticles in syngas conversion by changing the Co/Zr ratio. The CoZr nanocomposites were obtained from metal powders by mechanochemical activation in a high-energy mill under an argon atmosphere, followed by treatment with hydrogen at high pressure and room temperature. Ceramic-metal catalysts were prepared by mixing the corresponding CoZrH powder nanocomposite (30 wt%) with powdered aluminum (70 wt%), hydrothermal treatment of the mixture and subsequent calcination.

Catalytic co-combustion of biomass and brown coal in a fluidized bed: Economic and environmental benefits.

The work is devoted to the study of combustion of brown coal, pine sawdust, and their mixtures in a fluidized bed of catalyst at 600-750°С. It is shown that an increase in the content of sawdust in a mixture with brown coal leads to an increase in the burnout degree of solid fuel from 94.4% to 99.

Unusual Acid Sites in LSX Zeolite: Formation Features and Physico-Chemical Properties.

The advanced approach for the preparation of the NH form of highly crystalline LSX zeolite under gentle drying conditions (40 °C, membrane pump dynamic vacuum) is discussed. Decationization of this form at moderate temperatures led to the formation of Brønsted acid sites (BASs), whose concentration and strength were characterized by IR spectroscopy. It was found that a maximum concentration of three BASs per unit cell can be achieved at 200 °C prior to the initiation of zeolite structure degradation.

Crystallization of SAPO-11 Molecular Sieves Prepared from Silicoaluminophosphate Gels Using Boehmites with Different Properties.

In this article, we report the results of research the formation of silicoaluminophosphate gels under changing gel aging conditions and the influence of an aluminum source (boehmite), characterized by different properties. The samples of initial gels were characterized by XRF, X-ray diffraction, MAS NMR Al and P, and scanning electron microscopy (SEM). Products of crystallization were characterized by XRF, X-ray diffraction, MAS NMR Al and P, scanning electron microscopy (SEM), N-physical adsorption, and IR spectroscopy with pyridine adsorption.

LaCoCuTiO/KIT-6 perovskites: synthesis and catalytic behavior in syngas conversion to higher alcohols.

Highly dispersed LaCoCuTiO/KIT-6 perovskites were synthesized by the citrate method with inert mesoporous KIT-6 addition. The KIT-6 matrix was removed by dissolution in 7% NaOH aqueous solution. The dispersity of perovskites probably varies depending on the largest cation and its content at the B position of the perovskite ABO3 structure.

Model-Based Performance Analysis of Membrane Reactor with Ethanol Steam Reforming over a Monolith.

Membrane reactors (MR) with an appropriate catalyst are considered to be an innovative and intensified technology for converting a fuel into the hydrogen-rich gas with the simultaneous recovery of high-quality hydrogen. Characteristics of an asymmetric membrane disk module consisting of a gas-tight nanocomposite functional coating (Ni + Cu/NdWO mixed proton-electron conducting nanocomposite) deposited on a gas-permeable functionally graded substrate has previously been extensively studied at lab-scale using MRs, containing the catalyst in a packed bed and in the form of a monolith. The catalytic monolith consisted of a FeCrAl substrate with a washcoat and an Ni + Ru/PrCeZrO active component.

An Experimental Performance Study of a Catalytic Membrane Reactor for Ethanol Steam Reforming over a Metal Honeycomb Catalyst.

The present study deals with the combination of ethanol steam reforming over a monolithic catalyst and hydrogen separation by membrane in a lab-scale catalytic membrane reactor (CMR). The catalyst was comprised of honeycomb thin-walled Fechralloy substrate loaded with Ni + Ru/PrCeZrO active component. The asymmetric supported membrane consisted of a thin Ni-Cu alloy-Nd tungstate nanocomposite dense permselective layer deposited on a hierarchically structured asymmetric support.

Comparative Study of the Photocatalytic Hydrogen Evolution over CdMnS and CdS-β-MnO-MnOOH Photocatalysts under Visible Light.

A series of solid solutions of cadmium and manganese sulfides, CdMnS (x = 0-0.35), and composite photocatalysts, CdS-β-MnO-MnOOH, were synthesized by precipitation with sodium sulfide from soluble cadmium and manganese salts with further hydrothermal treatment at 120 °C. The obtained photocatalysts were studied by the X-ray diffraction method (XRD), UV-vis diffuse reflectance spectroscopy, transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), and N low temperature adsorption.