Solvating additives drive solution-mediated electrochemistry and enhance toroid growth in non-aqueous Li-O₂ batteries.

Given their high theoretical specific energy, lithium-oxygen batteries have received enormous attention as possible alternatives to current state-of-the-art rechargeable Li-ion batteries. However, the maximum discharge capacity in non-aqueous lithium-oxygen batteries is limited to a small fraction of its theoretical value due to the build-up of insulating lithium peroxide (Li₂O₂), the battery's primary discharge product. The discharge capacity can be increased if Li₂O₂ forms as large toroidal particles rather than as a thin conformal layer.

Chiral spin torque arising from proximity-induced magnetization.

Domain walls can be driven by current at very high speeds in nanowires formed from ultra-thin, perpendicularly magnetized cobalt layers and cobalt/nickel multilayers deposited on platinum underlayers due to a chiral spin torque. An important feature of this torque is a magnetic chiral exchange field that each domain wall senses and that can be measured by the applied magnetic field amplitude along the nanowire where the domain walls stop moving irrespective of the magnitude of the current. Here we show that this torque is manifested when the magnetic layer is interfaced with metals that display a large proximity-induced magnetization, including iridium, palladium and platinum but not gold.

Supramolecular high-aspect ratio assemblies with strong antifungal activity.

Efficient and pathogen-specific antifungal agents are required to mitigate drug resistance problems. Here we present cationic small molecules that exhibit excellent microbial selectivity with minimal host toxicity. Unlike typical cationic polymers possessing molecular weight distributions, these compounds have an absolute molecular weight aiding in isolation and characterization.