Mechanofluorochromic behaviors and data security protection properties of salicylaldimine-based difluoroboron complexes with different aryl substituents.

To further explore the relationship between aryl substituents and mechanofluorochromic (MFC) behaviors, four salicylaldimine-based difluoroboron complexes (ts-Ph BF, ts-Ph-NA BF, ts-2NA BF, and ts-triphenylamine [TPA] BF), including aromatic substituents with different steric hindrance effects, were designed and successfully synthesized. Four complexes with twisted molecular conformation displayed intramolecular charge transfer and aggregation-induced emission properties. Under external mechanical stimuli, the as-synthesized powders of ts-Ph BF, ts-Ph-NA BF, and ts-TPA BF exhibited redshift fluorescence emission behaviors, and ts-Ph BF and ts-TPA BF could be recovered to original shifts by fuming, but ts-Ph-NA BF displayed irreversible switching.

Organic matter protection by kaolinite over bio-decomposition as suggested by lignin and solvent-extractable lipid molecular markers.

The formation of organo-mineral complexes is essential in organic matter (OM) stabilization. However, limited studies have been conducted to systematically examine the mineral influence on the decomposition of plant residuals at a molecular level. In this study, pine needles and chestnut leaves were mixed with kaolinite at the weight ratio of 5:1.