Giant Piezoelectric Coefficient of Polyvinylidene Fluoride with Rationally Engineered Ultrafine Domains Achieved by Rapid Freezing Processing.

Domains play an essential role in determining the piezoelectric properties of polymers. The conventional method for achieving ultrafine piezoelectric domain structures for polymers is multiphase polymerization, which is not the primary choice for industrial-scale applications because of its complex synthesis and weak mechanical properties. In this study, it is demonstrated for the first time that a nanoscale domain design can be achieved in a commercially available polyvinylidene fluoride (PVDF) homopolymer through a simple fabrication method involving cyclic compression and rapid freezing.

Nonaqueous Contact-Electro-Chemistry via Triboelectric Charge.

Mechanochemistry revolutionizes traditional reactions through mechanical stimulation, but its reaction efficiency is limited. Recent advancements in utilizing triboelectric charge from liquid-solid contact electrification (CE) have demonstrated significant potential in improving the reaction efficiency. However, its efficacy remains constrained by interfacial electrical double-layer screening in aqueous solutions.

Biodegradable and Implantable Triboelectric Nanogenerator Improved by β-Lactoglobulin Fibrils-Assisted Flexible PVA Porous Film.

Triboelectric nanogenerators (TENGs) are highly promising as implantable, degradable energy sources and self-powered sensors. However, the degradable triboelectric materials are often limited in terms of contact electrification and mechanical properties. Here, a bio-macromolecule-assisted toughening strategy for PVA aerogel-based triboelectric materials is proposed.

Breaking Mass Transport Limit for Hydrogen Evolution-Inhibited and Dendrite-Free Aqueous Zn Batteries.

It is commonly accepted that batteries perform better at low current densities below the mass-transport limit, which restricts their current rate and capacity. Here, it is demonstrated that the performance of Zn metal electrodes can be dramatically enhanced at current densities and cut-off capacities exceeding the mass-transport limit by using pulsed-current protocols. These protocols achieve cumulative plating/stripping capacities of 11.

Sustainable Biopolymers in Eco-Friendly Triboelectric Energy Harvesting.

Biopolymer-based triboelectric nanogenerators (B-TENGs) represent an innovative fusion of eco-friendly, sustainable energy-harvesting technology with renewable and environmentally benign biopolymer material. This integration not only introduces novel pathways for advancing green energy solutions but also offers a critical approach to addressing contemporary environmental challenges and fostering sustainable progress. Over the past few years, B-TENGs have seen rapid and remarkable growth in the realm of biopolymers, device architecture, and their applications (e.

Self-powered visualized tactile-acoustic sensor for accurate artificial perception with high brightness and record-low detection limit.

The growth of the Internet of Things has focused attention on visualized sensors as a key technology. However, it remains challenging to achieve high sensing accuracy and self-power ability. Here, we propose a self-powered visualized tactile-acoustic sensor (SVTAS) based on an elaborated triboelectrification-induced electroluminescence (TIEL) unit.

MOF-Derived Nitrogen-Rich Hollow Nanocages as a Sulfur Carrier for High-Voltage Aluminum Sulfur Batteries.

Aluminum-sulfur batteries (ASBs) are emerging as promising energy storage systems due to their safety, low cost, and high theoretical capacity. However, it remains a challenge to overcome voltage hysteresis and short cycle life in the sulfur/AlS conversion reaction, which hinders the development of ASBs. Here, we studied a high-voltage ASB system based on sulfur oxidation in an AlCl/urea electrolyte.

Significantly Enhanced Output Performance of Triboelectric Nanogenerators via Charge Storage and Release Strategy.

As a novel energy harvesting technology, bettering the output performance of triboelectric nanogenerators (TENGs) is vital. Although quite a number methods to increase charge density have been proposed, challenges such as high impedance matching and low output current persist, severely limit the energy utilization efficiency of TENGs. Here, a new power management circuit (PMC) is proposed that through charge storage and release strategy.

Ultra-High Sensitivity Real-Time Monitoring of Landslide Surface Deformation via Triboelectric Nanogenerator.

Monitoring surface deformation is crucial for the early warning of landslides, facilitating timely preventive measures. Triboelectric nanogenerator (TENG) demonstrates great potential for self-powered distributed monitoring in remote and power-scarce landslide areas. However, landslides deform typically at a rate of a few millimeters per day (mm d), making it challenging for TENG to directly monitor the deformation process.

Cellulose-Templated Nanomaterials for Nanogenerators and Self-Powered Sensors.

Energy crisis inspires the development of renewable and clean energy sources, along with related applications such as nanogenerators and self-powered devices. Balancing high performance and environmental sustainability in advanced material innovation is a challenging task. Addressing the global challenges of sustainable development and carbon neutrality lead to increased interest in biopolymer research.

A Highly-Sensitive Omnidirectional Acoustic Sensor for Enhanced Human-Machine Interaction.

Acoustic sensor-based human-machine interaction (HMI) plays a crucial role in natural and efficient communication in intelligent robots. However, accurately identifying and tracking omnidirectional sound sources, especially in noisy environments still remains a notable challenge. Here, a self-powered triboelectric stereo acoustic sensor (SAS) with omnidirectional sound recognition and tracking capabilities by a 3D structure configuration is presented.

Enhancing CAR-T cell therapy against solid tumor by drug-free triboelectric immunotherapy.

Chimeric antigen receptor (CAR) T cell therapy is a highly effective immunotherapy for hematological tumors, but its efficacy against most solid tumors remains challenging. Herein, a novel synergistic combination therapy of drug-free triboelectric immunotherapy and CAR-T cell therapy against solid tumor was proposed. A triboelectric nanogenerator (TENG) that can generate pulsed direct-current by coupling triboelectrification effect and electrostatic breakdown effect was fabricated.

Extending Dynamic Blind Interaction: Microgap Discharge-Induced Flexible Virtual Electrotactile Braille.

Braille is an essential implement for the blind to communicate with outside, but traditional Braille is limited to a paper-based format that cannot directly provide real-time word information. In this work, a flexible virtual electrotactile Braille is proposed that can benefit the blind from blocked interaction. The Braille interface, S-shaped wires and a sphere electrode with a textile fingerstall integrated by silicone, offers flexibility and simultaneously generates the microgap through textile cracks, which achieves virtual electrotactile sensation by electrostatic discharge.

Regulating Contact-Electro-Catalysis Using Polymer/Metal Janus Composite Catalysts.

Interfacial contact electrification can catalyze redox reactions through a process called contact-electro-catalysis (CEC). The two main reaction paths for producing reactive oxygen species via CEC are the water oxidation reaction (WOR) and the oxygen reduction reaction (ORR). Herein, we designed a polymer/metal Janus composite catalyst that regulated the reaction rates of the WOR and ORR based on the catalyst composition.

A Study on the Mechanisms and Performance of a Polyvinyl Alcohol-Based Nanogenerator Based on the Triboelectric Effect.

Polyvinyl alcohol (PVA), a versatile polymer, is extensively used across many industries, such as chemicals, food, healthcare, textiles, and packaging. However, research on applying PVA to triboelectric nanogenerators (TENGs) remains limited. Consequently, we chose PVA as the primary material to explore its contact electrification mechanisms at the molecular level, alongside materials like Polyethylene (PE), Polyvinylidene fluoride (PVDF), and Polytetrafluoroethylene (PTFE).

Ultra-Durable Polysilicon Based Tribovoltaic Nanogenerators for Bearing In Situ Rotational Speed Sensing.

Tribovoltaic nanogenerator (TVNG) is an emerging energy device with the advantages of direct current and high power density. At present, many TVNGs are based on single-crystal materials, which are expensive and fragile during structural processing. Here, a polysilicon-based TVNG for bearing in situ rotational speed sensing is developed, which has the same level of performance and lower cost compared to monocrystalline silicon.

Considering the impact of the chirality of therapeutic nanoparticles on cancer therapy.

"Inadequate understanding of chirality has potentially disastrous consequences. "Genius on the left, madman on the right" is not an exaggerated verse in the field of chiral research, but a realistic warning…".