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Reverse atom transfer radical polymerization of dimethyl itaconate initiated by a new azo initiator: AIBME.

RSC Adv

April 2022

Beijing Advanced Innovation Center for Soft Matter Science and Engineering, State Key Laboratory of Organic-Inorganic Composites & Beijing Laboratory of Biomedical Materials, Beijing University of Chemical Technology Beijing 100029 P. R. China

Reverse atom transfer radical polymerization (RATRP) was used to synthesize poly(dimethyl itaconate) (PDMI) using an AIBME/CuBr/dNbpy system. The number average molecular weight ( ) of PDMI was as high as = 15 000 g mol, the monomer conversion rate reached up to 70%, and the dispersity remained low ( = 1.06-1.

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