Structural and functional analysis of rhizospheric bacterial diversity in the Pranmati basin, Himalayan critical zone observatory.

The study explores the structural and functional dynamics of rhizospheric bacterial diversity in the Pranmati basin, focusing on their ecological significance, diversity, and functional roles across dominant vegetation types; Rhododendron arboreum, Myrica esculenta, and Quercus leucotrichophora. The research provides critical insights into soil health and ecosystem functioning by analysing rhizospheric soil properties among the selected vegetations. The research findings reveal that Myrica esculenta exhibits the highest root colonization (95.

Click Chemistry for the Generation of Combination of Triazole Core and Thioether Donor Site in Organosulfur Ligands: Applications of Metal Complexes in Catalysis.

During the last two decades, organosulfur compounds have been used in the field of transition metal catalysis. Some of such compounds are known for their ability to withstand their exposure to air and moisture. These compounds are very important ligands.

Use of modified chitosan as bitumen modifier and its impact on rheological properties in bitumen modification.

Conventional bitumen is a viscoelastic material composed of asphaltene and maltene. It is prepared by air-blowing, but this approach makes the bitumen more brittle and susceptible to temperatures. To decrease the temperature susceptibility, synthetic polymers or additives are used to make polymer-modified bitumens.

Catalytic system having an organotellurium ligand on graphene oxide: immobilization of Pd(0) nanoparticles and application in heterogeneous catalysis of cross-coupling reactions.

First heterogeneous catalytic system, having a covalently linked hybrid bidentate organotellurium ligand [, PhTe-CH-CH-NH] on the surface of graphene oxide, has been synthesized with immobilized and stabilized Pd(0) nanoparticles. To the best of our knowledge, it is the first such catalytic system in which a heterogenized organotellurium ligand has been used. It has been well-characterized using different physicochemical characterization techniques P-XRD, XPS, HR-TEM, EELS, FE-SEM, EDX, TGA, BET surface area analysis, FT-IR spectroscopy, and Raman spectroscopy.

Understanding adsorption selectivity in zirconium-pillared clays for biogas upgradation: the role of metal/clay ratio.

Biogas, as a sustainable energy source, encounters challenges in practical applications due to impurities, notably carbon dioxide (CO), and nitrogen (N). This study investigates the effect of metal/clay ratio on the adsorption selectivity of porous zirconium-pillared clay adsorbents for biogas upgradation. Comprehensive analyses including nitrogen adsorption/desorption, X-ray diffraction (XRD), and Fourier-transform infrared spectroscopy (FTIR) were conducted to evaluate the physicochemical properties.

Fabrication of magnetite/GO/potassium copper hexacyanoferrate nanocomposite for removal of radioactive cesium ions.

Metal hexacyanoferrates (MHCF) are a class of inorganic adsorbents used for wastewater management due to the presence of interstitial sites for capturing heavy metal ions. In present work, we are reporting the synthesis of magnetic nanocomposite of FeO/graphene oxide/potassium copper hexacyanoferrate via wet chemical and coprecipitation approach. Potassium copper hexacyanoferrate (KCuHCF) and Graphene oxide (GO) both are marvelous adsorbents but their nano-size becomes a major obstacle in their separation process after the adsorption of the radionuclides.

Organosulphur and organoselenium compounds as ligands for catalytic systems in the Sonogashira coupling.

Sonogashira coupling is a reaction of aryl/vinyl halides with terminal alkynes. It is used for the synthesis of conjugated enynes. Generally, copper (Cu) is required as a mediator for this reaction.

Assessment of Black Carbon, optical properties and aerosol radiative forcing at Pranmati basin Himalayan critical zone observatory.

The study aimed to understand the optical properties of Black Carbon (BC) and radiative forcing over a data deficient Himalayan region focusing on critical zone observatory employing ground-based measurements by Aethalometer for BC and satellite retrieval techniques for optical properties during mid-May-June 2022 and January-May 2023. BC mass concentration ranged from 0.18 to 4.

Oxidative desulfurization of fuels using alcohol-based DESs.

The presence of sulfur-containing compounds in fuel oil has become a major global issue due to their release of toxic sulfur dioxide. Hydrodesulfurization is a commonly used method for removing sulfur from fuel. However, new desulfurization techniques have been developed recently as hydrodesulfurization (HDS) is ineffective in removing refractory sulfur, e.

Potential of ionic liquids as emerging green solvent for the pretreatment of lignocellulosic biomass.

Lignocellulosic biomass is available in abundance as a renewable resource, but the major portion of it is often discarded as waste without utilizing its immense potential as an alternative renewable energy resource. To overcome recalcitrance of lignocellulosic biomass, various pretreatment methods are applied to it, so that the complex and rigid polymeric structure can be broken down into fractions susceptible for enzymatic hydrolysis. Effective and efficient biomass processing is the goal of pretreatment methods, but none of the explored pretreatment methods are versatile enough to fulfil the requirement of biomass processing with greater flexibility in terms of operational cost and desired output efficiency.

Co-pyrolysis of orange peel and eggshell for oxygenated rich composite: Process optimization with response surface methodology.

Co-pyrolysis of orange peel and chicken eggshell was performed for the synthesis of the composite, a co-pyrolysis technique used to promote natural fabrication and to allow the raw material elemental combination effect and the preparatory conditions such as pyrolysis temperature, residence time, and eggshell/orange peel mixing ratio, to be optimized with the response surface methodology through Box-Behnken Design(BBD). BBD involved a randomized series of 17 experimental runs, and the best optimal conditions were found with a pyrolysis temperature of 300 °C, a residence time of 1 h, and 0.5 as the mixing ratio.

Polycyclic Aromatic Hydrocarbons (PAHs) in aquatic ecosystem exposed to the 2020 Baghjan oil spill in upper Assam, India: Short-term toxicity and ecological risk assessment.

This study focuses on the short-term contamination and associated risks arising from the release of Polycyclic Aromatic Hydrocarbons (PAHs) due to the 2020 Baghjan oil blowout in upper Assam, India. Shortly after the Baghjan oil blowout, samples were collected from water, sediment, and fish species and examined for PAHs contents. The results of the analysis revealed ΣPAHs concentrations ranged between 0.

Pharmaceutically active compounds in aqueous environment: recent developments in their fate, occurrence and elimination for efficient water purification.

The existence of pharmaceutically active compounds (PhACs) in the water is a major concern for environmentalists due to their deleterious effects on living organisms even at minuscule concentrations. This review focuses on PhACs such as analgesics and anti-inflammatory compounds, which are massively excreted in urine and account for the majority of pharmaceutical pollution. Furthermore, other PhACs such as anti-epileptics, beta-blockers and antibiotics are discussed because they also contribute significantly to pharmaceutical pollution in the aquatic environment.

Phytoremediation of Heavy Metal Contaminated Soil Using Bidens pilosa: Effect of Varying Concentrations of Sophorolipids.

The current study investigates the impact of biosurfactant (sophorolipids, SL) concentrations (0.1 to 1 g kg) on the removal of cadmium (29 mg kg) from soil using Bidens pilosa. The results showed that increasing concentrations of SL increased the plant biomass.

Surfactants in water and wastewater (greywater): Environmental toxicity and treatment options.

Surfactant, an emerging pollutant present in greywater, raises the toxicity levels in the water body. Soap, detergent, and personal care items add surfactant to greywater. Due to excessive washing and cleaning procedures brought on by the COVID-19 pandemic, the release of surfactants in greywater has also increased.

Modified hydrophobic and oleophilic polyurethane sponge for oil absorption with MIL-53.

A hydrophobic composite sponge (HPCS) is developed for the first time using the dip coating and drying method in an effort to remove organic contaminants like toluene and various oils from water. We employed a polyurethane (PU) sponge, which is reasonably priced, easily accessible, high mechanical strength and a suitable porous substrate on which the hydrophobic composite of MIL-53(Al) along with PDMS was anchored. A crystalline metal organic framework (MOF), MIL-53(Al), with adjustable porosity, functionality, and hydrophobicity is used for oil absorption.

Immobilized laccase: an effective biocatalyst for industrial dye degradation from wastewater.

Environmental concerns due to the release of industrial wastewater contaminated with dyes are becoming more and more intense with the increasing industrialization. Decolorization of industrial effluents has become the top priority due to the continuous demand for color-free discharge into the receiving water bodies. Different dye removal techniques have been developed, among which biodegradation by laccase enzyme is competitive.

Modeling enablers of supply chain decarbonisation to achieve zero carbon emissions: an environment, social and governance (ESG) perspective.

Climate change is the greatest threat to our planet and way of life. There is an immediate need of decarbonisation and a push for a smooth transition to a world with no net carbon emissions. To achieve sustainability, fast-moving consumer goods (FMCG) firms are increasing their efforts to reduce their carbon footprint across their supply chains.

Assessment of implementation barriers of blockchain technology in public healthcare: evidences from developing countries.

The widespread use of Blockchain technology (BT) in nations that are developing remains in its early stages, necessitating a more comprehensive evaluation using efficient and adaptable approaches. The need for digitalization to boost operational effectiveness is growing in the healthcare sector. Despite BT's potential as a competitive option for the healthcare sector, insufficient research has prevented it being fully utilised.

Role of Root Exudates on the Soil Microbial Diversity and Biogeochemistry of Heavy Metals.

Due to extensive industrialization and escalation in pollution, the world is facing problems related to soil heavy metal pollution. The traditional ways of soil remediation are neither feasible nor cost-effective in most of the real-world scenarios, where metal concentration is relatively low in soil. Therefore, phytoremediation using plants and plant secretions to remediate heavy metal-contaminated soil is recently getting more attention.

Psychological well-being of young adults during COVID-19 pandemic: Lesson learned and future research agenda.

Psychological and mental well-being has become a topic of concern worldwide after the hit of the COVID-19 pandemic. It has triggered enormous global health care vulnerabilities and resulted in full and partial lockdowns to prevent the new case. This research study provides a comprehensive overview of the published international scientific studies on the effect of COVID-19 on the psychological well-being of young adults.

Enhanced adsorptive removal of hexavalent chromium in aqueous media using chitosan-modified biochar: Synthesis, sorption mechanism, and reusability.

Hexavalent chromium (Cr(VI)) is deemed a priority contaminant owing to its carcinogenicity, teratogenicity, and mutagenicity towards flora and fauna. A novel Chitosan-modified Mimosa pigra biochar (CMPBC) was fabricated and the efficiency of Cr(VI) oxyanion removal in aqueous systems was compared with the pristine biochar. The instrumental characterization of X-ray photoelectron spectroscopy (XPS), and Fourier transform infrared spectroscopy (FT-IR) confirmed the amino modification of MPBC when treated with chitosan.