Polyoxometalate steric hindrance driven chirality-selective separation of subnanometer carbon nanotubes.

Subnanometer single-chirality single-walled carbon nanotubes (SWCNTs) are of particular interest in multiple applications. Inspired by the interdisciplinary combination of redox active polyoxometalates and SWCNTs, here we report a cluster steric hindrance strategy by assembling polyoxometalates on the outer surface of subnanometer SWCNTs electron transfer and demonstrate the selective separation of monochiral (6,5) SWCNTs with a diameter of 0.75 nm by a commercially available conjugated polymer.

Atomic origins of the strong metal-support interaction in silica supported catalysts.

Silica supported metal catalysts are most widely used in the modern chemical industry because of the high stability and tunable reactivity. The strong metal-support interaction (SMSI), which has been widely observed in metal oxide supported catalysts and significantly affects the catalytic behavior, has been speculated to rarely happen in silica supported catalysts since silica is hard to reduce. Here we revealed at the atomic scale the interfacial reaction induced SMSI in silica supported Co and Pt catalysts under reductive conditions at high temperature using aberration-corrected environmental transmission electron microscopy coupled with electron energy loss spectroscopy.

A Highly Strained Phase in PbZrTiO Films with Enhanced Ferroelectric Properties.

Although epitaxial strain imparted by lattice mismatch between a film and the underlying substrate has led to distinct structures and emergent functionalities, the discrete lattice parameters of limited substrates, combined with strain relaxations driven by film thickness, result in severe obstructions to subtly regulate electro-elastic coupling properties in perovskite ferroelectric films. Here a practical and universal method to achieve highly strained phases with large tetragonal distortions in Pb-based ferroelectric films through synergetic effects of moderately (≈1.0%) misfit strains and laser fluences during pulsed laser deposition process is demonstrated.

Synthesis of small Ni-core-Au-shell catalytic nanoparticles on TiO by galvanic replacement reaction.

We report the first preparation of small gold-nickel (AuNi) bimetallic nanoparticles (<5 nm) supported on titania by the method of galvanic replacement reaction (GRR), evidenced by the replacement of Ni atoms by Au atoms according to the stoichiometry of the reaction. We showed that this preparation method allowed not only the control of the gold and nickel contents in the samples, but also the formation of small bimetallic nanoparticles with strained core-shell structures, as revealed by aberration-corrected scanning transmission electron microscopy in combination with energy-dispersive X-ray spectroscopy mapping. The catalytic characterization by the probe reaction of semi-hydrogenation of butadiene showed that the resulting nickel-based nanocatalysts containing a small amount of gold exhibited higher selectivity to butenes than pure nickel catalysts and a high level of activity, closer to that of pure nickel catalysts than to that of pure gold catalysts.

Theoretical study of D-A'-π-A/D-π-A'-π-A triphenylamine and quinoline derivatives as sensitizers for dye-sensitized solar cells.

We have designed four dyes based on D-A'-π-A/D-π-A'-π-A triphenylamine and quinoline derivatives for dye-sensitized solar cells (DSSCs) and studied their optoelectronic properties as well as the effects of the introduction of alkoxy groups and thiophene group on these properties. The geometries, single point energy, charge population, electrostatic potential (ESP) distribution, dipole moments, frontier molecular orbitals (FMOs) and HOMO-LUMO energy gaps of the dyes were discussed to study the electronic properties of dyes based on density functional theory (DFT). And the absorption spectra, light harvesting efficiency (LHE), hole-electron distribution, charge transfer amount from HOMO to LUMO ( ), index, index, index and exciton binding energy ( ) were discussed to investigate the optical and charge-transfer properties of dyes by time-dependent density functional theory (TD-DFT).

A review on strategies for the fabrication of graphene fibres with graphene oxide.

Graphene fibres have been recognized as ideal building blocks to make advanced, macroscopic, and functional materials for a variety of applications. Direct fabrication of graphene fibres with ideal graphene sheets is still far from reality due to the weak intermolecular bonding between graphene sheets. In contrast, the construction of graphene oxide fibres by following a reduction process is a common compromise.