Correction: Controlling barrier height and spectral responsivity of p-i-n based GeSn photodetectors arsenic incorporation.

[This corrects the article DOI: 10.1039/D3RA00805C.].

Efficacious elimination of crystal violet pollutant via photo-Fenton process based on GdLaZrO nanoparticles.

The photo-Fenton process is an appropriate method of the Advanced Oxidation Process that is used in the photocatalysis of organic dyes like crystal violet (CV). La ion substituted gadolinium zirconium oxide GdLaZrO nanopowders (x = 0.1, 0.

The origin of Neolithic copper on the central Northern European plain and in Southern Scandinavia: Connectivities on a European scale.

The production, distribution and use of copper objects and the development of metallurgical skills in Neolithic Northern Central Europe and Southern Scandinavia are linked to early centres of copper metallurgy of South East Central Europe and Southeast Europe. A total of 45 Neolithic copper objects, until now the largest sample of Early Neolithic objects from the Northern Central European Plain and Southern Scandinavia, were selected for new lead isotope analyses. They aided in the identification of the origin of the copper: These new analyses indicate that the copper ore deposits in Southeastern Europe, especially from the Serbian mining areas, were used for the Early Neolithic northern artefacts (ca.

An economical electrocoagulation process of a hazardous anionic azo dye wastewater with the combination of recycled electrodes and solar energy.

The energy and electrode costs are the restrictions of applying electrocoagulation (EC) in wastewater treatment and many attempts have been made to decrease these costs. In this study, an economical EC was investigated to treat a hazardous anionic azo dye wastewater (DW) that threatens the environment and human health. Firstly, an electrode for EC process was produced from recycled aluminum cans (RACs) by remelting in an induction melting furnace.

Powder metallurgy as a perfect technique for preparation of Cu-TiO composite by identifying their microstructure and optical properties.

Powder metallurgy (PM) is a technique that involves the manufacturing of metal powders and their consolidation into finished products or components. This process involves the mixing of metal powders with other materials such as ceramics or polymers, followed by the application of heat and pressure to produce a solid, dense material. The use of PM has several advantages over traditional manufacturing techniques, including the ability to create complex shapes and the production of materials with improved properties.

Pollution trends and ecological risks of heavy metal(loid)s in coastal zones of Bangladesh: A chemometric review.

Heavy metal(loid)s inputs contribute to human and environmental stresses in the coastal zones of Bangladesh. Several studies have been conducted on metal(loid)s pollution in sediment, soil, and water in the coastal zones. However, they are sporadic, and no attempt has been made in coastal zones from the standpoint of chemometric review.

Enhancement of quasi-static compression strength for aluminum closed cell foam blocks shielded by aluminum tubes.

Aluminum closed cell foam blocks are created with a volume of 1 inch which consist of aluminum foam parts shielded with part of aluminum tube and in some types reinforced with inner aluminum tubes. Blocks have been made to overcome some existing problems in metallic foam used to protect some applications parts from impacts as a sacrificial part. Metallic foam has three main categories sandwich panels, filled tubes and corrugated sheets.

Removal of chemical oxygen demand and ammonia nitrogen from high salinity tungsten smelting wastewater by one-step electrochemical oxidation: From bench-scale test, pilot-scale test, to industrial test.

In recent years, electrochemical oxidation (EO) shows the characteristics of green and high efficiency in removing chemical oxygen demand (COD) and ammonia nitrogen (NH-N) from wastewater, which has been favored by researchers. However, at present, most of current studies on EO remain in laboratory stage, reports about pilot-scale or even industrial tests with large treatment capacity are few, which slowing down the use of the advanced technology to practical application. In this study, bench-scale tests, pilot-scale tests (treatment capacity 200-500 L/h), and industrial tests (treatment capacity 100 m/h) were carried out by EO technology in view of the characteristics of tungsten smelting wastewater (TSW) with high salinity (NaCl), COD, and NH-N.

A Novel Approach of Optimum Time Interval Estimation for Al-7.5Si/Al-18Si Liquid-Liquid Bimetal Casting in Sand and Metallic Moulds.

This work describes a novel approach for Al-7.5Si/Al-18Si liquid-liquid bimetal casting in sand and metallic moulds. The aim of the work is to facilitate and develop a simple procedure to produce an Al-7.

A novel test device and quantitative colorimetric method for the detection of human chorionic gonadotropin (hCG) based on Au@Zn-salen MOF for POCT applications.

The human chorionic gonadotropin (hCG) hormone is a biomarker that can predict tumors and early pregnancy; however, it is challenging to develop sensitive qualitative-quantitative procedures that are also effective, inventive, and unique. In this study, we used a novel easy reaction of an organic nano-linker with Zn(NO)·6HO and HAuCl·3HO to produce a gold-zinc-salen metal-organic framework composite known as Au-Zn-Sln-MOF. A wide variety of micro-analytical instruments and spectroscopic techniques were used in order to characterize the newly synthesized Au-Zn-Sln-MOF composite.

Thermal and Radiation Stability in Nanocrystalline Cu.

Nanocrystalline metals have presented intriguing possibilities for use in radiation environments due to their high grain boundary volume, serving as enhanced irradiation-induced defect sinks. Their promise has been lessened due to the propensity for nanocrystalline metals to suffer deleterious grain growth from combinations of irradiation and/or elevated homologous temperature. While approaches for stabilizing such materials against grain growth are the subject of current research, there is still a lack of central knowledge on the irradiation-grain boundary interactions in pure metals despite many studies on the same.

Recovery of Valuable Materials from End-of-Life Photovoltaic Solar Panels.

The disposal of end-of-life (EOL) photovoltaic solar panels has become a relevant environmental issue as they are considered to be a hazardous electronic waste. On the other hand, enormous benefits are achieved from recovering valuable metals and materials from such waste. Eventually, physical and chemical processing will become the most important stages during the recycling process.

A Novel Hydro-Thermal Synthesis of Nano-Structured Molybdenum-Iron Intermetallic Alloys at Relatively Low Temperatures.

Nano-structured Mo/Fe intermetallics were synthesized from precursors that contained 72/28% and 30/70% molar ratios of Mo/Fe, which were given as precursors A and B, respectively. These precursors were prepared from the co-precipitation of aqueous hot solutions of ammonium heptamolybdate tetrahydrate (AHM) and ferrous oxalate. The dry precipitates were thermally treated using TG-DSC to follow up their behavior during roasting, in an Ar atmosphere of up to 700 °C (10° K/min).

Microstructure and Mechanical Properties of Gradient Interfaces in Wire Arc Additive Remanufacturing of Hot Forging Die Steel.

Hot forging dies are subjected to periodic thermal stress and often fail in the forms of thermal fatigue, wear, plastic deformation, and fracture. A gradient multi-material wire arc additive remanufacturing method for hot forging dies was proposed to extend the service life of hot forging dies and reduce total production costs. The properties of multi-material gradient interfaces play a critical role in determining the overall performance of the final products.

Rational optimization of g-CN/CoO nanocomposite for enhanced photodegradation of Rhodamine B dye under visible light.

Heterogeneous catalysis is widely known as an efficient, clean, and low-cost technology to mitigate the environmental pollution of industrial effluents. This research aimed at optimizing the preparation and characterization of efficient g-CN/CoO nanocomposite for catalytic removal of Rhodamine B (Rh B) dye. The detected XRD peaks for the prepared nano-CoO are matched with the cubic crystal structure.

Metallurgical investigation of early failure of heater pipes in a gas complex.

An early corrosion failure of the piping system of a gas heater was reported by a gas complex company. Local corrosion rates of 0.90 and 0.

Structural, Optical, and Electrical Investigations of NdO-Doped PVA/PVP Polymeric Composites for Electronic and Optoelectronic Applications.

In this present work, a PVA/PVP-blend polymer was doped with various concentrations of neodymium oxide (PB-Nd) composite films using the solution casting technique. X-ray diffraction (XRD) analysis was used to investigate the composite structure and proved the semi-crystallinity of the pure PVA/PVP polymeric sample. Furthermore, Fourier transform infrared (FT-IR) analysis, a chemical-structure tool, illustrated a significant interaction of PB-Nd elements in the polymeric blends.

Investigations of Abrasive Wear Behaviour of Hybrid High-Boron Multi-Component Alloys: Effect of Boron and Carbon Contents by the Factorial Design Method.

This paper is devoted to the evaluation of the "three-body-abrasion" wear behaviour of (wt.%) 5W-5Mo-5V-10Cr-2.5Ti-Fe (balance) multi-component (C + B)-added alloys in the as-cast condition.

Controlling barrier height and spectral responsivity of p-i-n based GeSn photodetectors arsenic incorporation.

GeSn compounds have made many interesting contributions in photodetectors (PDs) over the last ten years, as they have a detection limit in the NIR and mid-IR region. Sn incorporation in Ge alters the cut off wavelength. In the present article, p-i-n structures based on GeSn junctions were fabricated to serve as PDs.

Effect of heat treatment atmospheres on microstructure evolution and corrosion resistance of 2205 duplex stainless steel weldments.

The effects of post heat treatment atmosphere on microstructure and corrosion resistance of duplex stainless steel welded joints were investigated. Post weld heat treatment (PWHT) was carried out with and without protective atmospheres. Nitrogen and argon are used as protective gases individually.

Insights into the mechanism of persulfate activation with carbonated waste metal adsorbed resin for the degradation of 2,4-dichlorophenol.

Superabsorbent resin (SAR) saturated with heavy metals poses a threat to surrounding ecosystem. To promote the reutilization of waste, resins adsorbed by Fe and Cu were carbonized and used as catalysts (Fe@C/Cu@C) to activate persulfate (PS) for 2,4-dichlorophenol (2,4-DCP) degradation. The heterogeneous catalytic reaction was mainly responsible for 2,4-DCP removal.

Utilisation of an active branching sucrase from Lactobacillus kunkeei AP-37 to produce techno-functional poly-oligosaccharides.

Glucansucrase AP-37 was extracted from the culture supernatant of Lactobacillus kunkeei AP-37 and characteristics of the glucan produced by the active glucansucrase in terms of structural and functional roles were determined in this study. A molecular weight around 300 kDa was observed for glucansucrase AP-37 and its acceptor reactions with maltose, melibiose and mannose were also conducted to unveil the prebiotic potential of the poly-oligosaccharides formed via these reactions. The core structure of glucan AP-37 was determined by H and C NMR and GC/MS analysis which revealed that glucan AP-37 was a highly branched dextran composing of high levels of (1 → 3)-linked α-d-glucose units with low levels of (1 → 2)-linked α-d-glucose units.

A Fresh One-Step Spray Pyrolysis Approach to Prepare Nickel-Rich Cathode Material for Lithium-Ion Batteries.

The Ni-rich layered cathode material LiNiCoMnO (NCM811) with high specific capacity and acceptable rate performance is one of the key cathode materials for high-energy-density lithium-ion batteries. Coprecipitation, the widely utilized method in the precursor synthesis of NCM811 materials, however, suffers long synthetic processes and challenges in uniform element distribution. The spray pyrolysis method is able to prepare oxide precursors in seconds where all transition-metal elements are well distributed, but the difficulty of lithium distribution will also arise when the lithium salts are added in the subsequent sintering process.

Facile Strategy for Fabricating an Organosilica-Modified FeO (OS/FeO) Hetero-nanocore and OS/FeO@SiO Core-Shell Structure for Wastewater Treatment with Promising Recyclable Efficiency.

The development of a sustainable process for heavy metal ion remediation has become a point of interest in various fields of research, including wastewater treatment, industrial development, and health and environmental safety. In the present study, a promising sustainable adsorbent was fabricated through continuous controlled adsorption/desorption processes for heavy metal uptake. The fabrication strategy is based on a simple modification of FeO magnetic nanoparticles with organosilica in a one-pot solvothermal process, carried out in order to insert the organosilica moieties into the FeO nanocore during their formation.