Preparation and characterization of highly crystalline hydroxyapatite (HAp) from the scales of an anadromous fish (): a comparative study with the freshwater fish scale () derived HAp.

Waste generation from fish processing sectors has become a significant environmental concern. This issue is exacerbated in countries with high aquaculture production and inefficient fish scale (FS) utilization. This study prepared and compared highly crystalline hydroxyapatite (HAp) from the FS of an anadromous fish, (I-HAp), and a freshwater fish, (R-HAp).

Combined experimental and first principles look into (Ce, Mo) doped BiVO.

Here we investigated the effects of Ce and Mo doping on hydrothermally synthesized bismuth vanadate BiVO nanoparticles (NPs). The existence of monoclinic scheelite and tetragonal zircon phases of NPs was validated from Rietveld refinement of the powdered X-ray diffraction, room temperature Raman, and Fourier-transform infrared spectroscopy. The co-doping of Bi and V sites with respective Ce and Mo dopants in a mixed tetragonal zircon and monoclinic scheelite phases of BiVO lattice was corroborated from high-resolution transmission electron microscopy and X-ray photoelectron spectroscopy.

The impact of feeding pattern on heavy metal accumulation and associated health risks in fishes from the Dhaleshwari River Bangladesh.

Heavy metals in aquatic ecosystems accumulate in fish tissues, posing significant ecological and health hazards due to their toxic effects on both the environment and human consumers. The purpose of the study was to assess the potential hazards associated with consuming carnivorous, omnivorous, and herbivorous fish species from the Dhaleshwari River in Bangladesh. The study focused on the seasonal variation and accumulation pattern of toxic heavy metals in these fish species.

Crystal structure modification of nano-hydroxyapatite using organic modifiers and hydrothermal technique.

Hydroxyapatite (HAp) synthesis was achieved through a hydrothermal method involving orthophosphoric acid and calcium hydroxide. Different organic modifiers such as urea, naphthalene, and palmitic acid were applied in the reaction system to modify the crystallite size along with the morphology of HAp. The synthesized HAp was validated X-ray diffraction (XRD) data, Fourier Transform Infrared (FTIR) spectra, Field Emission Scanning Electron Microscopy (FESEM) image, and optical bandgap energy (<6 eV) was determined through UV-vis spectrophotometry.

Fabrication and performance evaluation of polyethersulfone membranes with varying compositions of polyvinylpyrrolidone and polyethylene glycol for textile wastewater treatment using MBR.

Various industries polluting the water bodies by discharging untreated wastewater directly into the environment and conventional wastewater treatments are often insufficient for effectively treating the pollutants. However, membrane bioreactors (MBRs) offer a promising solution for wastewater treatment where membrane serving as the heart of the system. In this study, polyethersulfone (PES) was used as the membrane material and hydrophilicity of the membranes were tuned up by mixing with hydrophilic additives such as polyethylene glycol (PEG) and polyvinylpyrrolidone (PVP) and the membranes have shown promising results in treating wastewater, particularly in terms of chemical oxygen demand (COD), biochemical oxygen demand (BOD), and color removal.

First-Principles Calculations on Electronic, Optical, and Phonon Properties of γ-BiMoO.

The wide band gap γ-BiMoO (BMO) has tremendous potential in emergent solar harvesting applications. Here we present a combined experimental-first-principles density functional theory (DFT) approach to probe physical properties relevant to the light sensitivity of BMO like dynamic and structural stability, Raman and infrared absorption modes, value and nature of band gap (i.e.

Fatliquor for fungus resistant leather-a sustainable ecofriendly approach.

Surface-active softening agents, such as Fatliquors, have a significant impact on the leather industry as they enhance the physicochemical properties of leather. This study focuses on analyzing the synthesis, properties, characterization, and sulfonation of seed oil to determine its potential as a fatliquoring agent for leather. An investigation was conducted to verify the alteration of oil through the analysis of its properties before and after the sulfonation process.

Microbiological Analysis and Content of Heavy Metals in Different Candies, Chocolates, and Their Wrappers in Bangladesh.

Present study investigates 39 brands of candies, chocolate, and litchis, purchased from Dhaka City, Bangladesh, for their moisture content, sulphated ash value, heavy metal, and bacterial contamination. All the brands showed moisture content (0.64%-4.

Calcined chicken eggshell-derived biomimetic nano-hydroxyapatite as a local drug-delivery aid for doxycycline hyclate: characterization, bio-activity, cytotoxicity, antibacterial activity and release study.

The integration of bioactive substances with antibiotics has been extensively pursued for the treatment of osteomyelitis. These materials, also known as biomaterials, can serve both as bone replacements and targeted drug delivery systems for antibiotics. In this study, biomimetic nano-hydroxyapatite (nHAp) was synthesized the coprecipitation technique where waste chicken eggshell (WCE) was employed as the source of Ca.

A combined first principles and experimental approach to BiWO.

Here we synthesized BiWO (BWO) using both solid-state reaction (SBWO) and hydrothermal (HBWO-U and HBWO-S) methods. The orthorhombic 2 phase purity in all samples is confirmed from Rietveld refinement of X-ray diffraction data, Raman spectroscopy, and Fourier transform infrared spectroscopy. The HBWO-U and HBWO-S morphology revealed rectangular, spherical, and rod-like features with an average particle size of 55 nm in field emission scanning electron micrographs.

Waste newspaper driven activated carbon to remove polycyclic aromatic hydrocarbon from wastewater.

In this study, a carbon-based adsorbent was developed from waste newspaper through pyrolysis at 800 °C to evaluate the removal efficiency of polycyclic aromatic hydrocarbons (Benzo[ghi]perylene (BghiP) and Indeno [1,2,3-cd] pyrene (IP)) from wastewater. The surface area of the developed adsorbent was estimated at 509.247mg which allowed the adsorption of the PAHs from wastewater.

An DFT perspective on experimentally synthesized CuBiO.

Here we present a comprehensive density functional theory (DFT) based study of copper bismuth oxide CuBiO (CBO) in combination with experimental observations. The CBO samples were prepared following both solid-state reaction (SCBO) and hydrothermal (HCBO) methods. The 4/ phase purity of the as-synthesized samples was corroborated by Rietveld refinement of the powdered X-ray diffraction measurements along with Generalized Gradient Approximation of Perdew-Burke-Ernzerhof (GGA-PBE) and the Hubbard interaction corrected GGA-PBE+ relaxed crystallographic parameters.

Chemical profiles and pharmacological attributes of beehives using combined experimental and computer-aided studies.

The current study sought to determine the anxiolytic, antidepressant, and anti-inflammatory properties of distilled water-soluble extract of beehive (WSE-BH). Gas chromatography-mass spectrometry (GC-MS) studies were used to characterize the chemical compositions obtained from beehives extracted in water and methanol (also fractions). The GC-MS analysis identified 19 compounds in WSE-BH, including high total phenol and flavonoid contents, compared with the methanol extract (21 compounds), ethyl acetate fraction (9 compounds), and CCl fraction (27 compounds).

TOR1B: a predictor of bone metastasis in breast cancer patients.

Recent therapeutic advances in breast cancer (BC) have improved survival outcomes; however, the prognosis for patients with bone metastasis (BM) remains poor. Hence, novel clinical biomarkers are needed to accurately predict BC BM as well as to promote personalized medicine. Here, we discovered a novel biomarker, TOR1B, for BM in BC patients via analysis of BC gene expression data and clinical information downloaded from open public databases.

Phytochemical-Assisted Synthesis of FeO Nanoparticles and Evaluation of Their Catalytic Activity.

In this study, magnetite nanoparticles (FeO NPs) were synthesized using leaf extracts and characterized by visual observation, UV-Vis, FTIR, XRD, FESEM, and EDS. The UV-Vis spectrum showed continuous absorption at 300-500 nm, confirming the formation of FeO NPs. FTIR revealed that compounds containing the O-H group act as reducing agents during FeO NPs formation.

Covid-19 waste facemask conundrum: A facile way of utilization through fabricating composite material with unsaturated polyester resin and evaluation of its mechanical properties.

Since the outbreak of novel coronavirus (COVID-19), the use of personal protective equipment (PPE) has increased profusely. Among all the PPEs, face masks are the most picked ones by the mass people for protective purpose. This spawned extensive daily use of face masks and production of masks had to augment to keep up this booming demand.

Accumulation of Heavy Metals in Long-Evans Rat Through Feeding Fishes of Buriganga River and Their Histopathological Evaluation.

The study was conducted to evaluate the impacts of industrial discharges, including from tanneries, in terms of heavy metal loads in fin-fish of the Buriganga river, Dhaka, Bangladesh, and to find out the ultimate effects of feeding those heavy metal-contaminated fishes to Long-Evans rats to examine rats' heavy metal accumulation along with viable architectural alterations on various organs through histopathological screenings. Being the most edible by the populace, Labeo rohita was chosen for this purpose. Labeo rohita was collected from five different spots in the river close to the industrial outlets, covering three seasons: monsoon, winter, and summer throughout the year.

Phytochemical Analysis and Understanding the Antioxidant and Anticancer Properties of Methanol Extract from : In Vitro and In Vivo Studies.

() is considered an evidence-based medicinal plant for the treatment of cancer, the leading cause of death worldwide. In our study, the in vitro antioxidant and in vivo anticancer properties of an essential ethno-medicinal plant, , were examined using non-toxic doses and a phytochemical analysis was executed using gas-chromatography-mass-spectrometry. The in vitro antioxidant study of the methanolic extract (LGBME) revealed a concentration-dependent antioxidant property.

Polymerase chain reaction-based snake origin tracing in commercial venom crystals by targeting the mitochondrial D-loop.

Snake venom is a valuable raw material for numerous therapeutic formulations because of its life-saving pharmacological potential. However, due to their high price, fake "snake venoms" have captured a significant portion of the global market, and there is currently no reliable reported DNA-based method available for quickly distinguishing between fakes and originals. Therefore, in this study, a set of newly designed snake-specific universal primers targeting mitochondrial D-loop fragments were employed to detect snake origins in commercial venom crystals by only simplex polymerase chain reaction analysis.

Dietary carbohydrates: Pathogenesis and potential therapeutic targets to obesity-associated metabolic syndrome.

Metabolic syndrome (MetS) is a common feature in obesity, comprising a cluster of abnormalities including abdominal fat accumulation, hyperglycemia, hyperinsulinemia, dyslipidemia, and hypertension, leading to diabetes and cardiovascular diseases (CVD). Intake of carbohydrates (CHO), particularly a sugary diet that rapidly increases blood glucose, triglycerides, and blood pressure levels is the predominant determining factor of MetS. Complex CHO, on the other hand, are a stable source of energy taking a longer time to digest.

Phytochemical Profiling, Antioxidant Activity, and Analyses of and .

Our study aims to evaluate the chemical profiles and antioxidant activities of a methanolic extract of bark (MESV) and a methanolic extract of the whole plant (MEVP). The chemical profiling of MESV and MEVP was performed via gas chromatography-mass spectrometry (GC-MS), which identified 52 and 33 chemical compounds, respectively. The 2,2-diphenyl-1-picrylhydrazyl (DPPH) assay indicated that both MESV and MEVP displayed concentration-dependent scavenging activities, and half-maximal inhibitory concentration (IC) values for MEVP, MESV, and ascorbic acid were 305.

Recent Advances in Ovarian Cancer: Therapeutic Strategies, Potential Biomarkers, and Technological Improvements.

Aggressive and recurrent gynecological cancers are associated with worse prognosis and a lack of effective therapeutic response. Ovarian cancer (OC) patients are often diagnosed in advanced stages, when drug resistance, angiogenesis, relapse, and metastasis impact survival outcomes. Currently, surgical debulking, radiotherapy, and/or chemotherapy remain the mainstream treatment modalities; however, patients suffer unwanted side effects and drug resistance in the absence of targeted therapies.

Triglyceride Conversion of Waste Frying Oil up to 98.46% Using Low Concentration K/CaO Catalysts Derived from Eggshells.

In this study, biodiesel, also known as fatty acid methyl ester (FAME), was synthesized from multi-stage frying waste soybean oil using chicken eggshell-derived CaO and potassium-impregnated K-CaO heterogeneous catalysts. Potassium-impregnated catalysts (1.25% K-CaO, 2.