Role of extreme vertex design approach on the mechanical and morphological behaviour of residual soil composite.

This research work reports the usability of binary additive materials known as tile waste dust (TWD) and calcined kaolin (CK) in ameliorating the mechanical response of weak soil. The extreme vertex design (EVD) was adopted for the mixture experimental design and modelling of the mechanical properties of the soil-TWD-CK blend. In the course of this study, a total of fifteen (15) design mixture ingredients' ratios for water, TWD, CK and soil were formulated.

Quantum and experimental investigation of the application of Crassostrea gasar (mangrove oyster) shell-based CaO nanoparticles as adsorbent and photocatalyst for the removal of procaine penicillin from aqueous solution.

The present study was designed to synthesize and characterize calcium oxide nanoparticles (using mangrove oyster shell as a precursor) and apply the synthesized nanoparticles as a photocatalyst to degrade procaine penicillin in an aqueous solution. The photocatalyst exhibited an average band gap of 4.42 eV, showed a maximum wavelength of absorbance in the UV region (i.

Mathematical modeling and numerical simulation technique for selected heavy metal transport in MSW dumpsite.

The study focused on development of mathematical modeling and numerical simulation technique for selected heavy metal transport in Uyo municipal solid waste dumpsite in Akwa Ibom State to investigate the level in depth to which leachate from the dumpsite extends and the quantity of leachate at various depth of the dumpsite soil. Uyo waste dumpsite is operating open dumping system where provisions are not made for preservation and conservation of soil and water quality, hence, the need for this study. Three monitoring pits within Uyo waste dumpsite were constructed and infiltration runs were measured, and soil samples were collected beside infiltration points from nine designated depths ranging from 0 to 0.

Drying kinetics and thermo-economic analysis of drying hot water blanched ginger rhizomes in a hybrid composite solar dryer with heat exchanger.

This research aimed to examine the need of adding hot water blanching pre-treatment on the drying of ginger rhizomes using a hybrid solar-dryer with paraffin liquid as thermal storage infused into a copper tube to form a compact heat exchanger. Blanching duration quickened the drying rate of the ginger rhizomes and the average drying rate for blanching at 90 s, 60 s, 30 s and un-blanched ginger varied between 0.0147 kg/h to 0.

Exact solutions of [Formula: see text]-dependent Schrödinger equation with quantum pseudo-harmonic oscillator and its applications for the thermodynamic properties in normal and superstatistics.

The effects of the curvature parameters on the energy eigenvalues and thermodynamic properties of quantum pseudoharmonic oscillator are investigated within the framework of nonrelativistic quantum mechanics. By employing Nikiforov-Uvarov method, the energy spectra are obtained and used to study the ordinary statistics and q-deformed superstatistics as a function of temperature in the presence and absence of the curvature parameters. It is shown that the q-deformed supertatistics properties of the quantum pseudoharmonic oscillator reduce to the ordinary statistical properties in the absence of the deformation parameter.

Biodiesel synthesized from the blend of red and oil: An application of calcined base, optimization, kinetics, and thermodynamic parameters studies.

The study emphasized the use of the mixed oil (MO) extracted from and Red oilseeds for the synthesis of biodiesel using a derived bio-base catalyst from calcined shell powder. The MO properties were determined with a view to examine its quality for biodiesel production. The derived calcined catalyst was characterized using scanning electron microscopy (SEM), X-ray fluorescence (XRF), Fourier transforms infrared spectroscopy (FTIR), BET adsorption analysis, and Hammett indicator.

Application of machine and deep learning algorithms in optical microscopic detection of Plasmodium: A malaria diagnostic tool for the future.

Machine and deep learning techniques are prevalent in the medical discipline due to their high level of accuracy in disease diagnosis. One such disease is malaria caused by Plasmodium falciparum and transmitted by the female anopheles mosquito. According to the World Health Organisation (WHO), millions of people are infected annually, leading to inevitable deaths in the infected population.

Computational design and molecular modeling of the interaction of nicotinic acid hydrazide nickel-based complexes with HS gas.

The application of nickel complexes of nicotinic acid hydrazide ligand as a potential gas-sensor and adsorbent material for HS gas was examined using appropriate density functional theory (DFT) calculations with the ωB97XD/Gen/6-311++G(d,p)/LanL2DZ method. The FT-IR spectrum of the synthesized ligand exhibited a medium band at 3178 cm attributed to (NH) stretching vibrations and strong bands at 1657 and 1600 cm corresponding to the presence of (C[double bond, length as m-dash]O) and (C[double bond, length as m-dash]N) vibration modes. In the spectrum of the nickel(ii) complex, the (C[double bond, length as m-dash]O) and (C[double bond, length as m-dash]N) vibration bands experience negative shifts to 1605 cm and 1580 cm, respectively, compared to the ligand.

Sirtfoods: New Concept Foods, Functions, and Mechanisms.

Sirtfood is a new concept food that compounds diets that can target sirtuins (SIRTs). SIRTs are nicotinamide adenine dinucleotide (NAD)-dependent deacylases and ADP-ribosyltransferases (enzymes). SIRTs are mediators of calorie restriction (CR) and their activation can achieve some effects similar to CR.

Antibiotic resistance in the aquatic environment: Analytical techniques and interactive impact of emerging contaminants.

Antibiotic pollution is becoming an increasingly severe threat globally. Antibiotics have emerged as a new class of environmental pollutants due to their expanding usage and indiscriminate application in animal husbandry as growth boosters. Contamination of aquatic ecosystems by antibiotics can have a variety of negative impacts on the microbial flora of these water bodies, as well as lead to the development and spread of antibiotic-resistant genes.

Heteroatoms (Si, B, N, and P) doped 2D monolayer MoS for NH gas detection.

2D transition metal dichalcogenide MoS monolayer quantum dots (MoS-QD) and their doped boron (B@MoS-QD), nitrogen (N@MoS-QD), phosphorus (P@MoS-QD), and silicon (Si@MoS-QD) surfaces have been theoretically investigated using density functional theory (DFT) computation to understand their mechanistic sensing ability, such as conductivity, selectivity, and sensitivity toward NH gas. The results from electronic properties showed that P@MoS-QD had the lowest energy gap, which indicated an increase in electrical conductivity and better adsorption behavior. By carrying out comparative adsorption studies using m062-X, ωB97XD, B3LYP, and PBE0 methods at the 6-311G++(d,p) level of theory, the most negative values were observed from ωB97XD for the P@MoS-QD surface, signifying the preferred chemisorption surface for NH detection.

Integration of green economy concepts for sustainable biosurfactant production - A review.

The link between increasing global population, food demand, industrialization, and agricultural waste is strong. Decomposing by-products from food cycles can introduce harmful toxic heavy metals, active degrading microbes, and enzymes to the environment. Additionally, high greenhouse gas emissions from the decomposing wastes contribute to global change and a high carbon economy.

Dataset on FAEE synthesized from oil blends via a derived submerged fermented pod husk: Application of hybrid design optimizer.

A new base catalyst was derived from submerged fermented pod husk (TCPH) in this work, the developed catalyst was tested for the production of fatty acid ethyl ester (FAEE) using the blends of beef tallow (BTO) - waste use oil (WUO) in the ratios of 10:90 (BTO) 20:80 (BTO) 30:70 (BTO)….., 90:10 (BTO) respectively.

An overview of the interactions between food production and climate change.

This paper provides an overview of how food production influences climate change and also illustrates the impact of climate change on food production. To perform such an overview, the (inter)link between different parts of the food supply chain continuum (agriculture production, livestock farming, food processing, food transport and storing, retail food, and disposal of food waste) and climate change has been investigated through a bibliometric analysis. Besides UN Sustainable Development Goal (SDG) 13, associated with climate change, other SDGs that are associated with this overview are goals #1, #2, #3, #6, #7, #12, and #15.

A Brief Review on Fruit and Vegetable Extracts as Corrosion Inhibitors in Acidic Environments.

The corrosion of metals, i.e., the initiation and acceleration of the surface deterioration of metals through an electrochemical reaction with the surrounding intrusive environment, is a global concern because of the economic and environmental impacts.

Metaproteomics insights into fermented fish and vegetable products and associated microbes.

The interest in proteomic studies of fermented food is increasing; the role of proteins derived from fermentation extends beyond preservation, they also improve the organoleptic, anti-pathogenic, anti-cancer, anti-obesogenic properties, and other health conferring properties of fermented food. Traditional fermentation processes are still in use in certain cultures, but recently, the controlled process is gaining wider acceptance due to consistency and predictability. Scientists use modern biotechnological approaches to evaluate reactions and component yields from fermentation processes.

Inoculation of Azospirillum brasilense and exogenous application of trans-zeatin riboside alleviates arsenic induced physiological damages in wheat (Triticum aestivum).

Due to increased industrialization, arsenic (As) in the soil has become a serious issue for wheat production since past few decades. We investigated the role of Azospirillum brasilense and trans-zeatin riboside (tZR) in the mitigation of arsenic toxicity in wheat for 2 years (2018-2019 and 2019-2020) in pot experiments. Wheat plants grown in soil artificially spiked with arsenic (50, 70, and 100 μM) was left alone or amended with A.

Appraisal of protectivity and corrosivity of surficial hydrogeological units via geo-sounding measurements.

The surface resistivity method was used to appraise the protectivity of hydrogeological units and corrosivity of the top soil in Obot Akara County, southern Nigeria. A total of 28 vertical electrical sounding (VES) was undertaken in the area using the Schlumberger electrode configuration. The results of the VES data interpretation reveal 3 to 4 geoelectric layers in the study area.

Analyzing the Effects of Topological Defect (TD) on the Energy Spectra and Thermal Properties of LiH, TiC and I Diatomic Molecules.

In this study, the impacts of TD on the energy spectra and thermal properties of , and diatomic molecules is considered. The Schrodinger equation in cosmic string spacetime is solved with the generalized Morse potential using the well-known (NU) method. The energy spectra and eigenfunction are obtained respectively.

Synthesis of biodiesel from oil blends using calcined waste wood ash as a heterogeneous base catalyst.

Naturally, biodiesel synthesized from highly viscous and high-density vegetable oil is usually unsuitable as fuel in the internal combustion engine. However, mixing/blending of two or more oils as a feedstock for biodiesel production could produce a low viscous fuel suitable for the engine. This study produced a novel heterogeneous base catalyst from waste wood ash (WWA) and applied it to synthesis of biodiesel from and oilseed blend.

Integrating hydrogeological and second-order geo-electric indices in groundwater vulnerability mapping: A case study of alluvial environments.

AVI (Aquifer vulnerability index), GOD (groundwater occurrence, overlying lithology and depth to the aquifer), GLSI (geo-electric layer susceptibility indexing) and S (longitudinal unit conductance) models were used to assess economically exploitable groundwater resource in the coastal environment of Akwa Ibom State, southern Nigeria. The models were employed in order to delineate groundwater into its category of vulnerability to contamination sources using the first- and second-order geo-electric indices as well as hydrogeological inputs. Vertical electrical sounding technique employing Schlumberger electrode configuration was carried out in 16 locations, close to logged boreholes with known aquifer core samples.

Prioritization of zoonotic diseases of public health significance in Nigeria using the one-health approach.

Nigeria, with a population of over 190 million people, is rated among the 10 countries with the highest burden of infectious and zoonotic diseases globally. In Nigeria, there exist a sub-optimal surveillance system to monitor and track priority zoonoses. We therefore conducted a prioritization of zoonotic diseases for the first time in Nigeria to guide prevention and control efforts.

Plastic waste: Status, degradation and microbial management options for Africa.

This paper presents a review of synthetic polymer (notably plastic) wastes profiles in Africa, their current management status, and better options. Data revealed that of the approximated 86.14 million metric tonnes and 31.

Natural products based crown ethers: synthesis and their anticancer potential.

Natural products based novel crown ethers have been prepared by employing biologically active natural structures including tetrahydroisoquinoline, chrysin and biochanin-A as the side arms. The resulting crown scaffolds were evaluated for their anticancer potential against two cancer cell lines i.e.