Dietary exposure of stormwater contaminants in biofilm to two freshwater macroinvertebrates.

Aquatic habitats in urban environments are exposed to complex contaminant mixtures that may harm aquatic biota. The impact of contaminant transfer from contaminated biofilm through aquatic food webs is still understudied, as is the current state of knowledge on dietary exposure of urban contaminants to biota residing in stormwater ponds. Our overall objective was to characterize urban pesticide accumulation in a common aquatic food source (biofilm) in stormwater ponds and to investigate the potential toxicity of that food source by testing the responses of two freshwater macroinvertebrates to experimental exposure.

Not just social networks: How people infer relations from mutual connections.

People can infer relationships from incomplete information about social networks. We examined whether these inferences depend on domain-specific knowledge about social relationships or instead depend on domain-general statistical reasoning. In five preregistered experiments, participants (total N = 1,424) saw two target entities and their connections to others in social, semisocial, and nonsocial networks.

Interplay between element-specific distortions and electrocatalytic oxygen evolution for cobalt-iron hydroxides.

A microscopic understanding of how Fe-doping of Co(OH) improves electrocatalytic oxygen evolution remains elusive. We study two Co Fe (OH) series that differ in fabrication protocol and find composition alone poorly correlates to catalyst performance. Structural descriptors extracted using X-ray diffraction, X-ray absorption spectroscopy, and Raman spectroscopy reveal element-specific distortions in Co Fe (OH).

Tuning the Oxygen Reduction Reactivity of Layered Perovskites Using the Jahn-Teller Effect.

Compositional tuning of layered perovskite oxides provides a means of systematically studying how local distortions affect fundamental aspects of electrochemical reaction pathways. Structural analysis of a family of samples LaSrNiCoO shows that Ni-rich compositions have an expanded crystalline axis, which is anisotropically compressed by systematic Co incorporation. Raman spectra reveal the strong growth of a symmetry forbidden mode, which suggests that Co acts through localized distortions.

Impact of freeze-thaw cycles on greenhouse gas emissions in marginally productive agricultural land under different perennial bioenergy crops.

Knowledge of freeze-thaw-induced carbon (C) and nitrogen (N) cycling and concomitant nitrous oxide (NO) and carbon dioxide (CO) emissions in perennial bioenergy crops is crucial to understanding the contribution of these crops in mitigating climate change through reduced greenhouse gas (GHG) emissions. In this study, a 49-day laboratory incubation experiment was conducted to compare the impact of freeze-thaw cycles on NO and CO emissions in different perennial bioenergy crops [miscanthus (Miscanthus giganteus L.), switchgrass (Panicum virgatum L.

Operationalizing ambiguity in sustainability science: embracing the elephant in the room.

Ambiguity is often recognized as an intrinsic aspect of addressing complex sustainability challenges. Nevertheless, in the practice of transdisciplinary sustainability research, ambiguity is often an 'elephant in the room' to be either side-stepped or reduced rather than explicitly mobilized in pursuit of solutions. These responses threaten the salience and legitimacy of sustainability science by masking the pluralism of real-world sustainability challenges and how research renders certain frames visible and invisible.

People accept breaks in the causal chain between crime and punishment.

Crime and punishment are usually connected. An agent intentionally causes harm, other people find out, and they punish the agent in response. We investigated whether people care about the integrity of this causal chain.

Raman Spectroscopic Analysis of the Reaction between Al-Si Coatings and Steel.

Hot-stamped ultrahigh strength steel components are pivotal to automotive light-weighting. Steel blanks, often coated with an aluminum-silicon (Al-Si) layer to protect them from oxidation and decarburization, are austenitized within a furnace and then simultaneously quenched and formed into shape. The Al-Si coating melts within the furnace and reacts with iron from the steel to yield an intermetallic phase that provides some long-term corrosion protection.

EEG-Meta-Microstates: Towards a More Objective Use of Resting-State EEG Microstate Findings Across Studies.

Over the last decade, EEG resting-state microstate analysis has evolved from a niche existence to a widely used and well-accepted methodology. The rapidly increasing body of empirical findings started to yield overarching patterns of associations of biological and psychological states and traits with specific microstate classes. However, currently, this cross-referencing among apparently similar microstate classes of different studies is typically done by "eyeballing" of printed template maps by the individual authors, lacking a systematic procedure.

Close counterfactuals and almost doing the impossible.

Can we feel that an unrealized outcome nearly happened if it was never possible in the first place? People often consider counterfactual events that did not happen, and some counterfactuals seem so close to reality that people say they "almost" or "easily could have" happened. Across four preregistered experiments (total N = 1,228), we investigated how judgments of counterfactual closeness depend on possibility, and whether this varies across two kinds of close counterfactuals. In judging whether outcomes almost happened, participants were more strongly impacted by possibility than by incremental manipulations of probability.

High Voltage: The Molecular Properties of Redox-Active Dissolved Organic Matter in Northern High-Latitude Lakes.

Redox-active functional groups in dissolved organic matter (DOM) are crucial for microbial electron transfer and methane emissions. However, the extent of aquatic DOM redox properties across northern high-latitude lakes and their relationships with DOM composition have not been thoroughly described. We quantified electron donating capacity (EDC) and electron accepting capacity (EAC) in lake DOM from Canada to Alaska and assessed their relationships with parameters from absorbance, fluorescence, and ultrahigh resolution mass spectrometry (FT-ICR MS) analyses.

Six years of wearer experience in children participating in a myopia control study of MiSight® 1 day.

Purpose: To evaluate the experience of children wearing soft contact lenses (CLs) during a trial of MiSight® 1 day (omafilcon A, CooperVision, Inc.), a dual-focus myopia-control daily disposable CL.

Methods: A 3-year, double-masked, randomised trial (Part 1) comparing experiences with MiSight 1 day and a single-vision control (Proclear® 1 day, omafilcon A, CooperVision, Inc.

Validation of Field-Dependent Ion-Solvent Cluster Modeling via Direct Measurement of Cluster Size Distributions.

Ion mobility spectrometry is widely used in analytical chemistry, either as a stand-alone technique or coupled to mass spectrometry. Ions in the gas phase tend to form loosely bound clusters with surrounding solvent vapors, artificially increasing the collisional cross section and the mass of the ion. This, in turn, affects ion mobility and influences separation.

Do more stringent policies reduce daily COVID-19 case counts? Evidence from Canadian provinces.

The enactment of COVID-19 policies in Canada falls under provincial jurisdiction. This study exploits time-series variation across four Canadian provinces to evaluate the effects of stricter COVID-19 policies on daily case counts. Employing data from this time-period allows an evaluation of the efficacy of policies independent of vaccine impacts.

Customizable Machine-Learning Models for Rapid Microplastic Identification Using Raman Microscopy.

Raman spectroscopy is commonly used in microplastics identification, but equipment variations yield inconsistent data structures that disrupt the development of communal analytical tools. We report a strategy to overcome the issue using a database of high-resolution, full-window Raman spectra. This approach enables customizable analytical tools to be easily created─a feature we demonstrate by creating machine-learning classification models using open-source random-forest, K-nearest neighbors, and multi-layer perceptron algorithms.

Computational Screening of Metal-Organic Frameworks for Ammonia Capture from H/N/NH Mixtures.

The separation of ammonia from H/N/NH mixtures is an important step in ammonia decomposition for hydrogen production and ammonia synthesis from H and N based nonaqueous technologies. Metal-organic frameworks (MOFs) are considered as potential materials for capturing ammonia. In the present work, high-throughput screening of 2932 Computation-Ready Experimental MOFs (CoRE MOFs) was carried out for ammonia capture from H/N/NH mixtures by Grand Canonical Monte Carlo (GCMC) simulations.

A probabilistic approach to the quantification of methane generation in sewer networks.

Quantifying greenhouse gas (GHG) emissions from the conveyance of wastewater is an essential part of emissions reduction as it can identify areas of high emissions that can be targeted for mitigative action. In this study, a Monte Carlo algorithm that employs a reach-based methane generation sub-model was developed and applied to a full-scale municipal sewer system in Ontario, Canada. The algorithm employed eight categories of random variables including sewage temperature, slope, and coefficients described in the sewer reach model.

Electrified ammonia production as a commodity and energy storage medium to connect the food, energy, and trade sectors.

Ammonia, a versatile chemical that is distributed and traded widely, can be used as an energy storage medium. We carried out detailed analyses on the potential economic risks and benefits of using power-to-ammonia in three use pathways in the food, energy, and trade sectors, i.e.

Relationality, Responsibility and Reciprocity: Cultivating Indigenous Food Sovereignty within Urban Environments.

There are collective movements of Indigenous food sovereignty (IFS) initiatives taking up place and space within urban environments across the Grand River Territory, within southern Ontario, Canada. Indigenous Peoples living within urban centres are often displaced from their home territories and are seeking opportunities to reconnect with culture and identity through Land and food. This research was guided by Indigenous research methodologies and applied community-based participatory research to highlight experiences from seven Indigenous community members engaged in IFS programming and practice.

Numerical Investigation on the Anti-Angiogenic Therapy-Induced Normalization in Solid Tumors.

This study numerically analyzes the fluid flow and solute transport in a solid tumor to comprehensively examine the consequence of normalization induced by anti-angiogenic therapy on drug delivery. The current study leads to a more accurate model in comparison to previous research, as it incorporates a non-homogeneous real-human solid tumor including necrotic, semi-necrotic, and well-vascularized regions. Additionally, the model considers the effects of concurrently chemotherapeutic agents (three macromolecules of IgG, F(ab')2, and F(ab')) and different normalization intensities in various tumor sizes.

The devil is in the details: emerging insights on the relevance of wastewater surveillance for SARS-CoV-2 to public health.

The severe health consequences and global spread of the COVID-19 pandemic have necessitated the rapid development of surveillance programs to inform public health responses. Efforts to support surveillance capacity have included an unprecedented global research response into the use of genetic signals of SARS-CoV-2 in wastewater following the initial demonstration of the virus' detectability in wastewater in early 2020. The confirmation of fecal shedding of SARS-CoV-2 from asymptomatic, infected and recovering individuals further supports the potential for wastewater analysis to augment public health conventional surveillance techniques based on clinical testing of symptomatic individuals.

Improved First-Principles Model of Differential Mobility Using Higher Order Two-Temperature Theory.

Differential mobility spectrometry is a separation technique that may be applied to a variety of analytes ranging from small molecule drugs to peptides and proteins. Although rudimentary theoretical models of differential mobility exist, these models are often only applied to small molecules and atomic ions without considering the effects of dynamic microsolvation. Here, we advance our theoretical description of differential ion mobility in pure N and microsolvating environments by incorporating higher order corrections to two-temperature theory (2TT) and a pseudoequilibrium approach to describe ion-neutral interactions.

Differentiating Defects and Their Influence on Hematite Photoanodes Using X-ray Absorption Spectroscopy and Raman Microscopy.

A high degree of variability in behavior and performance of hematite as photoanodes for the oxygen evolution reaction signifies a need to improve our understanding of the interplay between defects and photoelectrochemical performance. We approach this problem by applying structure-property analysis to a series of hematite samples synthesized under either O or N environments such that they exhibit highly variable performance for photoelectrocatalytic oxygen evolution. X-ray absorption fine-structure spectroscopy and Raman spectroscopy provide parameters describing the structure of samples across the series.