93 results match your criteria: "Center for Physical Sciences and Technology FTMC[Affiliation]"

In this research, the wetting property control of a stainless-steel surface, structured using parallel processing via an array of 64-femtosecond laser beams, is presented. The scanning of an 8 × 8-beam array over the sample was used to uniformly cover the large areas with LIPSS. The static water contact angle and the LIPSS period dependence on processing parameters were investigated.

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The hands of nuclear medicine (NM) personnel involved in radiopharmaceutical preparation and administration can receive significant radiation doses. The dose distribution across the hand is nonuniform and the Hp(0.07) doses obtained by an individual passive ring dosimeter do not always present a real situation.

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National diagnostic reference levels (DRLs) are essential tools for optimizing protocols and protecting patients from an unjustified radiation exposure. The aim of this study was to conduct a nationwide survey of adult patient doses received from nuclear medicine (NM) procedures and to update national DRL (NDRL) values for most common procedures. Data on the radioactivity administered to standard adult patients were collected from all Lithuanian hospitals using NM applications in practice, between 2017 and 2022.

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The activity of prescribed radiopharmaceuticals, which are administered for diagnostic and therapeutic purposes, strongly depends on the accuracy of the measuring equipment used in nuclear medicine. This study presents the current status of uncertainty measurements of activity meters used in Lithuanian hospitals. During 2016-2021, the Ionizing Radiation Metrology Laboratory of the Center for Physical Sciences and Technology, which is the National Metrology Institute, performed a comparison of activity meters in the nuclear medicine departments of Lithuanian hospitals.

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The synthesis of magnetic particles triggers the interest of many scientists due to their relevant properties and wide range of applications in the catalysis, nanomedicine, biosensing and magnetic separation fields. A fast synthesis of iron oxide magnetic particles using an eco-friendly and facile microwave-assisted solvothermal method is presented in this study. Submicron FeO spheres were prepared using FeCl as an iron source, ethylene glycol as a solvent and reductor and sodium acetate as a precipitating and nucleating agent.

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One of the methods to improve the performance of a heterogeneous electrocatalyst is the dispersion of a catalytic material on a suitable substrate. In this study, femtosecond laser ablation was used to prepare very rough but also ordered copper surfaces consisting of vertical, parallel ridges. Then, a molybdenum sulfide coating was electrochemically deposited onto these surfaces.

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Development of molecularly imprinted polymer based phase boundaries for sensors design (review).

Adv Colloid Interface Sci

July 2022

Department of Physical Chemistry, Faculty of Chemistry and Geosciences, Institute of Chemistry, Vilnius University, Naugarduko 24, LT-03225 Vilnius, Lithuania. Electronic address:

Achievements in polymer chemistry enables to design artificial phase boundaries modified by imprints of selected molecules and some larger structures. These structures seem very useful for the design of new materials suitable for affinity chromatography and sensors. In this review, we are overviewing the synthesis of molecularly imprinted polymers (MIPs) and the applicability of these MIPs in the design of affinity sensors.

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For many years electroretinography (ERG) has been used for obtaining information about the retinal physiological function. More recently, a new technique called optoretinography (ORG) has been developed. In one form of this technique, the physiological response of retinal photoreceptors to visible light, resulting in a nanometric photoreceptor optical path length change, is measured by phase-sensitive optical coherence tomography (OCT).

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Electrochemical molecularly imprinted polymer based sensors for pharmaceutical and biomedical applications (review).

J Pharm Biomed Anal

June 2022

Department of Physical Chemistry, Faculty of Chemistry and Geosciences, Institute of Chemistry, Vilnius University, Naugarduko 24, LT-03225 Vilnius, Lithuania. Electronic address:

Recent challenges in the pharmaceutical and biomedical fields require the development of new analytical methods. Therefore, the development of new sensors is a very important task. In this paper, we are outlining the development of molecularly imprinted polymer (MIP) based sensors, which belongs to important branch of affinity sensors.

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Vibrational spectroscopy provides the possibility for sensitive and precise detection of chemical changes in biomolecules due to development of cancers. In this work, label-free near-infrared surface enhanced Raman spectroscopy (SERS) was applied for the differentiation between cancerous and normal human bladder tissues via analysis of the extracellular fluid of the tissue. Specific cancer-related SERS marker bands were identified by using a 1064 nm excitation wavelength.

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A detailed study on Raman spectroelectrochemistry of poly(N-methylaniline) (PNMA) layer deposited at a gold electrode was performed. Raman spectra were excited by four different laser wavelengths: UV line at 325 nm, a blue line at 442 nm, a red line at 633 nm, and a NIR line at 785 nm in solutions of different pH ranging from 1 to 9, and at different electrode potentials ranging from -0.5 V to 0.

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Graphene research and technology development requires to reveal adsorption processes and understand how the defects change the physicochemical properties of the graphene-based systems. In this study, shell-isolated nanoparticle-enhanced Raman spectroscopy (SHINERS) and graphene-enhanced Raman spectroscopy (GERS) coupled with density functional theory (DFT) modeling were applied for probing the structure of riboflavin adsorbed on single-layer graphene substrate grown on copper. Intense and detailed vibrational signatures of the adsorbed riboflavin were revealed by SHINERS method.

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Electrochemically Deposited Molecularly Imprinted Polymer-Based Sensors.

Sensors (Basel)

February 2022

Department of Physical Chemistry, Faculty of Chemistry and Geosciences, Institute of Chemistry, Vilnius University, Naugarduko 24, LT-03225 Vilnius, Lithuania.

This review is dedicated to the development of molecularly imprinted polymers (MIPs) and the application of MIPs in sensor design. MIP-based biological recognition parts can replace receptors or antibodies, which are rather expensive. Conducting polymers show unique properties that are applicable in sensor design.

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A quaternary lattice matched InAlGaN barrier layer with am indium content of 16.5 ± 0.2% and thickness of 9 nm was developed for high electron mobility transistor structures using the metalorganic chemical-vapor deposition method.

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The structural state and crystal structure of LuScFeO (0 ≤ ≤ 1) compounds prepared by a chemical route based on a modified sol-gel method were investigated using X-ray diffraction, Raman spectroscopy, as well as scanning electron microscopy. It was observed that chemical doping with Sc ions led to a structural phase transition from the orthorhombic structure to the hexagonal structure via a wide two-phase concentration region of 0.1 < < 0.

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Towards electrochemical surface plasmon resonance sensor based on the molecularly imprinted polypyrrole for glyphosate sensing.

Talanta

May 2022

Department of Physical Chemistry, Institute of Chemistry, Faculty of Chemistry and Geosciences, Vilnius University, Naugarduko Str. 24, LT, 03225, Vilnius, Lithuania; Nanotechnology Laboratory, Department of Functional Materials and Electronics, Center for Physical Sciences and Technology (FTMC), Saulėtekio av. 3, LT, 10257, Vilnius, Lithuania. Electronic address:

In this research the molecular imprinting technology was applied for the formation of glyphosate-sensitive layer. The glyphosate imprinted conducting polymer polypyrrole (MIPpy) was deposited on a gold chip/electrode and used as an electrochemical surface plasmon resonance (ESPR) sensor. The results described in this study disclose some restrictions and challenges, which arise during the development of glyphosate ESPR sensor based on the molecularly imprinted polymer development stage.

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NAtrium SuperIonic CONductor (NASICON) structured phosphate framework compounds are attracting a great deal of interest as suitable electrode materials for "rocking chair" type batteries. Manganese-based electrode materials are among the most favored due to their superior stability, resource non-criticality, and high electrode potentials. Although a large share of research was devoted to Mn-based oxides for Li- and Na-ion batteries, the understanding of thermodynamics and phase formation in Mn-rich polyanions is still generally lacking.

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In this study, sodium borohydride oxidation has been investigated on the platinum nanoparticles modified copper/titanium catalysts (PtNPsCu/Ti), which were fabricated by employing the electroless copper plating and galvanic displacement technique. ICP-OES, XRD, FESEM, and EDX have been used to characterize PtNPsCu/Ti catalysts' composition, structure, and surface morphology. The oxidation of sodium borohydride was examined on the PtNPsCu/Ti catalysts using cyclic voltammetry and chrono-techniques.

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Surface-enhanced Raman spectroscopy (SERS) substrates fabricated using a repeated laser treatment of thin gold films are demonstrated. The presented SERS substrates consist of the gold nanoparticles, whose density and size depend on the used film thickness and number of treated films. The larger number of the treated gold film layers increases the amount of larger nanoparticles (size >20 nm).

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This study investigates potential influence of urban trees on black carbon (BC) removal by Norway spruce and silver birch along with the BC formation, mass concentration in air, and source apportionment. The main sources of BC in urban areas are transport, household and industry. BC concentrations monitored in urban background station in Vilnius (Lithuania) showed that biomass burning was a significant contributor to BC emissions even during warm period of the year.

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Combined Use of Modal Analysis and Machine Learning for Materials Classification.

Materials (Basel)

July 2021

Department of Material Engineering, Faculty of Textile Engineering, Technical University of Liberec, 461 17 Liberec, Czech Republic.

The present study deals with modal work that is a type of framework for structural dynamic testing of linear structures. Modal analysis is a powerful tool that works on the modal parameters to ensure the safety of materials and eliminate the failure possibilities. The concept of classification through this study is validated for isotropic and orthotropic materials, reaching up to a 100% accuracy when deploying the machine learning approach between the mode number and the associated frequency of the interrelated variables that were extracted from modal analysis performed by ANSYS.

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Poly(N-methylaniline) vs. polyaniline: An extended pH range of polaron stability as revealed by Raman spectroelectrochemistry.

Spectrochim Acta A Mol Biomol Spectrosc

December 2021

Department of Organic Chemistry, Center for Physical Sciences and Technology (FTMC), Sauletekio av. 3, LT-10257 Vilnius, Lithuania. Electronic address:

A comparative study of polyaniline (PANI) and poly(N-methylaniline) (PNMA) has been performed by means of Raman spectroelectrochemical technique at 633 nm and 785 nm laser line excitations. The excitation wavelengths used fall into a resonance with the blue colored semi- and full-oxidized forms of these conducting polymers. The dependence of Raman features on electrode potential and solution acidity was studied, and relative content of polaronic and bipolaronic states was evaluated.

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This paper discusses the influence of fiber reinforcement on the properties of geopolymer concrete composites, based on fly ash, ground granulated blast furnace slag and metakaolin. Traditional concrete composites are brittle in nature due to low tensile strength. The inclusion of fibrous material alters brittle behavior of concrete along with a significant improvement in mechanical properties i.

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Roadmap of Terahertz Imaging 2021.

Sensors (Basel)

June 2021

Physikalisches Institut, Goethe-Universität, Max-von-Laue Straße 1, D-60438 Frankfurt am Main, Germany.

In this roadmap article, we have focused on the most recent advances in terahertz (THz) imaging with particular attention paid to the optimization and miniaturization of the THz imaging systems. Such systems entail enhanced functionality, reduced power consumption, and increased convenience, thus being geared toward the implementation of THz imaging systems in real operational conditions. The article will touch upon the advanced solid-state-based THz imaging systems, including room temperature THz sensors and arrays, as well as their on-chip integration with diffractive THz optical components.

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An ability of lensless titanium-based antenna coupled microbolometers (Ti-μbolometers) operating at room temperature to monitor precisely radiation patterns in terahertz time-domain spectroscopy (THz-TDS) systems are demonstrated. To provide comprehensive picture, two different THz-TDS systems and Ti-μbolometers coupled with three different antennas-narrowband dipole antennas for 0.3 THz, 0.

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