Synthesis, characterisation and evaluation of polydithiocarbamate resin supported on macroreticular styrene-divinylbenzene copolymer for the removal of trace and heavy metal ions.

A new chelating resin was synthesised by the modification of styrene-divinylbenzene (2%) copolymer and incorporation of dithiocarbamate groups. The polydithiocarbamate resin was characterised by elemental analysis, thermal studies and IR studies. The analytical characteristics of the sorbent were established and optimum sorption conditions for Cu, Ni, Pb, Fe, As and Mn determined.

In situ electrocatalytic oxidation of acid violet 12 dye effluent.

Electrochemical treatment of organic pollutants is a promising treatment technique for substances which are recalcitrant to biodegradation. Experiments were carried out to treat acid violet 12 dye house effluent using electrochemical technique for removal color and COD reduction covering wide range in operating conditions. Ruthenium/lead/tin oxide coated titanium and stainless steel were used as anode and cathode, respectively.

Electrochemical removal of chromium from wastewater by using carbon aerogel electrodes.

A study has been carried out to determine the feasibility of electrochemical removal of chromium ions from industrial wastewater using carbon aerogel electrodes. In this work the effect of key variables including pH (2-7), concentration 2-8 (mg/l), and charge 0.3-1.

Mercury (II) removal from water by coconut shell based activated carbon: batch and column studies.

This study was undertaken to investigate adsorption behavior of Hg (II) from aqueous systems on activated carbon in static and dynamic mode by varying initial Hg (II) concentration, adsorbent dose and pH. Langmuir and Freundlich adsorption isotherm were applied to model the adsorption data. Removal of mercury obeyed the Langmuir and Freundlich adsorption isotherm models.

Photodegradation of direct yellow-12 using UV/H2O2/Fe2+.

A detailed investigation of photodegradation of direct yellow-12 (DY12) using UV/H(2)O(2)/Fe(2+) has been carried out in a photochemical reactor. Experiments studied degradation as a function of concentration, decolorization and reduction in chemical oxygen demand (COD). The effect of operating parameters, such as UV, pH, amount of Fenton's reagent (H(2)O(2) and FeSO(4)), and amount of DY12 dye has also been determined.

Quantitative risk assessment for accidental release of titanium tetrachloride in a titanium sponge production plant.

This paper outlines the quantitative risk assessment for storage and purification section of a titanium sponge production facility. Based on qualitative HAZAN technique, which involves a detailed FETI and HAZOP study of the entire plant, the storage and the purification section were found to be the most hazardous sections. Titanium tetrachloride (TiCl(4)) is the major reactant used in this plant.

Studies on photo-degradation of 2,4-dinitro toluene in aqueous phase.

The efficiency of different photo-degradation processes was evaluated for degrading 2,4-dinitro toluene (DNT) in aqueous phase. The rate and extent of DNT degradation and removal of total organic carbon (TOC) and total nitrogen (TN) contents were compared for direct photolytic and photo-oxidative reactions using various concentrations of H2O2 and Fenton's reagent with a 125 W medium pressure UV lamp. DNT was degraded rapidly under photo-oxidative conditions.

Development of adsorptive removal process for treatment of explosives contaminated wastewater using activated carbon.

The adsorption characteristics of nitro-organics such as trinitro-toluene (TNT), dinitro-toluene (DNT) and nitrobenzene (NB) on granular activated carbon (GAC) were studied to understand their dynamic adsorption behaviour for dilute aqueous solutions. A model was developed to predict the dynamics of the adsorption process and the effect of various design and operating parameters on adsorption characteristics. The model predictions would provide inputs to design of bench scale and pilot plant scale experiments.

Radiation dose estimates in Indian adults in normal and pathological conditions due to 99Tcm-labelled radiopharmaceuticals.

ICRP Publications 53, 62 and 80 give organ dose coefficients and effective doses to ICRP Reference Man and Child from established nuclear medicine procedures. However, an average Indian adult differs significantly from the ICRP Reference Man as regards anatomical, physiological and metabolic characteristics, and is also considered to have different tissue weighting factors (called here risk factors). The masses of total body and most organs are significantly lower for the Indian adult than for his ICRP counterpart (e.