Phosphorylation/caproylation of cornstarch to improve its adhesion to PLA and cotton fibers.

To investigate the influence of phosphorylation/caproylation on the adhesion of cornstarch to polylactic acid (PLA) and cotton fibers for improving its applications, such as in PLA and cotton sizing, herein, a series of phosphorylated and caproylated cornstarch (PCS) samples with different total degrees of substitution (DS) were synthetized by the phosphorylation of acid-converted cornstarch (ACS) with sodium tripolyphosphate (STP) and subsequent caproylation with caproic anhydride (CA). The PCS granules were characterized by Fourier transform infrared spectroscopy and scanning electron microscopy. The adhesion was evaluated by determining the bonding forces of the impregnated PLA and cotton roving.