Unveiling the emerging concern of per- and polyfluoroalkyl substances (PFAS) and their potential impacts on estuarine ecosystems.

Per- and polyfluoroalkyl substances (PFAS) have become ubiquitous chemicals that pose potentially serious threats to both human health and the integrity of the ecosystem. This review compiles current knowledge on PFAS contamination in estuaries, focusing on sources, abundance, distribution, fate, and toxic mechanisms. It also addresses the health risks associated with these compounds and identifies research gaps, offering recommendations for future studies.

Spectral characterization, degradation behavior, quenching, and semi-quantification of fluoroquinolone antibiotics in the antibiotic-humic mixture using fluorescence spectroscopy.

Antibiotics, one of the significant emerging contaminants, are intensifying their continual spread out into the environment and affecting human health and the ecosystem in the developing country Bangladesh. This study characterizes widely used fluoroquinolone (FQ) antibiotics, formulates the method to spectrally distinguish them from ubiquitous, and important reactive, adsorbent, and altering catalytic macromolecule humic substances (HS), and further quantifies them using fluorescence spectroscopy. The presence of identical fluorophore at Excitation/Emission = 225-230/285-295 nm wavelength, possession of fluorescence spectra at short emission wavelength (<350 nm) during 275 nm excitation, different emission maxima, and various fluorescing components in antibiotics identified through three-dimensional excitation-emission matrix (EEM) and parallel factor analysis (PARAFAC) models distinguished them from the humic substance as well as from each other.