Nickel model complexes to mimic carbon monoxide dehydrogenase reactions.

Biological CO/CO interconversion catalyzed at the Ni/Fe heterobimetallic active site of anaerobic carbon monoxide dehydrogenases (CODHs) offers important insights for the design of efficient and selective synthetic catalysts for CO capture and utilization (CCU). Notably, this organometallic C interconversion process is mediated at a three-coordinate nickel site. Extensive research has been conducted to elucidate the redox and structural changes involved in substrate binding and conversion.

3D Bristle-Structured, Knitted-Fabric-Based Triboelectric Sensors for Machine Learning-Based Motion Recognition.

With the development of electronic technology, triboelectric-based sensors have been widely researched in fields such as healthcare, rehabilitation training, and sports assistance due to their manufacturing convenience and self-powering advantages. Among them, 3D fabric-based triboelectric sensors not only possess advantages such as easy mechanized production, good breathability, and ease of wearing but also their unique 3D structure enhances the specific surface area, thereby amplifying the sensitivity. This study proposes a 3D bristle-structured fabric made by a digital knitting technology that has not been studied widely for triboelectric devices.

δ-catenin promotes Twist1 stabilization in prostate cancer through ubiquitination modification.

Prostate cancer generally has a high long-term survival rate; however, metastatic prostate cancer remains largely incurable despite intensive multimodal therapy. Recent research has identified δ-catenin, a member of the catenin family, as playing a crucial role in the progression of prostate cancer. Nonetheless, the extent to which δ-catenin influences transcription factors associated with epithelial-mesenchymal transition (EMT) has not been thoroughly explored.

Enhanced solar-driven photoelectrochemical water splitting using nanoflower Au/CuO/GaN hybrid photoanodes.

Harnessing solar energy for large-scale hydrogen fuel (H) production shows promise in addressing the energy crisis and ecological degradation. This study focuses on the development of GaN-based photoelectrodes for efficient photoelectrochemical (PEC) water splitting, enabling environmentally friendly H production. Herein, a novel nanoflower Au/CuO/GaN hybrid structure was successfully synthesized using a combination of methods including successive ionic layer adsorption and reaction (SILAR), RF/DC sputtering, and metal-organic chemical vapour deposition (MOCVD) techniques.

Catalytic depolymerization of Kraft lignin to high yield alkylated-phenols over CoMo/SBA-15 catalyst in supercritical ethanol.

Lignin is generally considered to be a renewable and sustainable resource of aromatic chemicals. However, the depolymerization of Kraft lignin (KL) for the production of selective phenolic monomers presents a significant challenge due to its highly recalcitrant nature. Therefore, in this work, we investigated the effect of metal sites and acid active sites on Mo/SBA-15, Co/SBA-15 and CoMo/SBA-15 catalysts in supercritical ethanol for the depolymerization of KL to produce phenolic monomers.

Targeting the multidrug and toxin extrusion 1 gene (SLC47A1) sensitizes glioma stem cells to temozolomide.

Glioblastoma multiforme (GBM) is the most aggressive type of brain tumor, with an extremely poor prognosis due to resistance to standard-of-care treatments. Strong evidence suggests that the small population of glioma stem cells (GSCs) contributes to the aggressiveness of GBM. One of the mechanisms that promote GSC progression is the dysregulation of membrane transporters, which mediate the influx and efflux of substances to maintain cellular homeostasis.

Designing a TiO-MoO-BMIMBr nanocomposite by a solvohydrothermal method using an ionic liquid aqueous mixture: an ultra high sensitive acetaminophen sensor.

This study shows a simplistic, efficient procedure to synthesize TiO-MoO-BMIMBr nanocomposites. Powder X-ray diffraction, scanning electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray photoelectron spectroscopy have all been used to completely analyse the materials. The detection of acetaminophen (AC) has been examined at a modified glassy carbon electrode with TiO-MoO-BMIMBr nanocomposites.

Influence of bridge structure manipulation on the electrochemical performance of π-conjugated molecule-bridged silicon quantum dot nanocomposite anode materials for lithium-ion batteries.

To assess the influence of bridge structure manipulation on the electrochemical performance of π-conjugated molecule-bridged silicon quantum dot (Si QD) nanocomposite (SQNC) anode materials, we prepared two types of SQNCs by Sonogashira cross-coupling and hydrosilylation reactions; one is SQNC-VPEPV, wherein the Si QDs are covalently bonded by vinylene (V)-phenylene (P)-ethynylene (E)-phenylene-vinylene, and the other is SQNC-VPV. By comparing the electrochemical performances of the SQNCs, including that of the previously reported SQNC-VPEPEPV, we found that the SQNC with the highest specific capacity varied depending on the applied current density; SQNC-VPEPV (1420 mA h g) > SQNC-VPV (779 mA h g) > SQNC-VPEPEPV(465 mA h g) at 800 mA g, and SQNC-VPV (529 mA h g) > SQNC-VPEPEPV (53 mA h g) > SQNC-VPEPV (7 mA h g) at 2000 mA g. To understand this result, we performed EIS and GITT measurements of the SQNCs.

Epitaxial growth of 1D GaN-based heterostructures on various substrates for photonic and energy applications.

GaN is an important III-V semiconductor for a variety of applications owing to its large direct band gap. GaN nanowires (NWs) have demonstrated significant potential as critical building blocks for nanoelectronics and nanophotonic devices, as well as integrated nanosystems. We present a comprehensive analysis of the vapor-liquid-solid (VLS) as a general synthesis technique for NWs on a variety of substrates, the morphological and structural characterization, and applications of GaN NWs in piezoelectric nanogenerators, light-emitting diodes, and solar-driven water splitting.

Improving infra-red polarized imaging efficiency in a bilayer wire-grid polarizer.

The optical, plasmonic, and imaging performance of an infra-red polarized system exceeds that of a conventional infra-red detector due to its high resolution and precision. The wire-grid polarizer has large potential for use in an infra-red polarized imaging device owing to its large polarization efficiency. In this study, we theoretically and experimentally investigate a method to improve the polarization efficiency of a wire-grid polarizer.

MicroRNA-122 targets δ-catenin to suppress the tumorigenic potential of prostate cancer cells.

δ-Catenin is expressed abundantly in various human cancers, including prostate, brain, breast, and lung carcinomas, and is recognized as an oncogene that promotes cancer cell growth and tumorigenesis. Although several transcriptional and post-translational pathways for δ-catenin regulation have been identified in cancer cells, the potential effects of microRNA-mediated regulation remain elusive. Here, we used a δ-catenin 3'-UTR luciferase reporter assay to identify regulatory microRNAs.

Acoustofluidic Stimulation of Functional Immune Cells in a Microreactor.

The cytotoxic response of natural killer (NK) cells in a microreactor to surface acoustic waves (SAWs) is investigated, where the SAWs produce an acoustic streaming flow. The Rayleigh-type SAWs form by an interdigital transducer propagated along the surface of a piezoelectric substrate in order to allow the dynamic stimulation of functional immune cells in a noncontact and rotor-free manner. The developed acoustofluidic microreactor enables a dynamic cell culture to be set up in a miniaturized system while maintaining the performance of agitating media.

Plasmonic All-Frame-Faceted Octahedral Nanoframes with Eight Engraved Y-Shaped Hot Zones.

We report the synthesis of all-frame-faceted octahedral nanoframes containing eight Y-shaped hot zones in a single entity where electromagnetic near-field focusing can be maximized. To realize such state-of-the-art complex nanoframes, a series of multiple stepwise bottom-up processes were executed by exploiting Au octahedral nanoparticles as the initial template. By rationally controlling the chemical reactivity of different surface facets (, vertexes, edges, and terraces), the Au octahedral nanoparticles went through controlled shape transformations, leading to Au-engraved nanoparticles wherein 24 edges wrap the octahedral Au nanoparticle core.

Reduced graphene oxide-incorporated calcium phosphate cements with pulsed electromagnetic fields for bone regeneration.

Natural calcium phosphate cements (CPCs) derived from sintered animal bone have been investigated to treat bone defects, but their low mechanical strength remains a critical limitation. Graphene improves the mechanical properties of scaffolds and promotes higher osteoinduction. To this end, reduced graphene oxide-incorporated natural calcium phosphate cements (RGO-CPCs) are fabricated for reinforcement of CPCs' characteristics.

δ-Catenin promotes cell migration and invasion via Bcl-2-regulated suppression of autophagy in prostate cancer cells.

As a member of the catenin family, δ-catenin is overexpressed in many cancers, including prostate cancer, and the role of δ-catenin in prostate tumor growth has been reported. However, the involvement of δ-catenin in the migration and invasion of prostate cancer has rarely been studied. In this study, we innovatively proposed that δ-catenin would enhance the migration and invasion ability of prostate cancer cells.

bFGF-mediated phosphorylation of δ-catenin increases its protein stability and the ability to induce the nuclear redistribution of β-catenin.

Recently, we have shown that δ-catenin strengthened the epidermal growth factor receptor (EGFR)/Erk1/2 signaling pathway through the association between EGFR and δ-catenin. Now, we further analyzed the correlation between basic fibroblast growth factor (bFGF)/fibroblast growth factor receptor 1 (FGFR1) and δ-catenin in prostate cancer and investigated the molecular mechanism underlying the role of bFGF/FGFR1 modulation in CWR22Rv-1 (Rv-1) cells. Here, we demonstrated that bFGF phosphorylated the tyrosine residues of δ-catenin in Rv-1 cells and further proved that the bFGF mediated FGFR1/δ-catenin tyrosine phosphorylation was time dependent.

A heptamethine cyanine dye serves as a potential marker for myeloid-derived suppressor cells.

Myeloid-derived suppressor cells (MDSCs) are a heterogeneous population of immature myeloid cells with inhibitory effects on T cell-mediated immune response. MDSCs accumulate under many pathological conditions, including cancers, to avoid anticancer immunity. Unlike mouse MDSCs, common specific surface markers for human MDSCs are not clearly defined, mainly due to the complexity of MDSC subsets.

State-of-the-art anodes of potassium-ion batteries: synthesis, chemistry, and applications.

The growing demand for green energy has fueled the exploration of sustainable and eco-friendly energy storage systems. To date, the primary focus has been solely on the enhancement of lithium-ion battery (LIB) technologies. Recently, the increasing demand and uneven distribution of lithium resources have prompted extensive attention toward the development of other advanced battery systems.

Kesterite Solar Cells: Insights into Current Strategies and Challenges.

Earth-abundant and environmentally benign kesterite CuZnSn(S,Se) (CZTSSe) is a promising alternative to its cousin chalcopyrite Cu(In,Ga)(S,Se) (CIGS) for photovoltaic applications. However, the power conversion efficiency of CZTSSe solar cells has been stagnant at 12.6% for years, still far lower than that of CIGS (23.

Tin-selenide as a futuristic material: properties and applications.

SnSe/SnSe is a promising versatile material with applications in various fields like solar cells, photodetectors, memory devices, lithium and sodium-ion batteries, gas sensing, photocatalysis, supercapacitors, topological insulators, resistive switching devices due to its optimal band gap. In this review, all possible applications of SnSe/SnSe have been summarized. Some of the basic properties, as well as synthesis techniques have also been outlined.