Thermal, mechanical, and dielectric properties of high performance PEEK/AIN nanocomposites.

The mechanical, thermal, and dielectric properties of novel high performance poly(ether-ether-ketone) (PEEK)/AIN nanocomposites were discussed. The stiffness of the nanocomposites was significantly improved in the glassy state as well as rubbery state. The coefficient of thermal expansion (CTE) of the nanocomposites was found substantially lower than that of pure PEEK.

Tuned optical properties of in-situ synthesized m-nitroaniline doped Ag/PVA nano-composites.

Meta-nitroaniline (m-NA) doped silver/poly(vinylalcohol) (Ag/PVA) nanocomposites are prepared via in-situ reduction of silver salt by employing hydrazine hydrate (HH) in order to study the effect of the NLO active m-NA on the optical properties of nanoparticles of silver in the colloidal as well as self supported film form. Reduction of silver salt in aqueous alcoholic PVA with HH is done first followed by doping of the reaction mixture with m-NA. The UV-Visible absorption spectra show peak at about 400 nm for Ag nanoparticles due to surface plasmon resonance phenomenon, which gets blue shifted with the change in m-NA concentration.

Direct synthesis of nanocrystalline silver from the reaction between silver carboxylates and n-trioctylphosphine.

Neat n-Trioctylphosphine (TOP) has been used for the first ever time for reduction of silver nitrate and silver carboxylates (citrate, oleate, and myristate) under mild thermal reaction conditions. UV-visible absorption measurements of re-dispersible silver particles that were obtained by reduction of silver myristrate (product-IV) and silver nitrate (product-I) showed surface plasmon resonance absorption peak at 400 nm. The powder XRD pattern of fcc zero-valent silver resulted in diameters in the range of about 25-30 nm.