Catalytic behavior of a ZnO/TiO composite in the synthesis of polycarbonate diol.

ZnO/TiO catalysts with different ZnO contents have been prepared through equal volume impregnation method, characterized by XRD, SEM, Py-IR, ICP, XPS, NH-TPD and N adsorption/desorption, and evaluated in the synthesis of polycarbonate diol (PCDL) through transesterification. The results showed that titanium zinc oxide formed in these catalysts, and the content of acidic sites varied with the ZnO content, and ZnO/TiO (10%) has the highest acid amount. The ZnO/TiO (20%) with medium acidic sites showed the highest catalytic activity.