Structure-Property Correlation in Ba/Sr-Ca-Mg-Zn-Si-Al-O Glass: Elucidation by Experimental and Molecular Dynamics Simulation Study.

Broad band transmitting glasses from visible to mid-infrared with good mechanical strength, chemical durability, glass-forming ability, and thermal stability are preferred for optics and laser technology applications. Generally, low phonon energy glasses possess an extended transmission cutoff toward mid-infrared, but at the same time, retention of other desired properties is challenging for the researchers. In this work, we have shown that mixed alkaline earth (Ba/Sr) would have the potential to improve overall glass properties while retaining its low phonon energy when CaO is partially substituted by BaO/SrO in calcium magnesium zinc silica-aluminate (CMZSA) glass.

Zinc Oxide Nanoparticles Incorporated in Poly-Hydroxyethyl Methacrylate/Acrylamide Membrane Trigger the Key Events of Full-Thickness Wound Healing in a Rabbit Model.

Zinc oxide nanoparticles are known to possess anti-inflammatory, antibacterial, and antiseptic properties and find wide application in the preparation of topical ointments. Wound dressings in the form of hydrogels can replenish the wound microenvironment to aid the healing process in a multidimensional way. We have fabricated a composite hydrogel using 1-3 wt.

Evaluation of acute and subacute dermal toxicity of antibacterial bioactive glass-infused surgical cotton gauze in Wistar rats.

Mesoporous bioactive glass, with its versatile characteristics and morphology, holds significant potential as an ideal hemostatic material. However, limited data is available regarding its toxicity levels. Consequently, this research intends to assess the acute and repeated dose dermal toxicity of Mesoporous antibacterial bioactive glass microsphere impregnated nonwoven surgical cotton gauze (MABGmscg) dressing in albino Wistar rats, following the standards set by the Organization for Economic Cooperation and Development.

Role of in-situ electrical stimulation on early-stage mineralization and in-vitro osteogenesis of electroactive bioactive glass composites.

Bioactive glass (BAG) has emerged as an effective bone graft substitute due to its diverse qualities of biocompatibility, bioactivity, osteoblast adhesion and enhanced revascularization. However, inferior osteogenic capacity of BAG compared to autologous bone grafts continues to limiting it's wide-spread clinical applications towards repairing of bone fractures and healing. In this study, we have fabricated BAG composites with 0.

Highly sensitive and selective rGO-LaFeO nanocomposite based formaldehyde sensors towards air quality monitoring.

Formaldehyde (HCHO), a ubiquitous volatile organic compound and recognized human carcinogen, is extensively used in industrial applications such as resin and adhesive production. Even minimal exposure to HCHO can induce serious health effects, including respiratory distress and dermal irritation. Thus, the advancement of highly sensitive and selective sensors for HCHO detection is imperative for safeguarding environmental and indoor air quality.

Influence of intrinsic spin ordering in LaSrCoFeO and BaSrCoFeO towards electrocatalysis of oxygen redox reaction in solid oxide cell.

The redox reaction of oxygen (OER & ORR) forms the rate determining step of important processes like cellular respiration and water splitting. Being a spin relaxed process governed by quantum spin exchange interaction, QSEI (the ground triplet state in O is associated with singlet oxygen in HO/OH), its kinetics is sluggish and requires inclusion of selective catalyst. Functionality and sustainability of solid oxide cell involving fuel cell (FC) and electrolyzer cell (EC) are also controlled by ORR (oxygen redox reaction) and OER (oxygen evolution reaction).

Unraveling the interplay of common groundwater ions in arsenic removal by sulfide-modified nanoscale zerovalent iron.

Sulphidation of nZVI (S-nZVI) has shown to significantly improve the arsenic removal capacity of nZVI, concurrently modifying the sequestration mechanism. However, to better apply S-nZVI for groundwater arsenic remediation, the impact of groundwater coexisting ions on the efficacy of arsenic uptake by S-nZVI needs to be investigated. This present study evaluates the potential of S-nZVI to remove arsenic in the presence of typical groundwater coexisting ions such as Cl, HA, HCO, PO and SO through batch adsorption experiments.

Enhanced Triethylamine Detection at Room Temperature Using a Layered MoS Nanosheet-Coated PPy Nanorod: A Comprehensive Study.

The rapid and reliable detection of triethylamine (TEA), a toxic, explosive, volatile organic compound at room temperature, is highly significant for food safety, environmental, and human health monitoring. This manuscript reports a layered molybdenum disulfide (MoS) nanosheet-coated polypyrrole (PPy) nanorod-based heterostructure sensor (MsPy) which offers superior sensing properties toward TEA at room temperature (25 °C). Herein, different MsPy nanocomposites were synthesized, followed by a controlled sulfidation reaction through dissolution, diffusion, and regrowth mechanisms.

Stimulated Full-Thickness Cutaneous Wound Healing with Bioactive Dressings of Zinc and Cobalt Ion-Doped Bioactive Glass-Coated Eggshell Membranes in a Diabetic Rabbit Model.

Eggshell membrane-based biomedical applications have recently received great attention for their wound-healing properties. However, there are limited studies on diabetic wound healing. In this regard, we devised four types of composite eggshell membrane mats with nanoscale coatings of bioactive glass/Zn/Co-doped bioactive glass (ESM + BAG, ESM + ZnBAG, ESM + CoBAG, and ESM + ZnCoBAG) as wound-dressing materials for chronic nonhealing diabetic wounds.

H-Glass Supported Hybrid Gold Nano-Islands for Visible-Light-Driven Hydrogen Evolution.

Flat panel reactors, coated with photocatalytic materials, offer a sustainable approach for the commercial production of hydrogen (H) with zero carbon footprint. Despite this, achieving high solar-to-hydrogen (STH) conversion efficiency with these reactors is still a significant challenge due to the low utilization efficiency of solar light and rapid charge recombination. Herein, hybrid gold nano-islands (HGNIs) are developed on transparent glass support to improve the STH efficiency.

Tungsten-based Lindqvist and Keggin type polyoxometalates as efficient photocatalysts for degradation of toxic chemical dyes.

Photocatalytic dye degradation employing polyoxometalates (POMs) has been a research focus for several years. We report the facile synthesis of tungsten-based Lindqvist and Keggin-type POMs that degrade toxic chemical dyes, methyl orange (MO) and methylene blue (MB), respectively. The Lindqvist POM, sodium hexatungstate, NaWO, degrades MO under 100 W UV light irradiation within 15 min, whereas the Keggin POM, AgPWVO, degrades MB under 20 W visible light source within 180 min.

Development of the SbOCl@NbSe Composite: The Impact of 2H-NbSe Nanoparticles on SbOCl and Their Application for the Removal of Cr(VI)/Fe(III) and Methyl Orange from Wastewater.

A potential adsorbent, SbOCl@NbSe composite, was generated from the SbOCl photocatalyst and 5 wt % layered 2H-NbSe nanoparticles for the highly effective removal of Cr(VI) and Fe(III) ions and methyl orange (MO) from aqueous solution, and a comparison was drawn against the precursors. SbOCl crystallites and NbSe nanoparticles were synthesized hydrothermally, and the composite was prepared by the incipient wetness impregnation technique. The crystal structure of SbOCl was determined by single-crystal X-ray diffraction (SCXRD) data.

Minimal vertex model explains how the amnioserosa avoids fluidization during dorsal closure.

Dorsal closure is a process that occurs during embryogenesis of . During dorsal closure, the amnioserosa (AS), a one-cell thick epithelial tissue that fills the dorsal opening, shrinks as the lateral epidermis sheets converge and eventually merge. During this process, the aspect ratio of amnioserosa cells increases markedly.

Recent progress in chromium removal from wastewater using covalent organic frameworks - A review.

Covalent organic frameworks (COFs) offer a pivotal solution to urgently address heavy metal removal from wastewater due to their exceptional attributes such as high adsorption capacity, tunable porosity, controllable energy band structures, superior photocatalytic performance, and high stability-reusability. Despite these advantages, COFs encounter certain challenges, including inefficient utilization of visible light, rapid recombination of photogenerated carriers, and limited access to active sites due to close stacking. To enhance the photocatalytic and adsorptive performance of COF-based catalysts, various modification strategies have been reported, with a particular focus on molecular design, structural regulation, and heterostructure engineering.

An Overview of Metal-Organic Framework Based Electrocatalysts: Design and Synthesis for Electrochemical Hydrogen Evolution, Oxygen Evolution, and Carbon Dioxide Reduction Reactions.

Due to the increasing global energy demands, scarce fossil fuel supplies, and environmental issues, the pursued goals of energy technologies are being sustainable, more efficient, accessible, and produce near zero greenhouse gas emissions. Electrochemical water splitting is considered as a highly viable and eco-friendly energy technology. Further, electrochemical carbon dioxide (CO ) reduction reaction (CO RR) is a cleaner strategy for CO utilization and conversion to stable energy (fuels).

Multi-Functional Applications of H-Glass Embedded with Stable Plasmonic Gold Nanoislands.

Metal nanoparticles (MNPs) are synthesized using various techniques on diverse substrates that significantly impact their properties. However, among the substrate materials investigated, the major challenge is the stability of MNPs due to their poor adhesion to the substrate. Herein, it is demonstrated how a newly developed H-glass can concurrently stabilize plasmonic gold nanoislands (GNIs) and offer multifunctional applications.

Charge-transfer-driven enhanced room-temperature ferromagnetism in BiFeO/Ag nanocomposite.

We report observation of more than an order of magnitude jump in saturation magnetization in BiFeO/Ag nanocomposite at room temperature compared to what is observed in bare BiFeOnanoparticles. Using transmission electron microscopy together with energy dispersive x-ray spectra (which maps the element concentration across the BiFeO/Ag interface) and x-ray photoelectron spectroscopy, we show that both the observed specific self-assembly pattern of BiFeOand Ag nanoparticles and the charge transfer between Ag and O are responsible for such an enormous rise in room-temperature magnetization. The BiFeO/Ag nanocomposites, therefore, could prove to be extremely useful for a variety of applications including biomedical.

Improved Ethanol Sensing Performance of α-MnO Nanorods at Room Temperature Enabled through PPy Embedding.

Ethanol is a colorless, highly flammable, volatile organic compound and is a biomarker for fatty liver diseases. So, high-performance and reliable ethanol sensors are the need of the day for biomedical and environmental monitoring applications and drunken driving detection. In this work, we have reported a polypyrrole (PPy)-embedded α-MnO nanorod (NR)-based chemiresistive sensor for the selective detection of trace ethanol vapor at room temperature (25 °C).

Phyto-assisted synthesis of CuO/industrial waste derived biochar composite for adsorptive removal of doxycycline hydrochloride and recycling of spent biochar as green energy storage device.

The highest exposure of Endocrine disrupting compounds (EDC) into the water bodies as a result of extensive production and application of Covid-19 related drugs is a growing concern now a days. Herein, a novel nanocomposite material was developed by impregnating green synthesized copper oxide nanoparticles on the porous surface of fabric waste derived biochar to eliminate the concerned EDCs along with a sustainable disposal strategy for the spent adsorbent. Morphological characterizations by Field emission scanning electron microscopy confirmed the formation of hierarchical porous structured material.

Squeeze Film Effect in Surface Micromachined Nano Ultrasonic Sensor for Different Diaphragm Displacement Profiles.

In the present paper, we have analytically explored the small variations of the local pressure in the trapped air film of both sides of the clamped circular capacitive micromachined ultrasonic transducer (CMUT), which consists of a thin movable membrane of silicon nitride (SiN). This time-independent pressure profile has been investigated thoroughly by solving the associated linear Reynold's equation in the framework of three analytical models, viz. membrane model, plate model, and non-local plate model.

In Vitro and In Vivo Bone Regeneration Assessment of Titanium-Doped Waste Eggshell-Derived Hydroxyapatite in the Animal Model.

In this work, a titanium-doped hydroxyapatite (HAp) scaffold was produced from two different sources (natural eggshell and laboratory-grade reagents) to compare the efficacy of natural and synthetic resources of HAp materials on new bone regeneration. This comparative study also reports the effect of Ti doping on the physical, mechanical, and in vitro as well as in vivo biological properties of the HAp scaffold. Pellets were prepared in the conventional powder metallurgy route, compacted, and sintered at 900 °C, showing sufficient porosity for bony ingrowth.