Elucidating contributions of meteorology and emissions to O variations in coastal city of China during 2019-2022: Insights from VOCs sources.

Elucidating the meteorology and emissions contribution of O variation is a crucial issue for implementing effective measures for O pollution control. We quantified the impacts of meteorology and emissions on O variability during spring and autumn from 2019 to 2022, using multi-year continuous observations. A machine learning (ML)-based de-weathering model revealed that meteorology accounted for a greater proportion of O variability (71.

Quantitative analysis of influencing factors to aerosol pH and its responses to PM and O pollution in a coastal city.

Aerosol acidity (pH) plays an important role in the multiphase chemical processes of atmospheric particles. In this study, we demonstrated the seasonal trends of aerosol pH calculated with the ISORROPIA-II model in a coastal city of southeast China. We performed quantitative analysis on the various influencing factors on aerosol pH, and explored the responses of aerosol pH to different PM and O pollution levels.

Changing ozone sensitivity in Fujian Province, China, during 2012-2021: Importance of controlling VOC emissions.

In the troposphere, ozone (O) formation can be limited by NOx, VOCs, or both, complicating efforts to reduce O by controlling its precursors. This study used formaldehyde (HCHO) data and nitrogen dioxide (NO) data from the Ozone Monitoring Instrument (OMI) to analyze O formation sensitivity in Fujian from 2012 to 2021. Over the past decade, an 8.

The observation of atmospheric HONO by wet-rotating-denuder ion chromatograph in a coastal city: Performance and influencing factors.

Due to the significance of atmospheric HONO as a reservoir for radicals and the presence of substantial unknown sources of HONO, there is a pressing need for accurate and consistent measurement of its concentration. In this study, we compared the measurements obtained from the monitor for aerosols and gases in ambient air (MARGA) based on wet chemical method with those from the incoherent broadband cavity-enhanced absorption spectroscopy (IBBCEAS) based on optical method to assess the suitability of the MARGA instrument for accurate HONO detection. The diurnal patterns obtained by the two instruments are similar, with peaks at 8 a.

Meteorological impacts on the unexpected ozone pollution in coastal cities of China during the unprecedented hot summer of 2022.

Surface ozone pollution under climate warming has become a serious environmental issue. In the summer of 2022, abnormal warming spread over most of the Northern Hemisphere and resulted in the abnormal increase in O concentrations. In this study, we focused on the coastal cities in China and investigated the O trends in July during 2015 to 2022.

Atmospheric oxidation capacity and O formation in a coastal city of southeast China: Results from simulation based on four-season observation.

The pollution of atmospheric ozone in China shows an obvious upward trend in the past decade. However, the studies on the atmospheric oxidation capacity and O formation in four seasons in the southeastern coastal region of China with the rapid urbanization remain limited. Here, a four-season field observation was carried out in a coastal city of southeast China, using an observation-based model combining with the Master Chemical Mechanism, to explore the atmospheric oxidation capacity (AOC), radical chemistry, O formation pathways and sensitivity.

Photochemistry in the urban agglomeration along the coastline of southeastern China: Pollution mechanism and control implication.

The concentrations of ground-level ozone (O) in China have undergone a rapid increase in recent years, resulting in adverse impacts on the air quality and climate change. However, limited research has been conducted on the coastal urban agglomerations with increasingly serious O pollution. Therefore, in order to better understand in situ photochemistry, comprehensive field observations of O and its precursors, coupled with the model simulation, were conducted in autumn of 2019 at six sites in an urban agglomeration along the coastline of southeastern China.

The effect of nitrous acid (HONO) on ozone formation during pollution episodes in southeastern China: Results from model improvement and mechanism insights.

Two ozone (O) processes, summer episode dominated by local production and autumn episode dominated by regional transport, were chosen to investigate the role of HONO in different pollution processes. Meteorological conditions, diurnal variation of O, potential source contribution factor (PSCF) analysis, concentration weighted trajectory (CWT) models, and the distribution of the eight-hour maximum values of O on mainland China all prove that summer O was mainly locally generated while autumn O episode was more susceptible to regional transport. The gaps between observations and simulation results with the default HONO chemistry in Master Chemical Mechanism (MCM) of Observation Based Model (OBM) were higher in summer episode (0.

An approach of multi-element fusion method for harmful algal blooms prediction.

The harmful algal blooms (HABs) are an issue of concern for water management worldwide. Effective strategies for monitoring and predicting of HAB spatio-temporal variability in waterbodies are more essential. To promote the monitoring and predicting of HABs, we proposed a multi-element fusion prediction (MEFP) method for cyanobacteria bloom.

Pollution mechanisms and photochemical effects of atmospheric HCHO in a coastal city of southeast China.

Formaldehyde (HCHO) is a vital reactive carbonyl compound, which plays an important role in the photochemical process and atmospheric oxidation capacity. However, the current studies on the quantification of HCHO impacts on atmospheric photochemistry in southeast coastal areas of China with an obvious upward trend of ozone remain scarce and unclear, thus limiting the full understanding of formation mechanism and control strategy of photochemical pollution. Here, systematic field campaigns were conducted at a typical coastal urban site with good air quality to reveal HCHO mechanism and effects on O pollution mechanism during spring and autumn, when photochemical pollution events still frequently appeared.

Secondary organic aerosol of PM in a mountainous forest area in southeastern China: Molecular compositions and tracers implication.

Secondary organic aerosol (SOA) plays an important role in global climate change and air quality. PM (particles with aerodynamic diameters ≤2.5 μm) samples were collected at a mountainous forest site (Mt.

Enhanced fluorescence of terbium with thiabendazole and application in determining trace amounts of terbium and thiabendazole.

In this paper, a simple, rapid and sensitive fluorescence method based on the formation of terbium (Tb) complex has been developed for the rapid detection of Tb in water. The fluorescence sensor has been studied by using terbium complexed with thiabendazole (TBZ) while acetonitrile (MeCN) as solvent. The complex was made up of TBZ as small-molecule ligand and Tb as central ion.

A label-free fluorescent biosensor for ultratrace detection of terbium (ш) based on structural conversion of G-quadruplex DNA mediated by ThT and terbium (ш).

In this paper, a novel label-free fluorescent biosensor for terbium (ш) (Tb(3+)) was proposed based on structural conversion of G-quadruplex DNA mediated by Thioflavin T (ThT) and Tb(3+). In the presence of K(+), ThT could bind to K(+)-stabilized parallel G-quadruplex, giving rise to high fluorescence intensity. Upon the addition of Tb(3+), Tb(3+) could competitively bind to parallel G-quadruplex leading to the structural change, which resulted in fluorescence decrease.

Effects of urbanization on gaseous and particulate polycyclic aromatic hydrocarbons and polychlorinated biphenyls in a coastal city, China: levels, sources, and health risks.

Gas/particle distributions of polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) were measured in Xiamen from May 2009 to March 2010 to evaluate the impacts of urbanization on the fate of persistent organic pollutants (POPs) in the atmospheric environment. In a newly developing area (NDA), the concentrations of 16 PAHs (gas + particle) were significantly higher than that a historically urbanized area (HUA) (p value <0.05), while the trend of 28 PCBs was reversed.