1 results match your criteria: "Coordination Chemistry Saarland University[Affiliation]"
Pd(PDip): Cubic, Unsaturated, Zerovalent.
Adv Sci (Weinh)
July 2024
Coordination Chemistry Saarland University, Campus C4.1, D-66123, Saarbrücken, Germany.
Article Synopsis
- - This study explores the creation and characteristics of a unique palladium nanocluster (Pd(PDip)) achieved by treating palladium(0) precursors with triphosphirane, showcasing its potential for applications in electronic and magnetic materials.
- - The nanocluster is characterized using various advanced techniques including mass spectrometry and NMR, revealing a stable, cubic structure with specific electronic properties influenced by orbital mixing.
- - The researchers demonstrate that the cluster can interact with ethylene and isocyanides, leading to its transformation into a new tetrahedral structure, which underscores the cluster's versatility for future supramolecular assembly applications.