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Simultaneous pure-rotational coherent anti-Stokes Raman spectroscopy (PRCARS) and vibrational O CARS spectroscopy (VCARS) were performed at elevated pressure and lowered temperature conditions in non-reacting compressible flow. We applied dual-pump CARS in a three-laser, three-color configuration to simultaneously acquire the PRCARS and VCARS spectra of O PRCARS spectra provide excellent sensitivity to temperature at relatively low temperatures. Pressure was extracted using the differential response of collisional effects in the PRCARS and the VCARS spectra.

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