Plasmon-Triggered Ultrafast Operation of Color Centers in Hexagonal Boron Nitride Layers.

High-quality emission centers in two-dimensional materials are promising components for future photonic and optoelectronic applications. Carbon-enriched hexagonal boron nitride (hBN:C) layers host atom-like color-center (CC) defects with strong and robust photoemission up to room temperature. Placing the hBN:C layers on top of Ag triangle nanoparticles (NPs) accelerates the decay of the CC defects down to 46 ps from their reference bulk value of 350 ps.

Interface engineering of charge-transfer excitons in 2D lateral heterostructures.

The existence of bound charge transfer (CT) excitons at the interface of monolayer lateral heterojunctions has been debated in literature, but contrary to the case of interlayer excitons in vertical heterostructure their observation still has to be confirmed. Here, we present a microscopic study investigating signatures of bound CT excitons in photoluminescence spectra at the interface of hBN-encapsulated lateral MoSe-WSe heterostructures. Based on a fully microscopic and material-specific theory, we reveal the many-particle processes behind the formation of CT excitons and how they can be tuned via interface- and dielectric engineering.

Tunable electron-flexural phonon interaction in graphene heterostructures.

Peculiar electron-phonon interaction characteristics underpin the ultrahigh mobility, electron hydrodynamics, superconductivity and superfluidity observed in graphene heterostructures. The Lorenz ratio between the electronic thermal conductivity and the product of the electrical conductivity and temperature provides insight into electron-phonon interactions that is inaccessible to past graphene measurements. Here we show an unusual Lorenz ratio peak in degenerate graphene near 60 kelvin and decreased peak magnitude with increased mobility.

Gate-Controlled Magnetotransport and Electrostatic Modulation of Magnetism in 2D Magnetic Semiconductor CrPS.

Using field-effect transistors (FETs) to explore atomically thin magnetic semiconductors with transport measurements is difficult, because the very narrow bands of most 2D magnetic semiconductors cause carrier localization, preventing transistor operation. Here, it is shown that exfoliated layers of CrPS -a 2D layered antiferromagnetic semiconductor whose bandwidth approaches 1 eV-allow the realization of FETs that operate properly down to cryogenic temperature. Using these devices, conductance measurements as a function of temperature and magnetic field are performed to determine the full magnetic phase diagram, which includes a spin-flop and a spin-flip phase.

Identification of the monolayer thickness difference in a mechanically exfoliated thick flake of hexagonal boron nitride and graphite for van der Waals heterostructures.

Exfoliated flakes of layered materials, such as hexagonal boron nitride (hBN) and graphite with a thickness of several tens of nanometers, are used to construct van der Waals heterostructures. A flake with a desirable thickness, size, and shape is often selected from many exfoliated flakes placed randomly on a substrate using an optical microscope. This study examined the visualization of thick hBN and graphite flakes on SiO/Si substrates through calculations and experiments.

CNT-MXene ultralight membranes: fabrication, surface nano/microstructure, 2D-3D stacking architecture, ion-transport mechanism, and potential application as interlayers for Li-O batteries.

Multiwalled carbon nanotubes (MWCNTs) have shown effectiveness in improving the suitability of MXenes for energy-related applications. However, the ability of individually dispersed MWCNTs to control the structure of MXene-based macrostructures is unclear. Here, the correlation among composition, surface nano- and microstructure, MXenes' stacking order, structural swelling, and Li-ion transport mechanisms and properties in individually dispersed MWCNT-TiC films was investigated.

Observation of phonon Poiseuille flow in isotopically purified graphite ribbons.

In recent times, the unique collective transport physics of phonon hydrodynamics motivates theoreticians and experimentalists to explore it in micro- and nanoscale and at elevated temperatures. Graphitic materials have been predicted to facilitate hydrodynamic heat transport with their intrinsically strong normal scattering. However, owing to the experimental difficulties and vague theoretical understanding, the observation of phonon Poiseuille flow in graphitic systems remains challenging.

Extremely Tough, Stretchable Gel Electrolytes with Strong Interpolymer Hydrogen Bonding Prepared Using Concentrated Electrolytes to Stabilize Lithium-Metal Anodes.

Extremely tough and stretchable gel electrolytes, which can be prepared by leveraging the strong interpolymer hydrogen bonding in concentrated lithium (Li)-salt electrolytes, are reported. These electrolytes can be realized by optimizing the competitive hydrogen-bonding interactions between polymer chains, solvent molecules, Li cations, and counteranions. Free polar solvent molecules, which typically impede interpolymer hydrogen bonding, are scarce in concentrated electrolytes; this feature can be exploited to prepare hydrogen-bonded gel electrolytes with unprecedented toughness.

Layer-dependent correlated phases in WSe/MoS moiré superlattice.

Electron correlation plays an essential role in the macroscopic quantum phenomena in the moiré heterostructure, such as antiferromagnetism and correlated insulating phases. Unlike the phenomena where the interaction involves only electrons in one layer, the interaction of distinct phases in two or more layers represents a new horizon forward, such as the one in the Kondo lattice model. Here, using interlayer excitons as a probe, we show that the interlayer interactions in heterobilayers of tungsten diselenide and molybdenum disulfide (WSe/MoS) can be electrically switched on and off, resulting in a layer-dependent correlated phase diagram, including single-layer, layer-selective, excitonic-insulator and layer-hybridized regions.

Tunable spin and valley excitations of correlated insulators in Γ-valley moiré bands.

Moiré superlattices formed from transition metal dichalcogenides support a variety of quantum electronic phases that are highly tunable using applied electromagnetic fields. While the valley degree of freedom affects optoelectronic properties in the constituent transition metal dichalcogenides, it has yet to be fully explored in moiré systems. Here we establish twisted double-bilayer WSe as an experimental platform to study electronic correlations within Γ-valley moiré bands.

Chemomechanical modification of quantum emission in monolayer WSe.

Two-dimensional (2D) materials have attracted attention for quantum information science due to their ability to host single-photon emitters (SPEs). Although the properties of atomically thin materials are highly sensitive to surface modification, chemical functionalization remains unexplored in the design and control of 2D material SPEs. Here, we report a chemomechanical approach to modify SPEs in monolayer WSe through the synergistic combination of localized mechanical strain and noncovalent surface functionalization with aryl diazonium chemistry.

How Hydrogel Stiffness Affects Adipogenic Differentiation of Mesenchymal Stem Cells under Controlled Morphology.

Matrix stiffness has been disclosed as an essential regulator of cell fate. However, it is barely studied how the matrix stiffness affects stem cell functions when cell morphology changes. Thus, in this study, the effect of hydrogel stiffness on adipogenic differentiation of human bone-marrow-derived mesenchymal stem cells (hMSCs) with controlled morphology was investigated.

Unconventional correlated insulator in CrOCl-interfaced Bernal bilayer graphene.

The realization of graphene gapped states with large on/off ratios over wide doping ranges remains challenging. Here, we investigate heterostructures based on Bernal-stacked bilayer graphene (BLG) atop few-layered CrOCl, exhibiting an over-1-GΩ-resistance insulating state in a widely accessible gate voltage range. The insulating state could be switched into a metallic state with an on/off ratio up to 10 by applying an in-plane electric field, heating, or gating.

Identification of Exciton Complexes in Charge-Tunable Janus W Monolayers.

Janus transition-metal dichalcogenide monolayers are artificial materials, where one plane of chalcogen atoms is replaced by chalcogen atoms of a different type. Theory predicts an in-built out-of-plane electric field, giving rise to long-lived, dipolar excitons, while preserving direct-bandgap optical transitions in a uniform potential landscape. Previous Janus studies had broad photoluminescence (>18 meV) spectra obfuscating their specific excitonic origin.

A swallowable X-ray dosimeter for the real-time monitoring of radiotherapy.

Monitoring X-ray radiation in the gastrointestinal tract can enhance the precision of radiotherapy in patients with gastrointestinal cancer. Here we report the design and performance, in the gastrointestinal tract of rabbits, of a swallowable X-ray dosimeter for the simultaneous real-time monitoring of absolute absorbed radiation dose and of changes in pH and temperature. The dosimeter consists of a biocompatible optoelectronic capsule containing an optical fibre, lanthanide-doped persistent nanoscintillators, a pH-sensitive polyaniline film and a miniaturized system for the wireless readout of luminescence.

Experimental Formation and Mechanism Study for Super-High Dielectric Constant AlO/TiO Nanolaminates.

Super-high dielectric constant () AlO/TiO nanolaminates (ATO NLs) are deposited by an atomic layer deposition technique for application in next-generation electronics. Individual multilayers with uniform thicknesses are formed for the ATO NLs. With an increase in AlO content in each ATO sublayer, the shape of the Raman spectrum has a tendency to approach that of a single AlO layer.

Rydberg Excitons and Trions in Monolayer MoTe.

Monolayer transition metal dichalcogenide (TMDC) semiconductors exhibit strong excitonic optical resonances, which serve as a microscopic, noninvasive probe into their fundamental properties. Like the hydrogen atom, such excitons can exhibit an entire Rydberg series of resonances. Excitons have been extensively studied in most TMDCs (MoS, MoSe, WS, and WSe), but detailed exploration of excitonic phenomena has been lacking in the important TMDC material molybdenum ditelluride (MoTe).

Inflammation-targeting polyamine nanomedicines for the treatment of ulcerative colitis.

Inflammatory bowel disease (IBD) is a chronic inflammatory disorder characterized by immune system dysfunction. Despite the availability of various anti-inflammatory drugs, they exhibit low therapeutic efficacy with systemic side effects. In this study, we developed oral anti-inflammatory polyamine-based nanomedicines for the treatment of ulcerative colitis.

Domain-Dependent Surface Adhesion in Twisted Few-Layer Graphene: Platform for Moiré-Assisted Chemistry.

Twisted van der Waals multilayers are widely regarded as a rich platform to access novel electronic phases thanks to the multiple degrees of freedom available for controlling their electronic and chemical properties. Here, we propose that the stacking domains that form naturally due to the relative twist between successive layers act as an additional "knob" for controlling the behavior of these systems and report the emergence and engineering of stacking domain-dependent surface chemistry in twisted few-layer graphene. Using mid-infrared near-field optical microscopy and atomic force microscopy, we observe a selective adhesion of metallic nanoparticles and liquid water at the domains with rhombohedral stacking configurations of minimally twisted double bi- and trilayer graphene.

Mechanically reconfigurable van der Waals devices via low-friction gold sliding.

Interfaces of van der Waals (vdW) materials, such as graphite and hexagonal boron nitride (hBN), exhibit low-friction sliding due to their atomically flat surfaces and weak vdW bonding. We demonstrate that microfabricated gold also slides with low friction on hBN. This enables the arbitrary post-fabrication repositioning of device features both at ambient conditions and in situ to a measurement cryostat.

Plurality of excitons in Ruddlesden-Popper metal halides and the role of the B-site metal cation.

We investigate the effect of metal cation substition on the excitonic structure and dynamics in a prototypical Ruddlesden-Popper metal halide. Through an in-depth spectroscopic and theoretical analysis, we identify the presence of multiple resonances in the optical spectra of a phenethyl ammonium tin iodide, a tin-based RPMH. Based on calculations, we assign these resonances to distinct exciton series that originate from the splitting of the conduction band due to spin-orbit coupling.

Toughening Ceramics down to Cryogenic Temperatures by Reentrant Strain-Glass Transition.

Ceramics, often exhibiting important functional properties like piezoelectricity, superconductivity, and magnetism, are usually mechanically brittle at room temperature and even more brittle at low temperature due to their ionic or covalent bonding nature. The brittleness in their working temperature range (mostly from room down to cryogenic temperatures) has been a limiting factor for the usefulness of these ceramics. In this Letter, we report a surprising "low-temperature toughening" phenomenon in a La-doped CaTiO_{3} perovskite ceramic, where a 2.

Repetitive Direct Comparison Method for Odor Sensing.

Olfactory sensors are one of the most anticipated applications of gas sensors. To distinguish odors-complex mixtures of gas species, it is necessary to extract sensor responses originating from the target odors. However, the responses of gas sensors tend to be affected by interfering gases with much higher concentrations than target odor molecules.

Trehalose Biosynthesis Gene Protects against Stress in the Initial Infection Stage of -Bean Bug Symbiosis.

Trehalose, a nonreducing disaccharide, functions as a stress protectant in many organisms, including bacteria. In symbioses involving bacteria, the bacteria have to overcome various stressors to associate with their hosts; thus, trehalose biosynthesis may be important for symbiotic bacteria. Here, we investigated the role of trehalose biosynthesis in the -bean bug symbiosis.

Quantifying the local mechanical properties of twisted double bilayer graphene.

Nanomechanical measurements of minimally twisted van der Waals materials remained elusive despite their fundamental importance for device realisation. Here, we use Ultrasonic Force Microscopy (UFM) to locally quantify the variation of out-of-plane Young's modulus in minimally twisted double bilayer graphene (TDBG). We reveal a softening of the Young's modulus by 7% and 17% along single and double domain walls, respectively.