1,718 results match your criteria: "Bu Ali-Sina University[Affiliation]"

Determining 2,4,6-trinitrotoluene (TNT) in aqueous solution is of great importance for public security, environment, and public health protection. The covalent organic framework (COF) based fluoresce probes are still of interest in developing the sensor-based detection systems for TNT. So, a novel fluorescence solid-state probe based on a melamine-based COF (SNW1)for TNT detection was established for the first time.

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In our study, we aimed to use olive pomace, food industry waste, as biomass to produce biochar nanoparticles. The surface of the biochar was functionalized with the l-histidine ligand, and then cupric acetate was added to prepare Cu-l-histidine@biochar as a final catalyst for the chemo- and homoselective synthesis of amide and aniline derivatives. To characterize the novel catalyst, we employed various techniques.

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Highly efficient synthesis of pyrimidine-5-carbonitrile derivatives over a robust biowaste bone char-Bronsted solid acid catalyst.

Sci Rep

December 2024

Department of Organic Chemistry, Faculty of Chemistry and Petroleum Sciences, Bu-Ali Sina University, Hamedan, 6517838683, Iran.

In this study, the conversion of bones (waste of food industry) into bone char is described. The presence of calcium phosphate and graphitic carbon gives bone char unique properties, with different possible uses. The catalytic behavior of bone char modified with chlorosulfonic acid is tested as reusable and eco-friendly solid acid biocatalyst in synthesis of pyrimidine-5-carbonitrile derivatives.

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Since males and females have different number of X chromosome, different mechanisms have evolved to equalize dosage of gene products from the X chromosome between XX females and XY males. The aim of this study was to study X chromosome dosage compensation for growth rate (GR), Kleiber ratio (KR), efficiency of growth (EF) and relative growth rate (RGR) in Zandi sheep. A two steps procedure was adopted to analysis data.

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Background: Myeloid Derived Suppressor Cells (MDSCs) are capable of inhibiting both innate and adaptive immune responses and accumulate in the microenvironment of breast tumors. Hence, MDSC depletion by chemotherapeutic agents can improve clinical efficacy of cancer immunotherapy. The effects of 5-FU and doxorubicin agents on MDSC reduction in 4T1 breast cancer murine model were evaluated.

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Background And Aim: Research has documented chronic non-specific low back pain (CNSLBP) as one of the primary causes of absenteeism at work, often accompanied by the use of health insurance and healthcare services. Considering little research on the consequences of open/closed kinetic chain (O/CKC) exercises in water on CNSLBP improvement, the present study is to investigate the effects of such interventions on the electrical activity of selected lumbar muscles, pain, lumbopelvic control (LPC), ground reaction force (GRF), and psychological factors in men with CNSLBP.

Materials And Methods: This is a randomized controlled trial that involves individuals with CNSLBP between the ages of 40 and 60 years.

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Objective: This study aimed to evaluate the effect of Cognitive functional therapy (CFT) on plantar pressure distribution symmetry in chronic non-specific low back pain (CNSLBP) patients.

Method: forty females with NSCLBP (age range 30-50 years) were recruited for clinical trials. They were randomly divided into experimental and control groups (Each group had 20 patients).

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Article Synopsis
  • This study investigates how neurofeedback training (NFBT) can help improve psychological factors and plantar pressure distribution in patients with patellofemoral pain (PFP).
  • Thirty males with PFP participated; one group received NFBT for 12 weeks, while the control group did not, focusing on pain, catastrophizing, and kinesiophobia as primary outcomes.
  • The results showed significant reductions in pain and psychological issues, but only minor changes in plantar pressure distribution, suggesting that combining NFBT with physical therapy could enhance treatment effectiveness.
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Background: Hypertrophic scar (HS) is a cutaneous condition results from abnormal wound healing following deep tissue injury. To date, there is no optimal treatment for this skin disorder. Catechins possess anti-inflammatory, antioxidant and anti-fibrotic properties.

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Background: In camels, thelaziosis is mainly caused by Thelazia leesei Railliet & Henry, 1910, a little-known eyeworm species. Given the paucity of scientific data, this study aimed to provide new insights into the morphology, molecular characterization, and phylogenetic relationship of T. leesei and its occurrence in camels from Iran, where animals suffer from the high burden of eyeworms.

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Highly promoted CO separation of poly(ether-block-amide) based mixed matrix membranes using MOFs@aminoclay architectures as fillers.

Sci Rep

November 2024

Department of Applied Chemistry, Faculty of Chemistry and Petroleum Sciences, Bu-Ali Sina University, Hamedan, 6517838695, Iran.

Article Synopsis
  • This research focuses on creating new composite materials using aminoclays (MgAC and ZrAC) and Metal-Organic Frameworks (MOFs) integrated into a PEBAX matrix for improving gas separation effectiveness, particularly for carbon monoxide (CO).* -
  • The creation of specific composites like UiO-66-(COOH)@CuBDC@MgAC shows enhanced CO permeability due to the unique interactions between amine groups, unoccupied copper ions, and free carboxylic acid within the materials, as well as the nanosheet structure of CuBDC which enhances the interphase regions.* -
  • Experimental results indicate that composites such as PEBAX/Zr@Zr@Cu@Mg-4 achieve
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The novel Zn-Cu-Al layered double hydroxide (LDH) encapsulated within a chitosan/glutaraldehyde matrix, designated as LDH@Cs/G@Pd, was synthesized through simplified methodologies for the preparation of aromatic aldehyde derivatives. Formic acid served as the carbon monoxide source and hydrogen donor, while chitosan/glutaraldehyde acted as the linking agent between the substrate and palladium nanoparticles, with Echinophora platyloba extract functioning as the reducing agent for palladium. The characterization of LDH@Cs/G@Pd was conducted using a variety of analytical techniques, including Fourier-transform infrared spectroscopy (FT-IR), energy-dispersive X-ray spectroscopy (EDS), field-emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA), X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) surface area analysis, and inductively coupled plasma optical emission spectroscopy (ICP-OES).

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The process of sprouting makes legumes better by changing their nutrition, chemicals, and taste. Ground sprouted chickpeas are commonly used as the main ingredient in falafel. The aim of this research was to study the impact of drying techniques that include hot-air, infrared, and microwave on the moisture, ash, total phenolics, antioxidant capacity, color, and rehydration ratio of dried ground sprouted chickpeas.

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Objective: Walking is one of the most complex human movements that can be affected by various sources of attention. Dual tasks reduce attention, increase information processing, and may alter control mechanisms such as synergy. However, the effect of dual tasks on muscle synergy remains unknown.

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Article Synopsis
  • The study investigates antibiotic-resistant bacteria, specifically Enterococcus faecium (gram-positive) and Salmonella Typhimurium (gram-negative), focusing on how they adapt through changes in gene molecular activities and cellular structures.
  • Using Cytoscape software, the researchers analyzed gene networks to identify key hub genes and genetic pathways associated with the bacteria's survival against the antibiotic ciprofloxacin.
  • Findings highlight significant differences in the bacteria's mechanisms, such as E. faecium's emphasis on lipid biosynthesis and S. Typhimurium's focus on signal transduction and regulation, while also revealing some common pathways related to essential cellular functions.
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Background: Biofilms are bacterial communities that can protect them against external factors, including antibiotics. In this study, silver nanoparticles (AgNPs) were formed by modifying AgNPs with C-phycocyanin (Ag-Pc) to inhibit the growth of carbapenem-resistant (CR ) and methicillin-resistant (MRSA) and destroy biofilm of these bacteria.

Methods: The AgNPs were prepared with the green synthesis method, and Pc was used to stabilize the AgNPs.

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Background: Brucellosis is a major worldwide zoonotic disease that is caused by Brucella spp. and threatens the health of communities. Novel methods for rapid detection of Brucella bacteria are beneficial and necessary in preventing infection and subsequent economic losses.

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Metal-based catalysts play an essential role in organic chemistry and the chemical industry. This research designed and successfully synthesized a pillar-layered metal-organic framework (MOF) with the urea linkers, namely Basu-HDI, as a novel and efficient heterogeneous catalyst. Various techniques such as FT-IR, EDX, elemental mapping, SEM, XRD, BET, and TGA/DTA studied its structure and morphology.

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Background: Aged heart is defined via structural and mitochondrial dysfunction of the heart. However, there is still no potent compound to improve cardiac function abnormalities in aged individuals. Olive oil (OLO), as an oil with monounsaturated fatty acids, has diverse protective effects on the cardiovascular system, including anti-inflammatory, anti-diabetic, and mitigating effects on blood pressure.

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Article Synopsis
  • * The nanocomposite exhibited electrocatalytic capabilities that allowed for the sensitive and selective detection of AGM using square wave anodic stripping voltammetry, with optimal conditions established through experimental design.
  • * The detection method demonstrated impressive sensitivity, with a limit of detection of 0.002 μmol/L, and was effective in analyzing AGM in biological samples such as urine, serum, and saliva.
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Cold expansion is a mechanical method for creating residual stresses. This method is a proven technique to increase the fatigue life, and checking the residual stress on it, is of particular importance. A cold expansion process is widely used to generate beneficial residual stresses into an annular region around the hole.

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A visible light-responsive magnetically separable photocatalyst Pd-g-CN-Vanillin@γ-FeO-TiO is fabricated using vanillin as a natural junction under ultrasonic agitation. Structural, morphological, optical, thermal, and magnetic assessments of the as-prepared catalyst are carried out. The photocatalyst successfully drives the simultaneous benzimidazole formation, and olefin hydrogenation with high atom economy under blue LED light and mild conditions.

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Endophytes are symbionts that live in healthy plants and potentially improve the health of plant holobionts. Here, we investigated the bacterial endophyte community of Citrus reticulata grown in the northern Persian Gulf. Bacteria were isolated seasonally from healthy trees (root, stem, bark, trunk, leaf, and crown tissues) in four regions of Hormozgan province (i.

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The design of electrochemical sensors is crucial considering important factors such as efficiency, low cost, biocompatibility, and availability. Manganese oxides are readily available, low-cost, and biocompatible materials, but their low conductivity limits their efficiency as sensors. Today, morphology engineering of manganese oxide has been one of the most common research topics, because manganese oxides' electrochemical properties are highly dependent on their morphologies.

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Article Synopsis
  • A Ce-Mn binuclear LDH was synthesized at varying Ce to Mn molar ratios and modified with CPTMS and NAP, with numerous characterization techniques confirming that a 1:4 ratio was optimal.
  • This optimal catalyst was then utilized for a green synthesis process, producing spiro[acridine-indole]triones through a three-component reaction involving isatin, aniline, and 1,3-diketone under mild conditions.
  • The method offers benefits such as eliminating harmful solvents, easy catalyst separation, high yields, and consistent catalytic activity even after multiple uses.
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