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Angew Chem Int Ed Engl
May 2022
Department of Chemistry, Carleton College, 1N. College St., Northfield, MN 55057, USA.
Article Synopsis
- - This study highlights a new method of using cobalt silylene (Co=Si bond) for catalysis, which helps in group-transfer reactions.
- - The setup offers two different sites (Co and Si) for activating substrates, which makes the process more versatile and efficient.
- - By having these distinct reaction sites, the method prevents issues where competing substrates could deactivate the catalyst, allowing for smoother nitrene-group transfer to carbon monoxide.