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Interaction of glutathione and sodium selenite in vitro investigated by electrospray ionization tandem mass spectrometry.

J Biochem

May 2008

Department of Chemistry of Yanbian University, Key Laboratory of Organism Functional Factor of the Changbai Mountain, Ministry of Education Yanji, 133002, China.

Sheng-Yun Cui Hua Jin Seung-Jin Kim Avvaru Praveen Kumar Yong-Ill Lee

Selenite has been found to be an active catalyst for the oxidation of sulphhydryl compounds, such as glutathione (GSH). Considering the biological importance of GSH oxidation and the implication of sulphhydryl compounds in selenium poisoning and other biological activities, more information on selenite oxidation of GSH in enzyme-free conditions is desirable. Herein, we describe glutathione and sodium selenite simply mixed in aqueous solutions.

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