Selective Oxidation of Cyclohexene over the Mesoporous H-Beta Zeolite on Copper/Nickel Bimetal Catalyst in Continuous Reactor.

The copper/nickel-metal on commercial H-Beta zeolite supports was synthesized with different wt % (Ni) of 5, 10, 15, and 20, and was used in the cyclohexene epoxidation process. The synthesized catalyst has been used in a continuous reactor for the cyclohexene epoxidation process, with mild conditions and HO as an oxidant. The catalytic performance was ascertained by adjusting parameters such as the temperature, pressure, WHSV, reaction time, and solvents.

Liquid phase selective oxidation of veratryl alcohol to veratraldehyde using pure and Mg-doped copper chromite catalysts.

Mg-doped copper chromite (CuCrO) nanocomposites were synthesised through conventional technique. The pure and doped CuCrMg O ( = 0.00-0.

Sustainable biofuel synthesis from non-edible oils: a mesoporous ZSM-5/Ni/Pt catalyst approach.

This work examines the hydrodeoxygenation (HDO) activity of non-edible oils using a high surface area catalyst. The HDO activity was thoroughly examined and contrasted using the high surface area catalyst Ni/Pt-ZSM-5 as well as other supports like MCM-48 and H-beta. Ni/Pt bimetals supported on mesoporous ZSM-5 were created reverse order impregnation to facilitate HDO of non-edible oils.

Ni-Fe bimetallic catalysts with high dispersion supported by SBA-15 evaluated for the selective oxidation of benzyl alcohol to benzaldehyde.

A wetness impregnation method was used to impregnate the substrate with a substantial quantity of oleic acid together with a metal precursor, leading to significantly dispersed Ni-Fe bimetallic catalysts based on mesoporous SBA-15. Using a wide variety of characterization methods, such as XRD, BET, and TEM Analysis, the physiochemical properties of the catalyst were determined. The addition of the metal does not have any effect on the structural characteristics of the SBA-15 catalyst, as validated by transmission electron microscopy (TEM), which shows that the prepared SBA-15 supported catalyst has a hexagonal mesoporous structure.

Comparative risk assessment studies estimating the hazard posed by long-term consumption of PPCPs in river water.

This study assesses the risk due to Emerging Contaminants (ECs), present in Indian rivers - Ganga (650 million inhabitants), Yamuna (57 million inhabitants), and Musi (7,500,000 inhabitants), 13 ECs in total, have been used for risk assessment studies. Their concentrations (e.g.

Isomerization of C and C through Ionic Liquids Supported by a Fe/SBA-15 Catalyst.

Isomerization is extensively utilized in the petroleum industry, and this study demonstrates an energy-efficient process utilizing an ionic liquid catalyst. 1-Ethyl-3-methylimidazolium triflate [Emim][TFO] as an ionic liquid was immobilized on solid support Fe/SBA-15. Variants of the catalyst were developed with the Fe constant at 5% and different ratios of ionic liquid.

Long-term impacts of climate change on coastal and transitional eco-systems in India: an overview of its current status, future projections, solutions, and policies.

Urbanization and industrial development are increasing rapidly. These are accompanied by problems of population explosion, encroachment of agricultural, and construction lands, increased waste generation, effluent release, and escalated concentrations of several greenhouse gases (GHGs) and pollutants in the atmosphere. This has led to wide-scale adverse impacts.

Complexity of the Role of Various Site-Specific and Selective Sudlow Binding Site Drugs in the Energetics and Stability of the Acridinedione Dye-Bovine Serum Albumin Complex: A Molecular Docking Approach.

Molecular docking (Mol.Doc) techniques were employed to ascertain the binding affinity of two resorcinol-based acridinedione dyes (ADR1 and ADR2) with the widely studied globular protein Bovine Serum Albumin (BSA) in the presence of site-selective binding drugs by Autodock Vina 4.2 software.

Microplastic contamination in commercial fish species in southern coastal region of India.

Due to its potential impact on food safety and human health, commercial species that have been contaminated with microplastics (MPs) are drawing more attention on a global scale. This study investigated the possibility of MPs contamination in different marine fish species with substantial commercial value that was captured off the south coast of India, from Adyar and Ennore regions. Over the course of six months, from October 2019 to March 2020, 220 fish were examined.

A fluorescence approach on the investigation of urea derivatives interaction with a non-PET based acridinedione dye-beta Cyclodextrin (β-CD) complex in water: Hydrogen-bonding interaction or hydrophobic influences or combined effect?

Photophysical studies of resorcinol based acridinedione dyes with beta Cyclodextrin (β-CD) in the presence of urea (U) and tetramethylurea (TMU) were carried out in water. A marked variation in the absorption spectra of dye-β-CD complex was found to be more significant in the case of U rather in TMU. Interestingly, the role of urea on the excited state behavior of dye-β-CD complex is found to be entirely different from that of TMU.

Fluorescence and quantum mechanical approach on the interaction of amides and their role on the stability and coexistence of the rotamer conformations of L-tryptophan in aqueous solution.

Photophysical investigation on the fluorescence decay characteristics of L-tryptophan and a derivative N-acetyl-L-tryptophanamide (NATA) with alkyl amides were carried out in water. L-tryptophan exists in the zwitterionic form and exhibits a biexponential lifetime which is correlated to the existence of rotamer structures. Addition of formamide (F) and dimethylformamide (DMF) results in a decrease in the fluorescence lifetime and its proportion of the most stable structure of L-tryptophan wherein acetamide (ACM) results in an increase of the same.

Competitive hydrogen bonding influences of fluorophore- urea-adenine system in water: Photophysical and photochemical approaches.

Photophysical and photochemical investigation of photoinduced electron transfer (PET)-based acridinedione dye (ADR1) with urea in the presence of a nitrogenous base (adenine) were carried out in water. Urea suppresses the PET resulting in a fluorescence enhancement and the extent of binding is correlated and governed by the number of urea molecules surrounding the close vicinity of dye. On the contrary, adenine forms a true 1:2 complex with dye.

Electrostatic Investigation of 4-Dicyanomethylene-2,6-dimethyl-4-pyran (DDP) Dye with Amide Derivatives in Water.

Cyclic voltammetry (CV) studies of 4-dicyanomethylene-2,6-4-pyran (DDP) dye with alkyl-substituted amides were carried out in an aqueous solution. Formamide and substituted amide interaction with DDP dye were characterized by fluorescence spectral techniques in an aqueous solution, but the electrochemical nature and the interaction at the interface region between dye-amide remains largely unexplored. The introduction of formamide to DDP dye exhibits an increase in the peak current accompanied with potential values gradually shifting more toward a less positive region.