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http://dx.doi.org/10.1103/physrevb.44.11759 | DOI Listing |
J Chem Phys
January 2025
Department of Physics and Astronomy, University of Calgary, 2500 University Drive North West, Calgary, Alberta T2N 1N4, Canada.
Spectra of the weakly bound H2O-O2 dimer are studied in the region of the H2O ν2 band using a tunable quantum cascade laser to probe a pulsed supersonic slit jet expansion. These are the first gas-phase infrared spectra of H2O-O2 and among only a few such results for O2-containing complexes. Almost 100 infrared lines are assigned based on the ground state combination differences from the microwave spectrum of H2O-O2.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
Department of Chemistry "U. Schiff", University of Florence & UdR INSTM Firenze, 50019 Sesto Fiorentino, Italy.
Photoexcited organic chromophores appended to molecular qubits can serve as a source of spin initialization or multilevel qudit generation for quantum information applications. So far, this approach has been primarily investigated in chromophore-stable radical systems. Here, we extend this concept to a linked oxovanadium(IV) porphyrin-free-base porphyrin dimer.
View Article and Find Full Text PDFNanophotonics
November 2024
Chimie ParisTech, PSL University, CNRS, Institut de Recherche de Chimie Paris, Paris, France.
Efforts to harness quantum hardware relying on quantum mechanical principles have been steadily progressing. The search for novel material platforms that could spur the progress by providing new functionalities for solving the outstanding technological problems is however still active. Any physical property presenting two distinct energy states that can be found in a long-lived superposition state can serve as a quantum bit (qubit), the basic information processing unit in quantum technologies.
View Article and Find Full Text PDFSci Adv
December 2024
CAS Key Laboratory of Microscale Magnetic Resonance and School of Physical Sciences, University of Science and Technology of China, Hefei 230026, China.
Quantum systems, including superconducting circuits, trapped ions, quantum dots, solid-state defects, etc., have achieved considerable advancements in readout fidelity. However, the widely used threshold method disregards the importance of temporal characteristics of the signal during continuous measurements, leading to information loss.
View Article and Find Full Text PDFJ Phys Condens Matter
December 2024
Harish-Chandra Research Institute, a CI of Homi Bhabha National Institute, Chhatnag Road, Jhunsi, Allahabad 211019, India.
Symmetries play a crucial role in understanding phases of matter and the transitions between them. Theoretical investigations of quantum models with SU() symmetry have provided important insights into many-body phenomena. However, these models have generally remained a theoretical idealization, since it is very difficult to exactly realize the SU() symmetry in conventional quantum materials for large.
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