Bottom-up and top-down approaches for estimating road dust emission and correlating it with a receptor model results over a typical urban atmosphere of Indo Gangetic Plain.

To investigate the emission and concentration of PM and PM-related road dust over Agra, a typical semi-arid urban atmosphere of the Indo Gangetic Plain (IGP), a fine-resolution emission inventory and receptor modeling-based source apportionment was undertaken for the year 2019. On-road, the silt load of Agra (7-55 g/m of the road) was found to be 10 to 50 times higher than that reported in advanced countries. The silt load over Agra varied widely depending on road conditions, long-range transport, and land-use pattern.

Study of Tunable Dielectric Permittivity of PBDB-T-2CL Polymer in Ternary Organic Blend Thin Films Using Spectroscopic Ellipsometry.

The ellipsometric analyses reported in this paper present a novelty by bringing an in-depth optical investigation of some ternary organic blends. This study focuses on the tunability and control of the relative permittivity of active layers by varying the weight ratio of blended materials spin-coated as thin films. To investigate this, an extensive approach based on spectroscopic ellipsometry was conducted on ternary blend (D:A:A) thin films, involving a donor [D = chlorinated conjugated polymer (PBDB-T-2Cl)] and two acceptor materials [A = a non-fullerene (ITIC-F) and A = a fullerene (PCBM)].

Mining-related multi-resistance genes in sulfate-reducing bacteria treatment of typical karst nonferrous metal(loid) mine tailings in China.

Management of tailings at metal mine smelter sites can reduce the potential hazards associated with exposure to toxic metal(loid)s and residual organic flotation reagents. In addition, microbes in the tailings harboring multi-resistance genes (e.g.

Photocatalytic Activity of N-Doped ZrO Thin Films Determined by Direct and Indirect Irradiation.

In this paper, we investigate the decomposition of a toxic organic compound, Rhodamine B, by the photocatalytic activities of undoped and nitrogen-doped ZrO thin films, deposited using the HiPIMS technique. The investigation was performed in the presence and in the absence of HO, for two types of experimental arrangements: the irradiation of the films, followed by dipping them in the Rhodamine B solutions, and the irradiation of the films dipped in the solution. The two situations were named "direct irradiation" and "indirect irradiation", respectively.

Band-gap engineering of zirconia by nitrogen doping in reactive HiPIMS: a step forward in developing innovative technologies for photocatalysts synthesis.

In the global context of climate change and carbon neutrality, this work proposes a strategy to improve the light absorption of photocatalytic water-splitting materials into the visible spectrum by anion doping. In this framework, reactive high power impulse magnetron sputtering (HiPIMS) of a pure Zr target in Ar/N/O gas mixture was used for the deposition of crystalline zirconium oxynitride (ZrON) thin films with variable nitrogen doping concentration and energy band-gap. The nitrogen content into these films was controlled by the discharge pulsing frequency, which controls the target surface poisoning and peak discharge current.

Microbial metabolic activity in metal(loid)s contaminated sites impacted by different non-ferrous metal activities.

Many non-ferrous metal mining and smelting activities have caused severe metal(loid) contamination in the local soil environment. The metabolic activity of soil microorganisms in four areas affected by different metallurgical activities (production vs. waste disposal) was characterized using a contamination gradient from the contaminated site to the surrounding soils.

Dithionite accelerated copper slag heterogeneous-homogeneous coupled Fenton degradation of organic pollutants.

The heterogeneous-homogeneous coupled Fenton (HHCF) processes combine the advantages of rapid reaction and the catalyst reuse, which makes them attractive for wastewater treatment. Nevertheless, the lack of both, cost-effective catalysts and the desirable Fe/Fe conversion mediators limit the development of HHCF processes. This study investigates a prospective HHCF process, in which solid waste copper slag (CS) and dithionite (DNT) act as catalyst and mediator of Fe/Fe transformation, respectively.

Adhesion Properties and Stability of Non-Polar Polymers Treated by Air Atmospheric-Pressure Plasma.

Atmospheric-pressure plasma (APP) has advantages for enhancing the adhesion of polymers and has to provide uniform, efficient treatment, which also limits the recovery effect of treated surfaces. This study investigates the effects of APP treatment on polymers that have no oxygen bonded in their structure and varying crystallinity, aiming to assess the maximum level of modification and the post-treatment stability of non-polar polymers based on their initial structure parameters, including the crystalline-amorphous structure. An APP reactor simulating continuous processing operating in air is employed, and the polymers are analyzed using contact angle measurement, XPS, AFM, and XRD.

Analytical study on heavy metal output fluxes and source apportionment of a non-ferrous smelter in southwest China.

Abandoned Pb/Zn smelters are often accompanied by a large amount of smelting slag, which is a serious environmental problem. Previous studies have demonstrated that slag deposits pose an environmental threat even if the smelters are shut down. Herein, a Pb/Zn smelter and its impacted zone in GeJiu, Yunnan, China were selected as the study area.

New insights on the effect of non-ferrous metal mining and smelting activities on microbial activity characteristics and bacterial community structure.

Mining and smelting activities have brought potentially serious heavy metal(loid)s pollution to their surrounding locale. However, studies on microbial metabolic activities, community structure, and adaptation in soils proximal to non-ferrous metal mining and smelting areas are still lacking. Here the effects of biotic and abiotic characteristics of soil taken from sites surrounding inactive and active non-ferrous metal mine smelting facilities on microbial enzyme activity, microcalorimetry, and high-throughput sequencing of 16S rRNA gene barcoding were studied.

Effect of air pollution-controlled residue of a sewage sludge incinerator on the drying shrinkage and the pore structure of alkali-activated materials.

Recycling air pollution-controlled residues (APCR) generated from sewage sludge incinerators can be used for waste management, but the leaching of potentially toxic heavy metals from APCR poses environmental and human health issues. The present paper describes a procedure using APCR to produce alkali-activated materials and thereby realize their disposal. The effect of APCR on the compressive strength and drying shrinkage of the alkali-activated slag/glass powder was investigated.

Quantitation of guanidine derivatives as representative persistent and mobile organic compounds in water: method development.

Persistent and mobile organic compounds (PMOCs) are highly soluble in water, thereby posing a threat to water resource quality. Currently, there are no methods that can accurately quantify guanidine derivative PMOCs, other than 1,3-diphenylguanidine (DPG) and cyanoguanidine (CG), in aqueous media. In this study, we developed a quantitation method that combines solid-phase extraction and liquid chromatography (LC)-tandem mass spectrometry to detect seven guanidine derivatives in aquatic environments and applied it to environmental water samples.

Quantifying ecological and human health risks of metal(loid)s pollution from non-ferrous metal mining and smelting activities in Southwest China.

The environmental release and transfer of heavy metal(loids) from natural and anthropogenic sources to neighboring habitats can pose an ecological threat to the exposed biota and habitat, as well as a human health risk to the residents. However, analytical tools to identify the potential contamination source(s) and assess the impact of this transfer have not been well described. Soil samples were collected from affected areas proximal to non-ferrous metal(loid)s mining and smelting facilities.

Occurrence of halogenated methanesulfonic acids in water and sediment from the Hangzhou Bay, China.

Halogenated methanesulfonic acids (HMSAs) are an important new class of organic compounds as they were universal in the water cycle and drinking water sources. However, no study has investigated the presence of HMSAs in surface water and sediment from China. The present study reports the occurrence and spatiotemporal distribution of seven HMSAs in water and sediment samples from Hangzhou Bay, China.

Structured population balances to support microalgae-based processes: Review of the state-of-art and perspectives analysis.

Design and optimization of microalgae processes have traditionally relied on the application of unsegregated mathematical models, thus neglecting the impact of cell-to-cell heterogeneity. However, there is experimental evidence that the latter one, including but not limited to variation in mass/size, internal composition and cell cycle phase, can play a crucial role in both cultivation and downstream processes. Population balance equations (PBEs) represent a powerful approach to develop mathematical models describing the effect of cell-to-cell heterogeneity.

Humic Substance Photosensitized Degradation of Phthalate Esters Characterized by H and C Isotope Fractionation.

The photosensitized transformation of organic chemicals is an important degradation mechanism in natural surface waters, aerosols, and water films on surfaces. Dissolved organic matter including humic-like substances (HS), acting as photosensitizers that participate in electron transfer reactions, can generate a variety of reactive species, such as OH radicals and excited triplet-state HS (HS*), which promote the degradation of organic compounds. We use phthalate esters, which are important contaminants found in wastewaters, landfills, soils, rivers, lakes, groundwaters, and mine tailings.

Active tailings disturb the surrounding vegetation soil fungal community: Diversity, assembly process and co-occurrence patterns.

Soil fungi play an important role in the soil biogeochemical cycle and are important biological indicators for the ecological remediation of mine tailings contaminated sites, therefore understanding the characteristics of soil fungal communities is a key aspect of pollution remediation. However, the influence of biological factors on the characteristics of fungal community diversity; assembly mechanisms and co-occurrence patterns of fungal community along environmental gradients around tailings are not well understood. In this study, soil samples from forest, agriculture and grass around tailings were collected to reveal the assembly mechanisms and co-occurrence patterns of soil fungal community and to quantify the contribution of abiotic and biotic factors to fungal diversity.

Selective Photocatalytic Transformation of Lignin to Aromatic Chemicals by Crystalline Carbon Nitride in Water-Acetonitrile Solutions.

The photocatalytic conversion of lignin to aromatic compounds in aqueous solutions is a promising approach. We herein report a crystalline carbon nitride prepared by high-temperature thermal polymerization and alkali-metal molten salt treatment, which was then applied in the selective conversion of lignin to aromatic compounds. The results showed that the tri-s-tri-CN presented a relatively high activity and selectivity for the conversion of lignin in aqueous solutions.

Radical chemistry, degradation mechanism and toxicity evolution of BPA in the UV/chlorine and UV/HO.

UV-assisted advanced oxidation processes (AOPs) are widely used and studied in degradation of bisphenol A (BPA). However, detailed information on their radical chemistry and degradation mechanisms is still lacking. In this study, degradation of BPA was comparatively evaluated to investigate the radical mechanisms, products and the toxicity variation in UV/chlorine and UV/HO processes.

The Modulatory Effects of Non-Thermal Plasma on Seed's Morphology, Germination and Genetics-A Review.

Non-thermal plasma (NTP) is a novel and promising technique in the agricultural field that has the potential to improve vegetal material by modulating the expression of various genes involved in seed germination, plant immune response to abiotic stress, resistance to pathogens, and growth. Seeds are most frequently treated, in order to improve their ability to growth and evolve, but the whole plant can also be treated for a fast adaptive response to stress factors (heat, cold, pathogens). This review focuses mainly on the application of NTP on seeds.

Compound-specific isotopic analysis to characterize the photocatalytic reaction of TiO nanoparticles with diethyl phthalate.

In this study compound-specific isotope analysis (CSIA) has been used to explore the degradation mechanism of nano titanium dioxide (TiO) catalyzes photodegradation of diethyl phthalate (DEP). TiO is a popular photosensitizer with potential in waste water treatment and application in advanced oxidation processes. The degradation process of DEP can be described with a first-order kinetics in the applied concentration ranges.

Transcriptomic response of Pseudomonas nicosulfuronedens LAM1902 to the sulfonylurea herbicide nicosulfuron.

The overuse of the herbicide nicosulfuron has become a global environmental concern. As a potential bioremediation technology, the microbial degradation of nicosulfuron shows much promise; however, the mechanism by which microorganisms respond to nicosulfuron exposure requires further study. An isolated soil-borne bacteria Pseudomonas nicosulfuronedens LAM1902 displaying nicosulfuron, chlorimuron-ethyl, and cinosulfuron degradabilities in the presence of glucose, was used to determine the transcriptional responses to nicosulfuron exposure.