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Novel corrugated In9 anionic layer in Li2Y5In9: square pyramidal In5 clusters interconnected by unusual butterfly In4 clusters.
Inorg Chem
September 2005
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences and the Graduate School of Chinese Academy of Sciences, Fuzhou 350002, P. R. China.
The new ternary polar intermetallic phase, Li2Y5In9, was obtained by high-temperature solid-state reactions of the corresponding elements inwelded Ta tubes. Its crystal structure was established by a single-crystal X-ray diffraction study. Li2Y5In9 crystallizes in the tetragonal space group P4/nmm (No.
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