Non-invasive detection of systemic lupus erythematosus using SERS serum detection technology and deep learning algorithms.

Systemic lupus erythematosus (SLE) is an autoimmune disease with multiple symptoms, and its rapid screening is the research focus of surface-enhanced Raman scattering (SERS) technology. In this study, gold@silver-porous silicon (Au@Ag-PSi) composite substrates were synthesized by electrochemical etching and in-situ reduction methods, which showed excellent sensitivity and accuracy in the detection of rhodamine 6G (R6G) and serum from SLE patients. SERS technology was combined with deep learning algorithms to model serum features using selected CNN, AlexNet, and RF models.

Influence of Supercritical CO Fracturing Fluid on the Permeability of Shale Reservoir and Mechanism Analysis.

Reduction of the reservoir permeability during supercritical CO fracturing caused significant reservoir damage, which directly affects the crude oil recovery rate. This investigation explored a novel thickener for supercritical CO fracturing fluid, this CO thickener not only effectively improves the viscosity and rheological properties of CO fracturing fluid but also contributes to reduce reservoir damage and improve permeability. The research results indicated that the synthesized CO thickener (3 wt %) can increase the apparent viscosity of supercritical CO fracturing fluid to 7 mPa·s, and a 9% matrix permeability damage rate and a 0.

Preparation of Wheat Straw Hot-Pressed Board through Coupled Dilute Acid Pretreatment and Surface Modification.

The production of wheat straw waste board materials encounters challenges, including inadequate inherent adhesiveness and the utilization of environmentally harmful adhesives. Employing a hot-pressed method for converting wheat straw into board materials represents a positive stride towards the resourceful utilization of agricultural wastes. This study primarily focuses on examining the influence of hot-pressing process conditions on the mechanical properties of wheat straw board materials pretreated with dilute acid.

Optimization of Desalination Efficiency and Exploratory Applications of TiO Active Site Electrode Enhanced by Activated Carbon and Tween 80 in Capacitive Deionization Technology.

Capacitive deionization (CDI) is an emerging desalination technology for seawater desalination. The development of high-desalination and long-life electrode materials is a research focus in the global water treatment field. In this experiment, Tween T80 was used as a surface activator, and a modified electrode was prepared by facilitating the deposition of TiO active sites onto the surface of activated carbon through a sol-gel/hydrothermal two-step synthesis strategy.

Nitrogen-Rich Triazine-Based Covalent Organic Frameworks as Efficient Visible Light Photocatalysts for Hydrogen Peroxide Production.

Covalent organic frameworks (COFs) have been widely used in photocatalytic hydrogen peroxide (HO) production due to their favorable band structure and excellent light absorption. Due to the rapid recombination rate of charge carriers, however, their applications are mainly restricted. This study presents the design and development of two highly conjugated triazine-based COFs (TBP-COF and TTP-COF) and evaluates their photocatalytic HO production performance.

Sandwich-like CuNPs@AgNPs@PSB SERS substrates for sensitive detection of R6G and Forchlorfenuron.

The development of a highly sensitive, synthetically simple and economical SERS substrate is technically very important. A fast, economical, sensitive and reproducible CuNPs@AgNPs@ Porous silicon Bragg reflector (PSB) SERS substrate was prepared by electrochemical etching and in situ reduction method. The developed CuNPs@AgNPs@PSB has a large specific surface area and abundant "hot spot" region, which makes the SERS performance excellent.

Progress and Prospect of Ion Imprinting Technology in Targeted Extraction of Lithium.

Ion Imprinting Technology (IIT) is an innovative technique that produces Ion-Imprinted polymers (IIPs) capable of selectively extracting ions. IIPs exhibit strong specificity, excellent stability, and high practicality. Due to their superior characteristics, the application of IIPs for lithium resource extraction has garnered significant attention.

MXene and AgNW based flexible transparent conductive films with sandwich structure for high-performance EMI shielding and electrical heaters.

With the popularization of 5G technology and the development of science and technology, flexible and transparent conductive films (TCF) are increasingly used in the preparation of optoelectronic devices such as electromagnetic shielding devices, transparent flexible heaters, and solar cells. Silver nanowires (AgNW) are considered the best material for replacing indium tin oxide to prepare TCFs due to their excellent comprehensive properties. However, the loose overlap between AgNWs is a significant reason for the high resistance.

Progress in the Elimination of Organic Contaminants in Wastewater by Activation Persulfate over Iron-Based Metal-Organic Frameworks.

The release of organic contaminants has grown to be a major environmental concern and a threat to the ecology of water bodies. Persulfate-based Advanced Oxidation Technology (PAOT) is effective at eliminating hazardous pollutants and has an extensive spectrum of applications. Iron-based metal-organic frameworks (Fe-MOFs) and their derivatives have exhibited great advantages in activating persulfate for wastewater treatment.

Screening and characterization of a denitrifying with strong desulfurization capacity.

A denitrifying bacteria, which we named DNB-15, was screened and isolated from the Shengli Oilfield polymer-containing wastewater. The strain was characterized by 16S rDNA analysis and the effects of nutrient substrate type, pH, mineralization and temperature on the activity of the strain were also investigated. The strain was identified as , of which the most efficient carbon source is sodium citrate, the most suitable nitrogen source is potassium nitrate, the suitable temperature for growth is 35～45 °C, the suitable pH range for growth is 7.

Amorphous MnO Lamellae Encapsulated Covalent Triazine Polymer-Derived Multi-Heteroatoms-Doped Carbon for ORR/OER Bifunctional Electrocatalysis.

The intelligent construction of non-noble metal materials that exhibit reversible oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) with bifunctional electrocatalytic performance is greatly coveted in the realm of zinc-air batteries (ZABs). Herein, a crafted structure-amorphous MnO lamellae encapsulated covalent triazine polymer-derived N, S, P co-doped carbon sphere (A-MnO/NSPC) is designed using a self-doped pyrolysis coupled with an in situ encapsulation strategy. The customized A-MnO/NSPC-2 demonstrates a superior bifunctional electrocatalytic performance, confirmed by a small ΔE index of 0.

Viscosity of Ionic Liquids: Theories and Models.

Ionic liquids (ILs) offer a wide range of promising applications due to their unique and designable properties compared to conventional solvents. Further development and application of ILs require correlating/predicting their pressure-viscosity-temperature behavior. In this review, we firstly introduce methods for calculation of thermodynamic inputs of viscosity models.

Energy controls wave propagation in a neural network with spatial stimuli.

Nervous system has distinct anisotropy and some intrinsic biophysical properties enable neurons present various firing modes in neural activities. In presence of realistic electromagnetic fields, non-uniform radiation activates these neurons with energy diversity. By using a feasible model, energy function is obtained to predict the growth of synaptic connections of these neurons.

Bioconcentration of polycyclic aromatic hydrocarbons in different tissues of zebrafish (Danio rerio) investigated with PBTK model.

Due to the lipophilicity, polycyclic aromatic hydrocarbons (PAHs) are easily accumulated in fish. However, the research on PAH bioaccumulation process in different fish tissues and the relevant effect mechanisms are still deficient. The bioconcentration of PAHs (phenanthrene, anthracene, fluoranthene, and pyrene) in different zebrafish tissues (skin, fish muscle, gill, digestive tract, liver, gonad, and residual) was studied.

Recent Advances in Zeolites-Catalyzed Biomass Conversion to Hydroxymethylfurfural: The Role of Porosity and Acidity.

Biomass is an attractive raw material for the production of fuel oil and chemical intermediates due to its abundant reserves, low price, easy biodegradability, and renewable use. Hydroxymethylfurfural (5-HMF) is a valuable platform chemically derived from biomass that has gained significant research interest owing to its economic and environmental benefits. In this review, recent advances in biomass catalytic conversion systems for 5-HMF production were examined with a focus on the catalysts selection and feedstocks' impact on the 5-HMF selectivity and yield.

High-entropy oxides as photocatalysts for organic conversion.

A strategy involving organic photocatalytic conversion using hydrothermal synthesis of high-entropy oxide (HEO) (CoCuZnMnNa)O nanoparticles was developed. Under mild conditions, HEO nanoparticles were driven by visible light to achieve ideal yields and selectivity in sulfide oxidative coupling reactions and benzimidazole cyclization reactions, with a wide substrate range. This study is expected to contribute to the use of high-entropy oxides in organic photocatalysis.

"Have to do" or "willing to do": Examining the relationship between self-control and academic emotions using experience sampling method.

The purpose of this study was to examine the antecedents of academic emotions among university students through real-time and multilevel analyses. We explored the link between state self-control and academic emotions, the influence of self-determination on the relationship between them, and the moderating role of trait self-control. The data was collected over seven consecutive days during which university students (N = 155) completed smartphone questionnaires.

Novel SERS biosensor for rapid detection of breast cancer based on AgO-Ag-PSi nanochips.

AgO-Ag-PSi (porous silicon) surface-enhanced Raman scattering (SERS) chip was successfully synthesized by electrochemical corrosion, in situ reduction and heat treatment technology. The influence of different heat treatment temperature on SERS performance of the chip is studied. The results show that the chip treated at 300 °C has the best SERS performance.

One-Pot Three-Dimensional Printing of a Hierarchical NiMo/AlO Monolithic Catalyst for 4,6-Dimethyldibenzothiophene Hydrodesulfurization.

The development of a competitive-cost and high-efficiency NiMo/AlO hydrodesulfurization (HDS) catalyst remains challenging in the field of petrochemical industry. Herein, a highly efficient NiMo/AlO monolithic HDS catalyst was elaborately designed and successfully fabricated via a one-pot three-dimensional (3D) printing strategy, and its HDS activity was examined for 4,6-dimethyldibenzothiophene conversion. The results unveil that the NiMo/AlO monolithic catalyst prepared by the 3D printing strategy (3D-NiMo/AlO) exhibits hierarchical structure due to the combustion of hydroxymethyl cellulose serving as adhesive, which endows the weaker metal-support-interaction between Mo oxides and AlO, remarkably promoting sulfidation of both Mo and Ni species and the formation of "Type II" NiMoS active phase, thereby reducing the apparent activation energy ( = 109.

Effect and formulation of ecolabel policy: A perspective of green supply chain decision and coordination.

Ecolabel policy has become an important strategy to encourage the consumption of green products throughout the world, contributing to sustainable development which is an inevitable choice for human society. Considering the manufacturer's reputation, consumer's environmental awareness, and effects of ecolabel certification on product demand, this study proposes several Stankelberg game models containing one manufacturer and one retailer to compare the optimal decisions and the impacts on the green supply chain with/without ecolabel certification, where four different scenarios are investigated in the centralized and decentralized situations. The results indicate that the ecolabel policy only functions below a threshold associated with the consumer's environmental awareness, which is higher in the decentralized situation.

The effects of carbon pricing instruments on carbon emission reduction in China's refining industry: an evolutionary game between heterogeneous refineries.

Carbon emissions from the refining industry are receiving increasing national attention. In view of long-term sustainable development, a carbon pricing mechanism oriented to carbon emission reduction needs to be developed. Currently, the two most common carbon pricing instruments are emission trading system and carbon tax.

Coupling annealed silver nanoparticles with a porous silicon Bragg mirror SERS substrate and machine learning for rapid non-invasive disease diagnosis.

AgO-Ag-porous silicon Bragg mirror (PSB) composite SERS substrates were successfully synthesized by using a combination of electrochemical and thermochemical methods. Test results showed that the SERS signal increased and decreased as the annealing temperature used for the substrate increased, where the most intense SERS signal was obtained using a substrate annealed at 300 °C. Stability test results showed substantial enhancement of the SERS signal intensity of the AgO-Ag-PSB composite one month after preparation compared with that of conventional Ag-PSB.

Study on Wastewater Demulsification Technology of Crude Oil in Xinjiang Oilfield.

The Second Oil Production Plant of Xinjiang Oilfield produces a large amount of highly emulsified crude oil, which has a serious impact on the subsequent oil-water separation. At present, the concentration of demulsifier has increased to 2000 mg/L, but the demulsification effect is still poor. In this paper, the source and physical properties of highly emulsified crude oil are investigated firstly.

Selective Adsorption of Quercetin by the Sol-Gel Surface Molecularly Imprinted Polymer.

Quercetin, as one of the most biologically active natural flavonoids, is widely found in various vegetables, fruits and Chinese herbs. In this work, molecularly imprinted polymer (MIP) was synthesized through surface molecular imprinting technology with sol-gel polymerization mechanism on SiO at room temperature using quercetin as the template, SiO as the supporter, 3-aminopropyltriethoxysilane (APTES) as the functional monomer, and tetraethoxysilane (TEOS) as the cross-linker. The prepared MIP was characterized via scanning electron microscope (SEM), Fourier transform infrared spectroscopy (FT-IR) and nitrogen adsorption measurements to validate its surface morphology, structure and functionality.