Innovative alginate-clay shell and magnetite-gelatin core composite for multifaceted contaminant removal: Cadmium, thiabendazole and bacterial adsorption from aqueous solutions.

In this study, a novel magnetic composite adsorbent with an alginate-chamotte clay outer layer and a gelatin-magnetite core was synthesised for effective contaminant removal from aqueous solutions. The alginate component ensures biocompatibility, chamotte clay enhances adsorption, gelatin provides mechanical strength, and magnetite enables easy recovery of the adsorbent. The composite material was characterised using Fourier-transform infrared, X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy-energy-dispersive X-ray analysis, micro-computed tomography, Brunauer-Emmett-Teller analysis and dynamic mechanical analysis techniques.

Concentrations of radionuclides and trace elements in wetlands.

Environmental risks in wetlands are considered with radionuclides and trace elements to understand pollution accumulation. In this study, we aimed to determine the levels of radiation and heavy metals in water systems and assess pollution configurations. Radionuclides (Rn, Pb and Po) and trace elements (Ag, As, Ba, Be, Cd, Co, Cr, Cu, Fe, Li, Mo, Ni, Pb, V and Zn) were measured to evaluate anthropogenic factors.

Cytotoxicity of subcritical water extracts obtained from byproducts generated at commercial pecan shelling operations on cancer cells.

This study examined potential of the extracts obtained from the byproducts generated at commercial pecan nut-shelling operations in cancer treatment. The subcritical water extracts obtained from two varieties, Native and Pawnee, were analyzed for their phenolic contents and compositions. Effects of the extracts on viability and IC50 of the human cell lines representing a broad range of cancer types, cervical, lung, skin, breast, colon and prostate cancers, were investigated.

Variability of Isoquinoline Alkaloid Profiles and Anticholinesterase Activities with Binding-Mode Predictions of Glaucium flavum Population.

In this study, phytochemical and biological activity studies supported by docking were carried out on a species of the genus Glaucium, a repository of isoquinoline alkaloids. The GC-MS (Gas Chromatography-Mass Spectrometry) method is used to characterize the isoquinoline alkaloids of Glaucium flavum Crantz. (Papaveraceae).

Magnetic Hydrogel Beads as a Reusable Adsorbent for Highly Efficient and Rapid Removal of Aluminum: Characterization, Response Surface Methodology Optimization, and Evaluation of Isotherms, Kinetics, and Thermodynamic Studies.

Biopolymers such as alginate and gelatin have attracted much attention because of their exceptional adsorption properties and biocompatibility. The magnetic hydrogel beads produced and used in this study had a core structure composed of magnetite nanoparticles and gelatin and a shell structure composed of alginate. The combination of the metal-ion binding ability of alginate and the mechanical strength of gelatin in magnetic hydrogel beads presents a new approach for the removal of metal from water sources.

Metal-organic framework functionalized with deep eutectic solvent for solid-phase extraction of Rhodamine 6G in water and cosmetic products.

An NH -MIL-53(Al)-DES(ChCl-Urea) nanocomposite was synthesized for extraction and determination of Rhodamine (Rh) 6G from environmental and cosmetic samples. The deep eutectic solvent (DES) was prepared by mixing choline chloride and urea in a mole ratio of 1:2. NH -MIL-53(Al)-DES(ChCl-Urea) nanocomposite was synthesized using the impregnation method at a ratio of 60:40 (w/w).

FeO-SiO-MIL-53 (Fe) nanocomposite for magnetic dispersive micro-solid phase extraction of cadmium (II) at trace levels prior to HR-CS-FAAS detection.

A magnetic metal-organic framework FeO-SiO-MIL-53 (Fe) nanocomposite was synthesized for magnetic dispersion micro-solid phase extraction (M-d-µSPE) of cadmium in water, spice, chocolate, tea, and tobacco samples prior to the detection by flame atomic absorption spectrometry. FeO-SiO-MIL-53 (Fe) nanocomposite fabricated using the solvothermal technique was characterized using a field emission scanning electron microscope and X-ray diffraction. The extraction efficiency of the method was improved by optimizing the experimental factors.

Sample Preparation Methods for Metal Containing Pesticides in Food and Environmental Samples.

Metal-containing pesticides are used in many areas for purposes such as harvest efficiency and keeping pests away from the vegetable environment. Metal-containing pesticides are in the form of dithiocarbamate complexes and are named differently according to the type of metal they contain and are used for different purposes. Since the presence of these pesticides even at residue level threatens human and environmental health, their determination at trace level is important.

Chemical Composition and Antioxidant Properties of Pecan Shell Water Extracts.

This study examined the chemical composition and antioxidant properties of the extracts obtained from two byproduct streams generated at a commercial pecan nut shelling operation. Byproduct stream F contained more pecan nut meat pieces and packing material than stream S, consisting of mainly hard outer shell pieces. Samples from Native variety nuts were processed using subcritical, sonication aided and microwave heating, using water as a solvent.

Role of Intermediate Filaments in Blood-Brain Barrier in Health and Disease.

The blood-brain barrier (BBB) is a highly selective cellular monolayer unique to the microvasculature of the central nervous system (CNS), and it mediates the communication of the CNS with the rest of the body by regulating the passage of molecules into the CNS microenvironment. Limitation of passage of substances through the BBB is mainly due to tight junctions (TJ) and adherens junctions (AJ) between brain microvascular endothelial cells. The importance of actin filaments and microtubules in establishing and maintaining TJs and AJs has been indicated; however, recent studies have shown that intermediate filaments are also important in the formation and function of cell-cell junctions.

In Vitro Human Blood-Brain Barrier Model for Drug Permeability Testing.

Blood-brain barrier (BBB), although very important for protection of brain from major neurotoxins, negatively affects the treatment of central nervous system diseases by limiting the passage of neuropharmaceuticals from blood to the brain. Thus, researchers have to investigate the passage of the produced drug molecules through the BBB before they are introduced to the market. Although these experiments have been traditionally performed on experimental animals, drug permeability tests are now carried out mostly by in vitro BBB models due to ethical problems, differences between species, and expensive and troublesome in vivo test procedures.

Mechanobiology of cells and cell systems, such as organoids.

Organoids are in vitro 3D self-organizing tissues that mimic embryogenesis. Organoid research is advancing at a tremendous pace, since it offers great opportunities for disease modeling, drug development and screening, personalized medicine, as well as understanding organogenesis. Mechanobiology of organoids is an unexplored area, which can shed light to several unexplained aspects of self-organization behavior in organogenesis.

Optimization of chitosanase production by Bacillus mojavensis EGE-B-5.2i.

Maximum production of industrially important enzymes such as chitosanases through media optimization still holds foremost interest. The present study was conducted to improve chitosanase activity of an indigenous strain identified as Bacillus mojavensis. Initially, carbon and nitrogen sources were optimized by one-variable-at-a-time approach.