20 results match your criteria: "Centre for Advanced Studies in Earth Sciences[Affiliation]"

Synthesis of solid sodium silicate from waste glass and utilization on one-part alkali-activated materials based on spent oil filtering earth.

Environ Sci Pollut Res Int

May 2024

Department of Chemical, Environmental, and Materials Engineering, Higher Polytechnic School of Jaén, University of Jaén, Campus Las Lagunillas S/N, 23071, Jaén, Spain.

Alkali activated materials (AAMs) commonly known as geopolymers are considered ecofriendly substitutes for Portland cement. However, these materials still have a significant environmental impact, owing mainly to the use of activators based on commercial chemical products. In this sense, this research focuses on the production and use of waste glass-derived activators AAMs as an alternative to commercial activators.

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A grapevine shoot extract (GSE) was obtained using ultrasound-assisted extraction and characterized. The main phenolic constituents were identified as stilbenoids. Among them, -resveratrol and -ε-viniferin stood out.

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The aim of the current work was to examine for the first time the nephropreventive capacity of seed extract (E) against maternal exposure to acephate in rat offspring. The in vivo results revealed that supplementation for 28 days (40 mg/kg b.w.

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Biocidal and synergistic effect of three types of biologically synthesised silver/silver chloride nanoparticles.

World J Microbiol Biotechnol

November 2023

Department of Chemical, Environmental and Materials Engineering, Universidad de Jaén, Campus Las Lagunillas, 23071, Jaén, Spain.

Three types of silver/silver chloride nanoparticles were obtained by green synthesis from three types of microbial biomass. Their biocidal capacity was tested against six microorganisms. Two filamentous fungi were used that had previously demonstrated the ability to synthesise nanoparticles, Penicillium sp.

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The aim of the present study was to examine, for the first time, the phytochemical content of pulp extract (EAP) and explore its antioxidant and anti-inflammatory capacities. High-performance liquid chromatography-electrospray ionization-quadrupole-time-of-flight mass spectrometry (HPLC-ESI-QTOF/MS) was used for phytochemical analysis and three in vitro antioxidant assays together with three in vitro anti-inflammatory tests were used for the assessment of biological activity. The HPLC-ESI-QTOF/MS analysis revealed the presence of 42 metabolites, including flavonoids, sphingolipides, fatty acids, ephedrine derivatives, and amino acid derivatives.

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Ag(I) Biosorption and Green Synthesis of Silver/Silver Chloride Nanoparticles by 1S1.

Nanomaterials (Basel)

January 2023

Department of Chemical, Environmental and Materials Engineering, Universidad de Jaén, Campus Las Lagunillas, 23071 Jaén, Spain.

Article Synopsis
  • The study investigates the biosorption efficiency of 1S1 for Ag(I) and its capability to synthesize recoverable silver nanoparticles.
  • Kinetic and thermodynamic tests were conducted at three temperatures, revealing optimal conditions at 27 °C and establishing the sorption process fits a pseudo second-order model and the Freundlich isotherm.
  • Findings demonstrated a maximum biosorption capacity of 137.2 mg/g at 19 °C for a metal concentration of 459 mg/L, along with the successful synthesis of silver nanoparticles ranging from 12 nm to 20 nm.
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Deep eutectic solvents for improved biomass pretreatment: Current status and future prospective towards sustainable processes.

Bioresour Technol

February 2023

Department of Chemical, Environmental and Materials Engineering, Centre for Advanced Studies in Earth Sciences, Energy and Environment (CEACTEMA), Universidad de Jaén, Campus Las Lagunillas, Jaén 23071, Spain. Electronic address:

Pretreatment processes - recognized as critical steps for efficient biomass refining - have received much attention over the last two decades. In this context, deep eutectic solvents (DES) have emerged as a novel alternative to conventional solvents representing a step forward in achieving more sustainable processes with both environmental and economic benefits. This paper presents an updated review of the state-of-the-art of DES-based applications in biorefinery schemes.

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Extraction Systems and Analytical Techniques for Food Phenolic Compounds: A Review.

Foods

November 2022

Department of Chemical, Environmental and Materials Engineering, Centre for Advanced Studies in Earth Sciences, Energy and Environment (CEACTEMA), Universidad de Jaén, Campus Las Lagunillas, s/n, 23071 Jaén, Spain.

Phenolic compounds are highly valuable food components due to their potential utilisation as natural bioactive and antioxidant molecules for the food, cosmetic, chemical, and pharmaceutical industries. For this purpose, the development and optimisation of efficient extraction methods is crucial to obtain phenolic-rich extracts and, for some applications, free of interfering compounds. It should be accompanied with robust analytical tools that enable the standardisation of phenolic-rich extracts for industrial applications.

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Exhausted olive pomace (EOP) is produced in olive-pomace oil extractors as a by-product. However, the obtention of bioactive compounds from EOP can reinsert it into the economy as a new bioresource before applying other exploitation ways. The objective of the present study was to investigate the phytochemical differences between aqueous and aqueous acetonic extracts from EOP (AE-EOP and AAE-EOP, respectively) obtained by hydrothermal and ultrasound-assisted extraction, respectively.

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Due to population growth in the coming years, an increase in agricultural production will soon be mandatory, thus requiring fertilizers that are more environmentally sustainable than the currently most-consumed fertilizers since these are important contributors to climate change and water pollution. The objective of this work is the techno-economic evaluation of the production of biofertilizer concentrated in free amino acids from microalgal biomass produced in a wastewater treatment plant, to determine its economic viability. A process proposal has been made in six stages that have been modelled and simulated with the ASPEN Plus simulator.

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Optimization of Microwave-Assisted Water Extraction to Obtain High Value-Added Compounds from Exhausted Olive Pomace in a Biorefinery Context.

Foods

July 2022

Department of Chemical, Environmental and Materials Engineering, Universidad de Jaén, Campus Las Lagunillas, 23071 Jaén, Spain.

Microwave-assisted water extraction (MAWE) was evaluated to obtain the valuable bioactive compounds hydroxytyrosol and mannitol from exhausted olive pomace (EOP). The influence of the operational parameters solid loading (3-15%, /), temperature (40-100 °C), and extraction time (4-40 min) was studied using an experimental design. The optimized conditions maximizing their joint extraction were 12% / solid loading, 100 °C temperature, and 16 min.

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Biotechnological use of the ubiquitous fungus Penicillium sp. 8L2: Biosorption of Ag(I) and synthesis of silver nanoparticles.

J Environ Manage

August 2022

Department of Chemical, Environmental and Materials Engineering, Universidad de Jaén, Campus Las Lagunillas, 23071, Jaén, Spain; Centre for Advanced Studies in Earth Sciences, Energy and Environment (CEACTEMA), Universidad de Jaén, Campus Las Lagunillas, 23071, Jaén, Spain.

In this work, the efficiency of the ubiquitous fungus Penicillium sp. 8L2 to remove Ag(I) ions from synthetic solutions and its potential to synthesize silver nanoparticles (AgNPs) was evaluated. Using a Rotatable Central Composite Design pH and biomass concentration were optimized.

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Sequential Extraction of Hydroxytyrosol, Mannitol and Triterpenic Acids Using a Green Optimized Procedure Based on Ultrasound.

Antioxidants (Basel)

November 2021

Department of Chemical, Environmental and Materials Engineering, Universidad de Jaén, Campus Las Lagunillas, S/N, 23071 Jaén, Spain.

Olive-derived biomasses contain bioactive compounds with health promoting effects as well as antioxidant and sweet-tasting properties. However, their sequential extraction has not been attained. In the present study, firstly antioxidants and mannitol were extracted from exhausted olive pomace (EOP) by an eco-friendly method, ultrasound-assisted water extraction (UAWE).

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Biosorption mechanisms of Ag(I) and the synthesis of nanoparticles by the biomass from Botryosphaeria rhodina MAMB-05.

J Hazard Mater

October 2021

Department of Chemical, Environmental and Materials Engineering, Universidad de Jaén, Campus Las Lagunillas, 23071 Jaén, Spain; Centre for Advanced Studies in Earth Sciences, Energy and Environment (CEACTEMA), Universidad de Jaén, Campus Las Lagunillas, 23071 Jaén, Spain.

Two biomass types of Botryosphaeria rhodina MAMB-05 (VMSM and M3) were evaluated to determine their effectiveness in removing Ag(I) ions from synthetic solutions. Both biomass types obtained good results in the biosorption process with maximum biosorption capacities (q) for the Langmuir model of 34.67 and 39.

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Article Synopsis
  • Exhausted olive pomace (EOP) is a significant agro-industrial waste that contains valuable phenolic compounds and mannitol, making its bioactive extraction a key step for its valorization.
  • A study utilized ultrasound-assisted extraction (UAE) to optimize conditions for extracting these compounds, determining the best results with 40% acetone, 8.6% solids, and 43 minutes of extraction time.
  • Additionally, a probe-type UAE method was tested to reduce extraction time, successfully achieving similar phenolic compound levels in just 12 minutes, which may lower costs in industrial applications.
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Exhausted olive pomace (EOP) is the waste generated from the drying and subsequent extraction of residual oil from the olive pomace. In this work, the effect of different aqueous solvents on the recovery of antioxidant compounds from this lignocellulosic biomass was assessed. Water extraction was selected as the best option for recovering bioactive compounds from EOP, and the influence of the main operational parameters involved in the extraction was evaluated by response surface methodology.

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Optimization with Response Surface Methodology of Microwave-Assisted Conversion of Xylose to Furfural.

Molecules

August 2020

Department of Chemical, Environmental and Materials Engineering, Universidad de Jaén, Campus Las Lagunillas, 23071 Jaén, Spain.

The production of furfural from renewable sources, such as lignocellulosic biomass, has gained great interest within the concept of biorefineries. In lignocellulosic materials, xylose is the most abundant pentose, which forms the hemicellulosic part. One of the key steps in the production of furfural from biomass is the dehydration reaction of the pentoses.

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Extraction Strategies to Recover Bioactive Compounds, Incorporation into Food and Health Benefits: Current Works and Future Challenges.

Foods

March 2020

Department of Chemical, Environmental and Materials Engineering, Universidad de Jaén, Campus Las Lagunillas, 23071 Jaén, Spain.

There are numerous studies in the literature about bioactive products (extracts, essential oils, oleoresins, hydrolysates, etc [...

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This study aimed to investigate the effects that stand age and forest structure have on microbiological soil properties, enzymatic activities and nutrient content. Thirty forest compartments were randomly selected at the Palancares y Agregados managed forest area (Spain), supporting forest stands of five ages; from 100 to 80years old to compartments with trees that were 19-1years old. Forest area ranging from 80 to 120years old and without forest intervention was selected as the control.

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