An integrated assessment of land-use change impact, seasonal variation of pollution indices and human health risk of selected toxic elements in sediments of River Atuwara, Nigeria.

River sediments contain environmental fingerprints that provide useful ecological information. However, the geochemistry of River Atuwara sediments has received less attention over the years. One hundred and twenty-six sediments from 21 locations were collected over a two-season period from River Atuwara, and a detailed investigation of the land use and land cover (LULC) change between 1990 and 2019, analysis of selected toxic and potentially toxic metal(oid)s (TPTM) (Cu, As, Cd, Pb, Ni, Cr, Zn, Fe, Co and Al) using ICP-OES, pollution index assessment, potential source identification (using center log-transformation approach), potential ecological, and human health risk assessment were conducted.

Comprehensive review of the basic chemical behaviours, sources, processes, and endpoints of trace element contamination in paddy soil-rice systems in rice-growing countries.

Rice is the leading staple food for more than half of the world's population, and approximately 160 million hectares of agricultural area worldwide are under rice cultivation. Therefore, it is essential to fulfil the global demand for rice while maintaining food safety. Rice acts as a sink for potentially toxic metals such as arsenic (As), selenium (Se), cadmium (Cd), lead (Pb), zinc (Zn), manganese (Mn), nickel (Ni), and chromium (Cr) in paddy soil-rice systems due to the natural and anthropogenic sources of these metals that have developed in the last few decades.

Wastewater treatment in 2050: Challenges ahead and future vision in a European context.

•Wastewater treatment plants are slowly evolving.•In the next decade, successful implementation of technologies is focused intensification.•New technologies will be focused on gases and bio-based materials.

Molecular-level investigations of effective biogenic phosphorus adsorption by a lanthanum/aluminum-hydroxide composite.

Biogenic phosphorus (P), such as organic P and inorganic pyrophosphates, could substantially contribute towards eutrophication in aquatic systems by internal loading of P from sediment through P species transformation. Previous eutrophication management studies mainly focus on the removal of orthophosphate (Ortho-P), however, an effective approach for biogenic P control from water sources, prior to incorporation in sediment, is still lacking. In this study, a lanthanum/aluminum-hydroxide (LAH) composite was demonstrated to provide both superior removal of Ortho-P and biogenic P, employing myo-inositol hexakisphosphate (IHP) and pyrophosphate (Pyro-P) as model compounds.

Establishing the mechanisms underpinning solids breakthrough in UASB configured anaerobic membrane bioreactors to mitigate fouling.

In this study, the mechanisms for solids breakthrough in upflow anaerobic sludge blanket (UASB) configured anaerobic membrane bioreactors (AnMBRs) have been described to establish design parameters to limit membrane fouling. As the sludge blanket develops, two periods can be identified: (i) an initial progressive enhancement in solids separation provided through sludge blanket clarification, via depth filtration, which sustains downstream membrane permeability; and (ii) sludge blanket destabilisation, which imposed solids breakthrough resulting in a loss in membrane permeability. The onset of sludge blanket destabilisation was identified earlier in the flocculent AnMBR, which was ascribed to an increased gas production, caused by hydrolysis within the sludge blanket at extended solids residence time.

Leakage of CO from geological storage and its impacts on fresh soil-water systems: a review.

Leakage of CO from the geological storage is a serious issue for the sustainability of the receiving fresh soil-water systems. Subsurface water quality issues are no longer related to one type of pollution in many regions around the globe. Thus, an effort has been made to review studies performed to investigate supercritical CO (scCO) and CO enrich brine migration and it's leakage from geological storage formations.

Influence of granular activated carbon media properties on natural organic matter and disinfection by-product precursor removal from drinking water.

Operational and financial constraints challenge effective removal of natural organic matter (NOM), and specifically disinfection by-product (DBP) precursors, at remote and/or small sites. Granular activated carbon (GAC) is a widely used treatment option for such locations, due to its relatively low maintenance and process operational simplicity. However, its efficacy is highly dependent on the media capacity for the organic matter, which in turn depends on the media characteristics.

Association between water and sanitation service levels and soil-transmitted helminth infection risk factors: a cross-sectional study in rural Rwanda.

Background: Soil-transmitted helminth (STH) infections are one of the most prevalent neglected tropical diseases in the world. Drug treatment is the preferred method for infection control yet reinfection occurs rapidly, so water and sanitation represent important complementary barriers to transmission.

Methods: A cross-sectional study was conducted to observe STH risk factors in rural Rwandan households in relation to the Sustainable Development Goal for water and sanitation service levels.

Understanding the biochemical characteristics of struvite bio-mineralising microorganisms and their future in nutrient recovery.

The biochemical properties of selected microorganisms (Bacillus pumilus, Brevibacterium antiquum, Myxococcus xanthus, Halobacterium salinarum and Idiomarina loihiensis), known for their ability to produce struvite through biomineralisation, were investigated. All five microorganisms grew at mesophilic temperature ranges (22-34 °C), produced urease (except I. loihiensis) and used bovine serum albumin as a carbon source.

Trihalomethanes in Drinking Water and Bladder Cancer Burden in the European Union.

Background: Trihalomethanes (THMs) are widespread disinfection by-products (DBPs) in drinking water, and long-term exposure has been consistently associated with increased bladder cancer risk.

Objective: We assessed THM levels in drinking water in the European Union as a marker of DBP exposure and estimated the attributable burden of bladder cancer.

Methods: We collected recent annual mean THM levels in municipal drinking water in 28 European countries (EU28) from routine monitoring records.

A method for the characterisation of microplastics in sludge.

Microplastics (MP) have become a concern owing to their increasing detection in the environment and potential impact on ecosystems. One of the main MP reservoirs is sludge generated during wastewater treatment. Estimates suggest that, through sludge settling, treatment processes remove between 80 and 90 % of MP present in wastewater.

Ensemble modelling framework for groundwater level prediction in urban areas of India.

India is facing the worst water crisis in its history and major Indian cities which accommodate about 50% of its population will be among highly groundwater stressed cities by 2020. In past few decades, the urban groundwater resources declined significantly due to over exploitation, urbanization, population growth and climate change. To understand the role of these variables on groundwater level fluctuation, we developed a machine learning based modelling approach considering singular spectrum analysis (SSA), mutual information theory (MI), genetic algorithm (GA), artificial neural network (ANN) and support vector machine (SVM).

Estimation of some trace metal pollutants in River Atuwara southwestern Nigeria and spatio-temporal human health risks assessment.

Over twenty thousand persons rely on water from Atuwara River for drinking and other domestic purposes, hence the need to ascertain the human health risk inherent in such practice. Seventy-two water samples were collected from River Atuwara during the dry and wet seasons of 2018, and the concentration of heavy metals (Pb, As, Ni, Cr, Zn, Cu, and Cd) were measured using ICP-OES. A newly developed human health risk assessment method, HHRISK code was used to estimate the health risks associated with consumption of water from Atuwara River.

Nanomaterial-based aptamer sensors for arsenic detection.

Arsenic (As) is a highly toxic contaminant in the environment and a serious carcinogen for the human being. The toxicity of arsenic significantly threatens environmental and human health. The effective removing technology for arsenic remains challenging, and one of the reasons is due to the lack of powerful detection method in the complex environmental matrix.

Industrial effluent treatment with immersed MBRs: treatability and cost.

A comprehensive OPEX analysis for both municipal and industrial wastewaters has been conducted encompassing energy, critical component (membrane) replacement, chemicals consumption, waste disposal and labour. The analysis was preceded by a review of recent data on industrial effluent treatability with reference to published chemical oxygen demand (COD) removal data for four effluent types: food and beverage, textile, petroleum and landfill leachate. Outcomes revealed labour costs to be the most significant of those considered, contributing 50% of the OPEX for a 10,000 m/day capacity municipal wastewater treatment works.

Do domestic animals contribute to bacterial contamination of infant transmission pathways? Formative evidence from Ethiopia.

Child stunting is associated with poor water, sanitation and hygiene (WASH), partly due to the effect of infection on intestinal nutrient absorption. WASH interventions, however, show little effect on growth. A hypothesis is that bacterial contamination of hands and floors from domestic animals and their faeces, and subsequent ingestion via infant hand-to-mouth behaviours, may explain this.

Environmentally friendly synthesized and magnetically recoverable designed ferrite photo-catalysts for wastewater treatment applications.

Fenton processes are promising wastewater treatment alternatives for bio-recalcitrant compounds. Three different methods (i.e.

Recovery and reuse of alginate in an immobilized algae reactor.

The use of microalgae for nutrients removal from wastewater has attracted more attention in recent years. More specifically, immobilized systems where algae cells are entrapped in beads in a matrix of a polysaccharide such as alginate have shown a great potential for nutrients removal from wastewater to low levels with reduced retention times and hence smaller footprint. However, a significant operational cost in the up-scaling of alginate-immobilized algae reactors will be the gelling agent alginate.

An empirical determination of the whole-life cost of FO-based open-loop wastewater reclamation technologies.

Over the past 5-10 years it has become apparent that the significant energy benefit provided by forward osmosis (FO) for desalination arises only when direct recovery of the permeate product from the solution used to transfer the water through the membrane (the draw solution) is obviated. These circumstances occur specifically when wastewater purification is combined with saline water desalination. It has been suggested that, for such an "open loop" system, the FO technology offers a lower-cost water reclamation option than the conventional process based on reverse osmosis (RO).

Interactions between Organic Model Compounds and Ion Exchange Resins.

Ion exchange (IEX) can successfully remove natural organic matter (NOM) from surface water. However, the removal mechanism is not well understood due to the complexity and variability of NOM in real source waters as well as the influence of multiple parameters on the removal behavior. For example, this includes the physicochemical properties of the NOM and IEX resin, and the presence of competing anions.

Water diplomacy and nexus governance in a transboundary context: In the search for complementarities.

Growing evidence within nexus research has highlighted the importance for sustainable governance of considering the interdependencies between water, energy, food and the environment, whereas water diplomacy has provided the necessary tools to address water conflicts of a transboundary nature. This paper therefore identifies and evaluates unrealised complementarities between nexus governance and water diplomacy, and discusses the benefits of integrating both for improved transboundary basin management. Two case studies - a wastewater treatment plant within the Jordan's nexus vision and a research project into management of the transboundary Zambezi River Basin - illustrate the identified complementarities and their contribution towards collaborative transboundary natural resources management.

Critical Review of Adaptation Measures to Reduce the Vulnerability of European Drinking Water Resources to the Pressures of Climate Change.

One of the consequences of the generally agreed rise of global temperatures, furtherly exacerbated by the growth of water demand caused by the needs of a growing population, is an increase of areas with water stress. This will imply and in part is already implying, an always greater imbalance between water (and in particular drinking water) demand and supply. These issues are among those investigated by the "Adapting Drinking Water resources to the Impacts of Climate change in Europe" (ADWICE) project that had, among its main goals, the identification of priority adaptation measures aimed at reducing drinking water vulnerability to the pressures of a changing climate.

Sustainable removal of NO by mediated electrocatalytic reduction at ambient temperature electro-scrubbing using electrogenerated Ni(I) electron mediator.

Direct catalysis is generally proposed for nitrous oxide (NO) abatement but catalysis is expensive, requires high temperatures, and suffers from media fouling, which limits its lifetime. In the present study, an ambient temperature electroscrubbing method was developed, coupling wet-scrubbing with an electrogenerated Ni(I) ([Ni(I)(CN)]) mediator, to enable NO reduction in a single process stage. The initial studies of 10 ppm NO absorption into 9 M KOH and an electrolyzed 9 M KOH solution showed no removal.

Comparing flow cytometry with culture-based methods for microbial monitoring and as a diagnostic tool for assessing drinking water treatment processes.

Flow cytometry (FCM) and the ability to measure both total and intact cell populations through DNA staining methodologies has rapidly gained attention and consideration across the water sector in the past decade. In this study, water quality monitoring was undertaken over three years across 213 drinking water treatment works (WTW) in the Scottish Water region (Total n = 39,340). Samples subject to routine regulatory microbial analysis using culture-based methods were also analysed using FCM.