Advanced mechanisms and applications of microwave-assisted synthesis of carbon-based materials: a brief review.

The interaction of microwave radiation with carbon-based materials induces rapid, instantaneous heating. When combined with the plasma excitation capabilities of microwaves, this property presents novel avenues for synthesizing carbon-based materials that require high temperatures and catalytic activity. This review investigates the response of carbon-based materials to microwave radiation, analyzes the dielectric loss mechanism responsible for heat generation, and details the microwave plasma excitation mechanisms employed in the synthesis and processing of carbon-based materials.

Study on the discoloration phenomenon caused by iron ion oxidation in Boston ivy pads and its effect on adhesion force.

Boston ivy has received much attention from researchers owing to its exceptional climbing abilities. However, many aspects of their adhesion behavior remain unresolved. Our research has discovered a phenomenon of oxidation and discoloration in Boston ivy pads, which leads to a significant decrease in adhesion force.

Improved catalytic performance in gas-phase dimethyl ether carbonylation over facile NHF etched ferrierite.

Gas-phase dimethyl ether (DME) carbonylation to methyl acetate (MA) initiates a promising route for producing ethanol from syngas. Ferrierite (FER, ZSM-35) has received considerable attention as it displays excellent stability in the carbonylation reaction and its modification strategy is to improve its catalytic activity on the premise of maintaining its stability as much as possible. However, conventional post-treatment methods such as dealumination and desilication usually selectively remove framework Al or Si atoms, ultimately altering the intrinsic composition, crystallinity, and acidity of zeolites inevitably.

Grafting macromolecular chains on the surface of graphene oxide through crosslinker for antistatic and thermally stable polyethylene terephthalate nanocomposites.

The graphene oxide (GO) and polyethylene terephthalate (PET) molecular chains are connected together by the two amino groups of the crosslinking agent -phenylenediamine (PPD). The presence of macromolecular chains could make GO uniformly dispersed in the polymer matrix, improving the antistatic performance and thermal stability of the nanocomposite. In this paper, GO was prepared by the improved Hummers, method.

Correction: Temperature-sensitive foaming agent developed for smart foam drainage technology.

[This corrects the article DOI: 10.1039/D2RA04034D.].

Temperature-sensitive foaming agent developed for smart foam drainage technology.

The conventional foam drainage technology needs to be defoamed, which is not convenient for its popularization and application. In view of this problem, from the point of molecular design, a temperature-responsive surfactant was designed and synthesized. In the synthetic process, polyoxyethylene alkyl ether carboxylic acid, diethanolamine and sodium chloroacetate were used as raw materials.

Using starch graft copolymer gel to assist the CO huff-n-puff process for enhanced oil recovery in a water channeling reservoir.

The CO huff-n-puff process is an effective method to enhance oil recovery (EOR) and reduce CO emissions. However, its utilization is limited in a channeling reservoir due to early water and gas breakthrough. A novel starch graft copolymer (SGC) gel is proposed for treating the channels and assisting with the CO huff-n-puff process.

Performance demonstration of gas-assisted gravity drainage in a heterogeneous reservoir using a 3D scaled model.

Gas-assisted gravity drainage (GAGD) is an effective method for oil recovery. Gravity increases the stability of the Gas-Oil Contact (GOC), thus delaying gas breakthrough and promoting crude oil production. Studying the effects of fluid and reservoir parameters on the stability of GOC could help understand the mechanism of GAGD.

Modifying Y zeolite with chloropropyl for improving Cu load on Y zeolite as a super Cu/Y catalyst for toluene oxidation.

Developing an efficient catalyst is desirable when for example moving from a noble metal-based catalyst to a transition metal-based one for VOC removal. In this work, the chloropropyl-modified NaY zeolite (NaY-CPT) was first synthesized in an extremely dense system through introducing 3-chloropropyl-trimethoxysilane (CPT) in the aluminosilicate sol. Then the Cu/Y-CPT catalyst was fabricated by impregnating Cu species on the NaY-CPT zeolite and the highly effective Cu/Y based catalyst has been achieved for catalytic toluene oxidation.

Synthesis of ZSM-5 zeolites from biomass power plant ash for removal of ionic dyes from aqueous solution: equilibrium isotherm, kinetic and thermodynamic analysis.

In this work, industrial biomass power plant ash was used to synthesize the ZSM-5 zeolites for the first time with the original intention to turn value-added material into wealth, and then committed to adsorption performance testing. Typical chemical structure and morphology of ZSM-5 zeolite were identified by comprehensive technologies. Uniquely, it was found that there was a low pressure hysteresis loop which was caused by crossed 10-membered rings in the N adsorption-desorption isotherm.

An online optimization strategy for a fluid catalytic cracking process using a case-based reasoning method based on big data technology.

Rigorous mechanistic models of refining processes are often too complex, which results in long modeling times, low model computational efficiencies, and poor convergence, limiting the application of mechanistic-model-based process optimization and advanced control in complex refining production processes. To address this problem and take advantage of big data technology, this study used case-based reasoning (CBR) for process optimization. The proposed method makes full use of previous process cases and reuses previous process cases to solve production optimization problems.

Identifying key mononuclear Fe species for low-temperature methane oxidation.

The direct functionalization of methane into platform chemicals is arguably one of the holy grails in chemistry. The actual active sites for methane activation are intensively debated. By correlating a wide variety of characterization results with catalytic performance data we have been able to identify mononuclear Fe species as the active site in the Fe/ZSM-5 zeolites for the mild oxidation of methane with HO at 50 °C.

Design and characterization of oil-in-water nanoemulsion for enhanced oil recovery stabilized by amphiphilic copolymer, nonionic surfactant, and LAPONITE® RD.

The application of nanotechnology in the oil and gas industry has attracted widespread attention in recent years. This study aims to develop a nanoemulsion (NE) for use in enhanced oil recovery (EOR). The NE stabilized by anion amphiphilic copolymer, nonionic surfactant (Brij30) and modified LAPONITE® RD was prepared by the phase inversion composition (PIC) method.

N-foam-assisted CO huff-n-puff process for enhanced oil recovery in a heterogeneous edge-water reservoir: experiments and pilot tests.

The CO huff-n-puff process is an effective method to enhance oil recovery; however, its utilization is limited in heterogenous edge-water reservoirs due to the severe water channeling. Accordingly, herein, a stable N foam is proposed to assist CO huff-n-puff process for enhanced oil recovery. Sodium dodecyl sulfate (SDS) and polyacrylamide (HPAM) were used as the surfactant and stabilizer, respectively, and 0.

Analysis of Xinjiang asphaltenes using high precision spectroscopy.

Asphaltenes are known for causing flow assurance problems in numerous oil fields. In this study we present a comparative spectroscopic analysis of Xinjiang heavy oil asphaltenes as part of ongoing research for an environmentally friendly and cheap chemical inhibitor. The goal is to predict the internal morphology of these asphaltenes through comparative analysis using high precision spectroscopy.

The mechanical properties, microstructures and mechanism of carbon nanotube-reinforced oil well cement-based nanocomposites.

High performance cement-based nanocomposites were successfully fabricated through the use of oil well cement filled with multiwalled carbon nanotubes (MWCNTs) as reinforcements. The dispersibilities of four dispersing agents for the MWCNTs were investigated and compared. The dispersed morphologies and structural characteristics of the MWCNTs were analyzed TEM, FTIR and Raman spectroscopy studies.

Anion amphiphilic random copolymers and their performance as stabilizers for O/W nanoemulsions.

A series of anionic amphiphilic random copolymers with sodium p-styrene sulfonate and dodecyl methacrylate side chains were synthesized free radical polymerization and their properties in the formation and stabilization of nano-emulsions were investigated. Using poly(sodium p-styrene sulfonate)--poly(dodecyl methacrylate) and Brij 30 as a stabilizer to prepare nanoemulsions, we obtained small droplet size and unimodal distribution nanoemulsions by a low-energy phase inversion composition (PIC) method. The p(SSS)--p(LMA)-Brij 30 co-stabilized nanoemulsions show extraordinary long-term stability and heat resistance, there were almost no variations of droplet size after storing for 35 days and no phase inversion occurred when heating the temperature up to 90 °C.

The influence of organically intercalated montmorillonites on the interfacial tension and structure of oil-in-water nanoemulsions.

The properties of O/W emulsions can be improved by the addition of nanomaterials. To explore the influence of organically intercalated montmorillonites (OMts) on the properties of O/W emulsions, we introduced an OMt into a nanoemulsion as a co-stabilizer with the quaternary ammonium Gemini cationic surfactant (G16-2-16) and nonionic lauryl polyoxyethylene ether (Brij 30). The influence of the organically intercalated montmorillonite (OMt) on the properties, such as the interfacial tension, zeta potential, stability, conductivity and morphology of the droplets, of the nanoemulsions was investigated.

Multi-color carbon dots for white light-emitting diodes.

Heteroatom doped carbon dots (CDs) with color adjustable properties have attracted extensive attention. The doping of elements can effectively tune the surface chemical properties of CDs, thus resulting in its multi-functional applications such as in bio-imaging, photocatalysis, and photothermal conversion. The facile preparation of single metal-doped CDs with color-tunable properties has been rarely reported yet.

Study on the blockage mechanism of carbon dioxide hydrate slurry and its microscopic particle characteristics.

In order to better understand the process of carbon dioxide hydrate formation and blockage, a series of experiments were performed in a high pressure hydrate experimental loop which has been constructed. The impacts of varying flow rate, pressure, and restarting of the pump on the plugging have been studied in this paper. The particle chord length distribution in the process of hydrate formation and blockage was monitored in real time by using the advanced device, Focused Beam Reflectance Measurement (FBRM).

Study on the growth rate of natural gas hydrate in water-in-oil emulsion system using a high-pressure flow loop.

Hydrate slurry transport technology in deep-water pipelines has become a focal point among worldwide researches, due to its high economic efficiency. However, as the key part of the hydrate slurry transport technology research, the mechanism and laws of natural gas hydrate growth dynamics are still unclear in the flow emulsion system. On this basis, we have conducted a series of growth kinetic experiments in a high-pressure loop, investigated systematically several influencing factors ( the flow rate, water-cut, AA concentration and so on) of growth kinetics, obtained the quantitative relations between these factors and the gas consumption as well as the hydrate growth rate (gas consumption rate).

Preparation and properties of nanocomposites of β-cyclodextrin-functionalized polyacrylamide and its application for enhancing oil recovery.

In this paper, β-cyclodextrin was successfully modified by maleic anhydride under certain experimental conditions. A novel water-soluble nanocomposite (AAMC-S1) consisting of nano-SiO was synthesized by free-radical polymerization using acrylamide (AM), 2-acrylamido-2-methyl propane sulfonic acid (AMPS) and modified β-cyclodextrin (MAH-β-CD) as raw materials. The characterization of AAMC-S1 was measured by Fourier transform infrared spectroscopy (FT-IR), H nuclear magnetic resonance spectroscopy (H NMR), thermal degradation (TGA) and scanning electron microscopy (SEM).

Multicolor carbon nanodots from food waste and their heavy metal ion detection application.

Multicolor carbon dots (C-dots) have excellent performance characteristics, high photoluminescence efficiency, ease of fabrication and low toxicity. C-dots have been used in a wide variety of fields including bioimaging, biomedicine, photocatalysis and environmental monitoring. The mass production of multicolor CDs using low-cost, facile methods is an important issue for future industrial applications.

Zr-Induced high temperature resistance of polymer microsphere based on double crosslinked structure.

In order to obtain polymer microspheres for profile control and water shutoff with high temperature resistance and good swelling properties, micrometer microspheres with a double crosslinked structure were synthesized using the monomers acrylamide (AM), -vinylpyrrolidone (NVP) and 2-acrylamide-2-methylpropanesulfonic acid (AMPS), an initiator of potassium persulfate, a crosslinking agent of ,-methylene bis acrylamide and zirconium acetate. The crosslinked Zr-AM/NVP/AMPS microspheres were fully characterized with several means including FT-IR, C NMR, TG-DSC and SEM. Metal crosslinking was introduced into the polymer microspheres to improve the temperature resistance by crosslinking the hydrolyzed polymer molecular chains.

Pore structure characteristics and methane adsorption and desorption properties of marine shale in Sichuan Province, China.

Shale gas is one of the most promising resources for unconventional natural gas. Several shale samples were collected from the Silurian Longmaxi Formation in the Yibin region, Sichuan Province, China. The basic geological parameters of the shale samples including total organic carbon, clay mineral content, and vitrinite reflectance were detected.