47 results match your criteria: "CNRS - University of Rennes 1[Affiliation]"

Transition zones between natural and human-altered spaces are eroding in most terrestrial ecosystems. The persistence of animals in shared landscapes depends in part on their behavioral flexibility, which may involve being able to exploit human agricultural production. As a forest-dependent species, the Barbary macaque (Macaca sylvanus) is affected by the progressive conversion of forest-adjacent lands into crops.

View Article and Find Full Text PDF

Cells exist in an astonishing range of volumes across and within species. However, our understanding of cell size control remains limited, owing in large part to the challenges associated with accurate determination of cell volume. Much of our comprehension of size regulation derives from yeast models, but even for these morphologically stereotypical cells, assessment of cell volume has mostly relied on proxies and extrapolations from two-dimensional measurements.

View Article and Find Full Text PDF

Background: Numerous Ebola virus outbreaks have occurred in Equatorial Africa over the past decades. Besides human fatalities, gorillas and chimpanzees have also succumbed to the fatal virus. The 2004 outbreak at the Odzala-Kokoua National Park (Republic of Congo) alone caused a severe decline in the resident western lowland gorilla (Gorilla gorilla gorilla) population, with a 95% mortality rate.

View Article and Find Full Text PDF

We have studied the ionic conductivity and the dipolar reorientational dynamics of aqueous solutions of a prototypical deep eutectic solvent (DES), ethaline, by dielectric spectroscopy in a broad range of frequencies (MHz-Hz) and for temperatures ranging from 128 to 283 K. The fraction of water in the DES was varied systematically to cover different regimes, starting from the pure DES and its water-in-DES mixtures to the diluted electrolyte solutions. Depending on these parameters, different physical states were examined, including low viscosity liquid, supercooled viscous liquid, amorphous solid, and freeze-concentrated solution.

View Article and Find Full Text PDF

We have investigated the dynamics of liquid water confined in mesostructured porous silica (MCM-41) and periodic mesoporous organosilicas (PMOs) by incoherent quasielastic neutron scattering experiments. The effect of tuning the water/surface interaction from hydrophilic to more hydrophobic on the water mobility, while keeping the pore size in the range 3.5 nm-4.

View Article and Find Full Text PDF

We have performed small-angle neutron scattering in a momentum transfer range (0.05 < < 0.5 Å) to study long-range order and concentration fluctuations in deep eutectic solvents (DESs) and their aqueous solutions.

View Article and Find Full Text PDF

Deciphering the genomic regulatory code of enhancers is a key challenge in biology because this code underlies cellular identity. A better understanding of how enhancers work will improve the interpretation of noncoding genome variation and empower the generation of cell type-specific drivers for gene therapy. Here, we explore the combination of deep learning and cross-species chromatin accessibility profiling to build explainable enhancer models.

View Article and Find Full Text PDF

Extension and Limits of Cryoscopy for Nanoconfined Solutions.

J Phys Chem Lett

July 2020

Institute of Physics of Rennes, CNRS-University of Rennes 1, UMR 6251, F-35042 Rennes, France.

This work investigates the phase behavior of aqueous solutions of glycerol confined in MCM-41 and SBA-15 nanoporous matrixes by calorimetry. Limitations due to overfilling and eutectic freezing are prevented by the absence of an external liquid reservoir and by the glass-forming property of glycerol. Consequently, the stability of nanoconfined ice in equilibrium with aqueous solutions is studied over a wide range of compositions.

View Article and Find Full Text PDF

The outcome of species range expansion depends on the interplay of demographic, environmental and genetic factors. Self-fertilizing species usually show a higher invasive ability than outcrossers but selfing and bottlenecks during colonization also lead to an increased genetic load. The relationship between genomic and phenotypic characteristics of expanding populations has, hitherto, rarely been tested experimentally.

View Article and Find Full Text PDF

Binary liquid mixtures can exhibit nanosegregation, albeit being fully miscible and homogeneous at the macroscopic scale. This tendency can be amplified by geometrical nanoconfinement, leading to remarkable properties. This work investigates the molecular dynamics of -butanol (TBA)-toluene (TOL) mixtures confined in silica nanochannels by quasielastic neutron scattering and molecular dynamics simulation.

View Article and Find Full Text PDF

In humans, histiocytic sarcoma (HS) is an aggressive cancer involving histiocytes. Its rarity and heterogeneity explain that treatment remains a challenge. Sharing high clinical and histopathological similarities with human HS, the canine HS is conversely frequent in specific breeds and thus constitutes a unique spontaneous model for human HS to decipher the genetic bases and to explore therapeutic options.

View Article and Find Full Text PDF

Canine oral melanoma is the first malignancy of the oral cavity in dogs and is characterized by a local invasiveness and a high metastatic propensity. A better knowledge of genetic alterations is expected to improve management of this tumour. Copy number alterations are known characteristics of mucosal melanomas both in dogs and humans.

View Article and Find Full Text PDF

Social dispersal is an important feature of population dynamics. When female mammals occur in polygynous groups, their dispersal decisions are conditioned by various female-, male-, and group-related factors. Among them, the influence of disease often remains difficult to assess.

View Article and Find Full Text PDF

Background: Metastatic melanoma is one of the most aggressive forms of cancer in humans. Among its types, mucosal melanomas represent one of the most highly metastatic and aggressive forms, with a very poor prognosis. Because they are rare in Caucasian individuals, unlike cutaneous melanomas, there has been fewer epidemiological, clinical and genetic evaluation of mucosal melanomas.

View Article and Find Full Text PDF

New chemistry of transition metal oxyhydrides.

Sci Technol Adv Mater

November 2017

Department of Energy & Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Kyoto, Japan.

In this review we describe recent advances in transition metal oxyhydride chemistry obtained by topochemical routes, such as low temperature reduction with metal hydrides, or high-pressure solid-state reactions. Besides the crystal chemistry, magnetic and transport properties of the bulk powder and epitaxial thin film samples, the remarkable lability of the hydride anion is particularly highlighted as a new strategy to discover unprecedented mixed anion materials.

View Article and Find Full Text PDF

We report the photoluminescence (PL) and cathodoluminescence (CL) properties of face-capped [MoXL] (X = Cl, Br, I; L = organic or inorganic ligands) cluster units. We show that the emission of Mo metal atom clusters depends not only on the nature of X and L ligands bound to the cluster and counter-cations, but also on the excitation source. Seven members of the AMoXL series (A = Cs, (n-CH)N, NH) were selected to evaluate the influence of counter-cations and ligands on de-excitation mechanisms responsible for multicomponent emission of cluster units.

View Article and Find Full Text PDF

Objectives: Demographic crashes due to emerging diseases can contribute to population fragmentation and increase extinction risk of small populations. Ebola outbreaks in 2002-2004 are suspected to have caused a decline of more than 80% in some Western lowland gorilla (Gorilla gorilla gorilla) populations. We investigated whether demographic indicators of this event allowed for the detection of spatial fragmentation in gorilla populations.

View Article and Find Full Text PDF

The confinement of liquid mixtures in porous channels provides new insight into fluid ordering at the nanoscale. In this study, we address a phenomenon of microphase separation, which appears as a novel fascinating confinement effect for fully miscible binary liquids. We investigate the structure of tert-butanol-toluene mixtures confined in the straight and mono-dispersed cylindrical nanochannels of SBA-15 mesoporous silicates (D = 8.

View Article and Find Full Text PDF

Visible tunable lighting system based on polymer composites embedding ZnO and metallic clusters: from colloids to thin films.

Sci Technol Adv Mater

August 2016

Laboratory for Innovative Key Materials and Structures (LINK), UMI 3629 CNRS-Saint Gobain-NIMS, National Institute for Materials Science (NIMS), Tsukuba, Japan; Optical and Electronic Materials Unit, NIMS, Tsukuba, Japan; NIMS-Saint-Gobain Center of Excellence for Advanced Materials, NIMS, Tsukuba, Japan.

The development of phosphor devices free of heavy metal or rare earth elements is an important issue for environmental reasons and energy efficiency. Different mixtures of ZnO nanocrystals with CsMoI(OOCF) cluster compound (CMIF) dispersed into polyvinylpyrrolidone matrix have been prepared by very simple and low cost solution chemistry. The resulting solutions have been used to fabricate highly transparent and luminescent films by dip coating free of heavy metal or rare earth elements.

View Article and Find Full Text PDF

Predicting the effect of a changing environment, e.g., caused by climate change, on realized niche dynamics, and consequently, biodiversity is a challenging scientific question that needs to be addressed.

View Article and Find Full Text PDF

Dispersal movements, i.e. movements leading to gene flow, are key behaviours with important, but only partially understood, consequences for the dynamics and evolution of populations.

View Article and Find Full Text PDF

Crystal structure of 4,6-di-chloro-5-methyl-pyrimidine.

Acta Crystallogr E Crystallogr Commun

December 2015

UMR 6226 CNRS University of Rennes 1 'Chemical Sciences Rennes', 'Team Systems and Synthetic Condensed Electroactive', 263 Avenue du General Leclerc, F-35042 Rennes, France.

Article Synopsis
  • The compound C5H4Cl2N2 has a nearly flat structure, with non-hydrogen atoms deviating only slightly from a mean plane.
  • The maximum deviation from this plane is found in a nitrogen atom, measuring just 0.016 Å.
  • In the crystal structure, molecules are connected through C-H⋯N hydrogen bonds, creating inversion dimers that form a specific ring pattern (R (2) 2(6)).
View Article and Find Full Text PDF

Plant-plant interactions as a mechanism structuring plant diversity in a Mediterranean semi-arid ecosystem.

Ecol Evol

November 2015

Instituto Pirenaico de Ecología (CSIC) Av. Montañana 1005 P.O. Box 13.034 50080 Zaragoza Spain.

Plant-plant interactions are among the fundamental processes that shape structure and functioning of arid and semi-arid plant communities. Despite the large amount of studies that have assessed the relationship between plant-plant interactions (i.e.

View Article and Find Full Text PDF

Phenotypic plasticity may be advantageous for plants to be able to rapidly cope with new and changing environments associated with climate change or during biological invasions. This is especially true for perennial plants, as they may need a longer period to respond genetically to selective pressures than annuals, and also because they are more likely to experience environmental changes during their lifespan. However, few studies have explored the plasticity of the reproductive life history traits of woody perennial species.

View Article and Find Full Text PDF

Novel Ge-Ga-Te-CsBr glass system with ultrahigh resolvability of halide.

Spectrochim Acta A Mol Biomol Spectrosc

November 2015

Laboratory of Glasses and Ceramics, UMR 6226 CNRS-University of Rennes 1, Rennes Cedex 135042, France.

CO2 molecule, one of the main molecules to create new life, should be probed accurately to detect the existence of life in exoplanets. The primary signature of CO2 molecule is approximately 15 μm, and traditional S- and Se-based glass fibers are unsuitable. Thus, Te-based glass is the only ideal candidate glass for far-infrared detection.

View Article and Find Full Text PDF