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Rheological and thermal degradation properties of hyperbranched polyisoprene prepared by anionic polymerization.
R Soc Open Sci
November 2019
Section of Polymer Engineering Technology, Universiti Kuala Lumpur, Branch Campus Malaysian Institute of Chemical and Bioengineering Technology (UniKL MICET), Lot 1988, Taboh Naning, 78000 Alor Gajah, Malacca, Malaysia.
Hyperbranched polyisoprene was prepared by anionic copolymerization under high vacuum condition. Size exclusion chromatography was used to characterize the molecular weight and branching nature of these polymers. The characterization by differential scanning calorimetry and melt rheology indicated lower and complex viscosity in the branched polymers as compared with the linear polymer.
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