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Regio-isomeric effects in tandem mass spectra of sulfonium cations generated from thiacyclane based sulfonium salts under soft ionization conditions.
Eur J Mass Spectrom (Chichester)
February 2018
3 D. I. Mendeleev University of Chemical Technology of Russia, Department of High Energy Chemistry and Radioecology, Moscow, Russian Federation.
The influence of regio-isomerism of even-electron sulfonium ions on tandem electrospray and matrix-assisted laser desorption/ionization mass spectra recorded by using collision-induced dissociation was investigated. The initial organic sulfides belonged to isomeric thiabicyclane series (substituted 7- and 8-thiabicyclo[4.3.
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