6 results match your criteria: "Cologne Institute of Conservation Sciences[Affiliation]"

Material Characterization of Silicones for Additive Manufacturing.

Polymers (Basel)

August 2024

Cologne Institute of Conservation Sciences, Faculty of Cultural Sciences, TH Köln, Campus Südstadt, Ubierring 40, 50678 Cologne, Germany.

Three-dimensional printing is ideally suited to produce unique and complex shapes. In this study, the material properties of polysiloxanes, commonly named silicones, produced additively by two different methods, namely, multi-jet fusion (MJF) and material extrusion (ME) with liquid printing heads, are investigated. The chemical composition was compared via Fourier-transform infrared spectroscopy, evolved gas analysis mass spectrometry, pyrolysis gas chromatography coupled to mass spectrometry, and thermogravimetry (TGA).

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Over time, artworks often sustain paint layer separation and air gaps within their internal structure due to storage conditions and past restoration efforts. Because of this, paint layer consolidation interventions are an essential activity for art conservators. However, it is difficult to determine the exact location and the extent of layer separation on a piece of art in a non-invasive way, and even more difficult to evaluate the success of a consolidation intervention.

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The paper structure of historical prints is sort of a unique fingerprint. Paper with the same origin shows similar chain line distances. As the manual measurement of chain line distances is time consuming, the automatic detection of chain lines is beneficial.

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The Ins and Outs of C Dating Lead White Paint for Artworks Application.

Anal Chem

June 2020

Department of Chemistry and Applied Biosciences, ETH-Zürich, Vladimir-Prelog-Weg 1, 8093 Zurich, Switzerland.

Article Synopsis
  • Lead white is a historical pigment used in art that can help determine the age of paintings through radiocarbon dating.
  • The traditional method of analyzing carbonates has limitations when dealing with paint samples containing a mix of different carbonates, making it necessary to use a thermal approach for accurate separation and analysis.
  • A new procedure involving solvent extraction before thermal treatment has been developed, improving the accuracy of dating by isolating carbon dioxide from lead white specifically, and has been successfully tested on samples from a Baroque painting.
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Uncovering modern paint forgeries by radiocarbon dating.

Proc Natl Acad Sci U S A

July 2019

Laboratory of Inorganic Chemistry, Eidgenössische Technische Hochschule-Zürich, 8093 Zürich, Switzerland.

Art forgeries have existed since antiquity, but with the recent rapidly expanding commercialization of art, the approach to art authentication has demanded increasingly sophisticated detection schemes. So far, the most conclusive criterion in the field of counterfeit detection is the scientific proof of material anachronisms. The establishment of the earliest possible date of realization of a painting, called the , is based on the comparison of materials present in an artwork with information on their earliest date of discovery or production.

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Matrix-assisted laser desorption/ionisation-time of flight (MALDI-TOF) mass spectrometry is commonly used for the identification of proteinaceous binders and their mixtures in artworks. The determination of protein binders is based on a comparison between the m/z values of tryptic peptides in the unknown sample and a reference one (egg, casein, animal glues etc.), but this method has greater potential to study changes due to ageing and the influence of organic/inorganic components on protein identification.

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